• Title/Summary/Keyword: 투과성계수

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Fourth harmonic generation of a Nd:YAG laser using $CsLiB_6O_{10}$(CLBO) crystals ($CsLiB_6O_{10}$ 단결정을 이용한 Nd:YAG 레이저의 4차 조화파 발생)

  • 김지원;김민수;류기한;윤춘섭
    • Proceedings of the Optical Society of Korea Conference
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    • 2001.02a
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    • pp.226-227
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    • 2001
  • CsLiB$_{6}$O$_{10}$(CLBO) 단결정은 넓은 광투과 영역, 극자외선 영역에서의 광투과성, 비교적 큰 비선형 광학계수, 높은 레이저 광손상 문턱값 등의 우수한 특성으로 인해 극자외선 영역에서의 파장변환과 고출력 레이저의 파장변환에 매우 활발한 응용이 시도되고 있다. 본 연구에서는 CLBO 단결정을 이용하여 Nd:YAG 레이저의 1064 nm 파장을 4차 조화파인 266 nm 파장으로 변환시키고 광변환 특성을 조사하였다. (중략)

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$CO_2$ 분리용 Polyetherimide Hollow Fiber Membrane의 제조 및 투과특성

  • 박유인;이규호
    • Proceedings of the Membrane Society of Korea Conference
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    • 1993.04a
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    • pp.36-37
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    • 1993
  • 상전이 공정에 의해 제조된 기체분리용 중공사막은 1차적으로 방사원액의 조성과 내.외부응고제의 조성, 중공사 방사조건 그리고 후처리 과정에 의해서 전체적인 구조가 결정되어진다. 특히 기체 분리에 이용되는 Nonprous Membrane의 경우 Dense Skin의 Thickness와 Pinhole의 유무에 따라 투과성과 선택성에 커다란 영향을 미친다. 따라서 최근에는 Dense Skin의 초박막화와 Pinhole이 없는 비대칭막 제조등 폭넓은 연구가 이루어지고 있다. 본 연구에서는 CO$_2$ Gas 분리용 Polyetherimide 중공사막을 제조하여, 중공사막 제조조건과 후처리 조건에 따른 $CO_2/N_2$ Gas의 분리계수를 측정하였다.

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The Preparation of a Polyimide Membrane for the Separation of Water-Acetic Acid Mixture through Pervaporation (Polyimide 막에 의한 물-초산계의 투과증발 분리)

  • 박영태
    • Membrane Journal
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    • v.9 no.4
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    • pp.215-220
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    • 1999
  • The asymmetric polyimide [PI] membrane with good solvent-resisting and heat-resisting properties was prepared by using the phase inversion method from polyamic acid, and its pervaporation separation characteristics of water-acetic acid system were studied. It was appeared from the prepared membranes that the best non-solvent of polyamie acid for the phase inversion was toluene. The best heat-treatment condition for the imidization of polyamic acid was 1 hr heating at each of the temperatures, 373, 473, and 573 K The thermal durability and chemical stability during the pervaporation separation of water-acetic acid of the prepared PI membrane was superior. The pervaporation characteristics of prepared membrane were 180 of separation factor and 0.5 kg/$m^2$hr of total flux for 80 wt% acetic acid feed.

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Experimental Study on Functional Improvement of Porous Floating Breakwaters (유공부유식방파제의 방파성능에 관한 실험적 연구)

