• KSCE Journal of Civil and Environmental Engineering Research
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• v.36 no.2
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• pp.207-217
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• 2016

Permeability can not be expressed as a function of porosity alone, it depends on the porosity, pore size and distribution, and tortuosity of pore channels in concrete. There has been considerable interest in the relationship between microstructure and transport in cementitious materials, however, it is very rare to deal with the theoretical study on gas permeability coefficient in connection with carbonation of concrete and the effect of volumetric fraction of cement paste or aggregate on the permeability coefficient. The majority of these researches have not dealt with this issue combined with carbonation of concrete, although carbonation can significantly impact on the permeability coefficient of concrete. In this study, fundamental approach to compute gas permeability of (non)carbonated concrete is suggested. For several compositions of cement pastes, the gas permeability coefficient was calculated with the analytical formulation, followed by a microstructure-based model. For carbonated concrete, reduced porosity was calculated and this was used for calculating the gas permeability coefficeint. As the result of calculation of gas permeability for carbonated concrete, carbonation leaded to the significant reduction of gas permeability coefficient and this was obvious for concrete with high w/c ratio. Meanwhile, the relationship between gas permeability and water permeability has a linear function for cement paste based on Klinkenberg effect, however, which is not effective for concrete. For the evidence of the modeling, YOON's test was accomplished and these results were compared to each other.

• Journal of the Korea Concrete Institute
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• v.13 no.3
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• pp.277-284
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• 2001

Hardened concrete contains pores of varying types and sizes, and therefore the transport of air through concrete can be considered. The rate of permeability will not only depends on the continuity of pores, but also on the moisture contents in concrete and finishing material on concrete. Also it knows that the durability of reinforced concrete structure is concerned with air permeability which effects on the carbonation occurred by invasion of CO2 gas and the corrosion of steel bar occurred by O$_2$. In this paper, the effects of curing conditions and finishing materials on carbonation and air permeability are investigated according to the accelerated carbonation test. As results, carbonation velocity and air permeability are effected by curing conditions and finishing materials, and air permeability coefficient is effected by moisture content. Also the relationship between carbonation velocity coefficients and air permeability coefficients has been quite well established.

• Journal of the Korean Society of Groundwater Environment
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• v.7 no.1
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• pp.24-31
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• 2000

Soil air permeability and influence of radius in air injection/extraction tests were estimated. These are important factors in the determination of optimal design for SVE or bioventing system. For evaluation of the effects of air leakage from the ground surface on those factors, Theis (1935) and Hantush (1960) methods were used in the data analysis. The air permeability of the studied area was in the range of 1.64$\times$$10^{-7}$~5.66$\times$$10^{-6}$ $\textrm{cm}^2$, and this result would be used for the design of SVE or bioventing system.

• Journal of Soil and Groundwater Environment
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• v.12 no.5
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• pp.9-18
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• 2007

Soil vapor extraction (SVE) is an effective and cost efficient method of removing volatile organic compounds (VOCs) and petroleum hydrocarbons from unsaturated soils. However, soil vapor extraction becomes ineffective in soils with low gas permeability, for example soils with air permeabilities less than 1 Darcy. Incorporating PVDs in an SVE system can extend the effectiveness of SVE to lower permeability soils by shortening the air flow-paths and ultimately expediting contaminant removal. The objective of the research described herein was to effectively incorporate PVDs into a SVE remediation system. The test results show that the gas permeability was evaluated for four different equivalent diameters, increasing the equivalent diameter results in a decrease in the calculated gas permeability. It was found that the porosity for the dry condition was greater than that of the wet condition and will allow flow rate for the same vacuum flow, offering a low resistance to the air flow.

• Proceedings of the Korea Concrete Institute Conference
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• 2010.05a
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• pp.221-222
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• 2010

In this study an expression is obtained the model equation for the prediction of carbonation based on the time and interaction velocity between $CO_2$ and $Ca(OH)_2$ diffusion coefficient.