  • Yoon, Jae-Seon;Han, Sae-Jong;Cho, Yong-Sik
    • Proceedings of the Korea Water Resources Association Conference
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    • 2011.05a
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    • pp.44-48
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    • 2011
  • 본 연구에서는 구조물 상치에 에어챔버를 설치하여 챔버 내부의 공기주입량에 따라 흘수심을 조절 할 수 있는 유공 및 투수성부유식방파제를 사용하였으며, 부유식방파제의 흘수심구간에 유공을 두어 내부의 흐름에 따른 에너지소산 효과를 수리모형실험을 통하여 분석하였다. 기존 연구에 의하여 선행되어진 부유식방파제의 형상은 구조물 제체의 입사면과 투과면이 막힌 형태의 연구가 대다수였으나, 계류라인의 장력에 따른 부체의 안정성을 고려하여 본 수리모형실험에서는 입사면 흘수심구간과 투과면 흘수심구간에 유공 및 투수층을 두어 진행하는 입사파랑을 일부 흡수하도록 하였다. 또한, 부유식방파제 흘수심단면의 내부에서 흐름변화에 의한 에너지소산 효과와 입사면과 투과면의 유공률 변화에 따른 방파성능을 무공 부유식방파제와 비교하며 효율성을 분석하였다.

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The Relationship between Affinity of Membrane and Optimum Operation Conditions in the Pervaporation of Aqueous Ethanol (에탄올 수용액의 투과증발에 있어서 막의 친화성과 최적 조업조건의 관계)

  • 전종기;명완재;임선기
    • Membrane Journal
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    • v.1 no.1
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    • pp.34-43
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    • 1991
  • The relationships between affinity of membranes and optimum operation conditions were investigated in the pervaporation of water(1)/ethanol(2) mixture through cellulose acetate(CA) membranes having more affinity to water and silicone rubber(SR) membranes having more affinity to ethanol. CA and SR membranes were prepared and amount of sorption, sorption selectivity, pervaporation separation factor and pervaporation rate in both of membranes were determined and compared. The effects of downstream pressure were analyzed using Thompson diagram and the sorption and pervaporation characteristics with composition of feed and operation temperature were examined in terms of affinity, activity coefficient, plasticizing effect and activation energy of individual species. In the separation of water through CA membranes, high performance of both pervaporation separation factor (water to ethanol, $[\alpha^2_1]_{PV}$) and pervaporation rate was obtained in the conditions of low downstream pressure, middle range of feed concentration and high temperature. In the separation of ethanol through SR membranes, pervaporation separation factor(ethanol to water, $[\alpha^2_1]_{PV}$) increased with downstream pressure and decreased with concentration of ethanol in feed and operation temperature, while pervaporation rate showed opposite trends to those of ($[\alpha^2_1]_{PV}$).

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Natural Convection for Air-Layer between Body Skin and Clothing with Considering Coefficient of Permeability (투과계수를 고려한 의복과 인체 사이의 공기층에서 자연대류 특성)

  • 지명국;배강렬;정효민;정한식;추미선
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.12
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    • pp.1282-1287
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    • 2001
  • This study presents the numerical analysis of natural convection of a micro- environments with air permeability in the clothing air-layer. As a numerical model the clothing air layer of shoulder and arm were adopted. Finite volume method for two-dimensional laminar flow was used for the analysis of flow and thermal characteristics of velocity, temperature and concentration in the air layer between body and clothing. As temperature boundary conditions, a body skin has a high temperature with $34^{\circ}C$ and the environmental temperatures are 5, 15 and $25^{\circ}C$ for various permeability coefficients. The distributions of concentration, temperature and velocity are shown that two large cells form at horizontal and vertical air layer, respectively. As the temperature difference between body skin and environment decreases, the heat transfer is decreased rapidly.

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Effect of Inorganic Fillers on the Dimensional Stability of Poly(ethylene naphthalate) Film as a Flexible Substrate (무기 필러가 유연기판용 폴리에틸렌나프탈레이트 필름 치수안정성에 미치는 영향)

  • Kim, Jongwha;Kim, Hongsuk;Kang, Ho-Jong
    • Polymer(Korea)
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    • v.36 no.6
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    • pp.733-738
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    • 2012
  • The effect of glass bead and glass fiber on the enhancement of dimensional stability in poly(ethylene naphthalate) (PEN) flexible substrate for photovoltaic devices has been studied. It was found that the coefficient of thermal expansion (CTE) and the optical transmittance decreased with increasing inorganic filler content. In addition to filler contents, the size and size distribution of fillers are the other important factors to improve CTE and optical transmittance of PEN film. Our results showed that the optimum filler content was found to be about 5 wt% to enhance the dimensional stability of PEN by more than 50% with maintaining the optical transmittance over 85% for the flexible substrate.

Analysis of RTM Process to Manufacture Composite Bogie Frame Considering Fiber Orientation (섬유방향성을 고려한 복합소재 대차 프레임의 RTM 성형 특성 해석)

  • Kim, Moo Sun;Kim, Jung-Seok;Kim, Seung Mo
    • Journal of the Korean Society for Railway
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    • v.18 no.4
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    • pp.301-308
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    • 2015
  • To reduce the weight of a railroad vehicle, a bogie frame skin is considered for manufacture using an RTM process and composite material. Compared to other processes, RTM has merits in that it demands only simple manufacturing facilities and can produce a large and complex structure in a short cycle time. On the other hand, it is important to determine the proper number and locations of gates and vents to prevent void formation inside a structure. In this study, we numerically predicted the flow pattern in a bogie frame skin during the RTM process by distinguishing the permeability of a fiber mat as isotropic or anisotropic. Using the results, we analyzed the RTM process conditions of the bogie frame to predict skin void formation, mold filling time, and optimum location of vents depending on the permeability conditions.

Preparation and Characterization of the Impregnation to Porous Membranes with PVA/PSSA-MA for Fuel Cell Applications (연료전지 응용을 위한 다공성막에 친수성 고분자의 함침을 통한 고내구성 이온교환막의 제조 및 특성 연구)

  • Lee, Bo-Sung;Jung, Sun-Kyoung;Rhim, Ji-Won
    • Polymer(Korea)
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    • v.35 no.4
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    • pp.296-301
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    • 2011
  • This study focuses on the investigation of the impregnation of poly (vinyl alcohol) (PVA) crosslinked with poly(styrene sulfonic acid-co-maleic acid) (PSSA-MA) to porous polyethylene membrane for the fuel cell application. The membranes were characterized by the measurements of the water content, contact angle, FTIR spectra, thermal gravimetric analysis, ion exchange capacity, proton conductivity, methanol permeability and elastic modulus. The existence of hydrophilic moieties in the impregnated membranes was confirmed by contact angle and FTIR measurements. The impregnated PVA/PSSAMA(90:10) membrane exhibited a higher ion exchange capacity (1.2 meq./g dry membrane) than Nafion membrane (0.91 meq./g dry membrane). Through the elastic modulus measurement, the dimensional stability of the resulting membranes was expected to increase higher than the polyethylene membranes. The methanol crossover and water content decreased even if the PSSA-MA content increased due to the reduction of the free volume.

The Study for Diffusion Mechanism of Amino Acids Through Poly(2-Hydroxyethyl Methacrylate) Membrane (Poly(2-Hydroxyethyl Methacrylate)막을 통한 아미노산의 확산 기구에 관한 연구)

  • Kim Ui-Rak;Jeong Bong-Jin;Lee Myung-Jae;Min Kyung-Sub
    • Journal of the Korean Chemical Society
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    • v.37 no.1
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    • pp.10-21
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    • 1993
  • The transport phenomena of ten amino acid molecules through poly(2-hydroxyethyl methacrylate), P(HEMA) membrane have been investigated in various range pH solutions. It is found that the permeability and diffusivity of the amino acids through membrane depended on the different shape, size and the charge of them are changed by the pH. The permeabilities and diffusivities of amino acids have the largest value in the neutral solution. In this case, they are diffused through free water in the P(HEMA) membrane and the diffusion mechanism is the pore type. The basic solution have larger value than the acidic it. Whether the diffusion mechanism of the core type or the partition type, it is depended on the effect of side chain of the amino acid in basic and acidic solution.

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