• Journal of Korea Soil Environment Society
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• v.3 no.1
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• pp.83-92
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• 1998

This study presents a relationship between gas quantity and measurement resistance using the bubble meter, the water head indicator and the rotor meter from the gas vent sanitary landfill. From the one-dimensional analyses and experiments, the below results have been obtained. The gas volume sourcing from the gas vent depends on the permeability of final cover soil, its cover depth and distance between the gas vents. The total gas volume producing in the interested domain may be accurately measured by the bubble meter, the water head indicator and the rotor meter if the clay is used for the final cover soil. The required times approaching to the steady-state are different with respect to the flow meters, one day is for the bubble meter and the water head indicator and one hour for the rotor meter.

• Journal of the Korea Concrete Institute
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• v.22 no.2
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• pp.209-217
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• 2010

Recently, some mathematical models for the prediction on progress of carbonation of concrete were reported. These models take account for $CO_2$ diffusion and chemical reaction between $Ca(OH)_2$ and $CO_2$. Based on the assumption that $CO_2$ diffuses in the carbonation zone and reacts with $Ca(OH)_2$ at the outer face of carbonation zone and non-carbonation zone. In this study, a mathematical model to predict the progress of carbonation of concrete has been established based on the reducing concentration of $Ca(OH)_2$ in the carbonation progress zone, where $Ca(OH)_2$ reacts with $CO_2$ and $Ca(OH)_2$ and $CaCO_3$ coexist. Also, the prediction model of carbonation progress rate of concrete using the air permeability coefficient regarding to $CO_2$ diffusion is developed. As a result of this study, an expression, the model equation is obtained for the prediction of carbonation based on the time and interaction velocity between $CO_2$ and Ca(OH)$_2$ dependent air permeability coefficient. The prediction by the model satisfied the experimental data of the accelerated carbonation for painted concrete. Consequently, the model can predict the rate of carbonation and the potential service life of concrete structure exposed to atmosphere.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2023.05a
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• pp.113-114
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• 2023

This study measured the thickness and speculation coefficient of the coating for existing buildings and calculated the diffusion coefficient of the coating to predict the depth of carbonation through numerical analysis in order to evaluate the impact of the external finish and local environment. As a result, it was possible to predict the short-term and long-term carbonation depth of reinforced concrete buildings coated with coating film with considerable reliability.

• Asia-Pacific Journal of Business Venturing and Entrepreneurship
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• v.12 no.1
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• pp.133-144
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• 2017

This study investigates firm-specific financial variables that determine investment or speculative grades from the viewpoint of firms, which are one of the major stakeholders related to the credit rating. We employ an ordered probit model for our analysis with the sample data from 1999 to 2015 for listed firms in the Korean stock markets. For investment grades, operating margin, sales, market-to-book, dividend payment, capital expenditure ratio, and tangible asset ratio have a significantly positive impact on credit ratings. In the subsample for speculative grades, the coefficients of the dividend payment, retained earnings ratio, and capital expenditure ratio are significantly positive while short-term debt ratio and R&D expenditures have a significantly negative impact on credit ratings. For the analysis before and after 2009, when the Credit Information Use and Protection Act was strengthened after the global financial crisis, the coefficients of the capital expenditure ratio, cash ratio, and tangible asset ratio are significantly positive in the subsample for investment grades before 2009, but not significant after 2010. The coefficient of the long-term debt ratio is more significantly negative than that of the short-term debt ratio before 2009, for speculative grades, but short-term debt ratio has a more negative effect on ratings than long-term debt ratio after 2010. Surprisingly, the coefficient of the R&D expenditures is significantly negative in both investment and speculative grades since 2010. Our findings are inconsistent with the conjecture that the increase in R&D expenditures enhances the possibility of creating cash-flow by raising the investment growth opportunity, and thus affects positively the credit rating.

• Proceedings of the Korea Concrete Institute Conference
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• 2010.05a
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• pp.379-380
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• 2010

This study is aimed to investigate performance of the NPP structure. Thus, assess the effects of physical properties of NPP concrete by measure the compressive strength, permeability coefficient and air permeability coefficient.