• Title/Summary/Keyword: 통과전하

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Development of a continuous electrolytic system with an ion exchange membrane for pH-control with only one discharge of electrolytic solution and its characteristics (단일 전해액 배출만을 가지는 pH조절용 연속식 이온 교환막 전해 시스템의 개발과 그 특성)

  • Kim Kwang-Wook;Kim In-Tae;Park Geun-Il;Lee Eil-Hee
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.3 no.4
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    • pp.269-278
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    • 2005
  • In order to produce only a pH-controlled solution without discharging any unwanted solution, this work has developed a continuous electrolytic system with a pH-adjustment reservoir being placed before an ion exchange membrane-equipped electrolyzer, where as a target solution was fed into the pH-adjustment reservoir, some portion of the solution in the pH-adjustment reservoir was circulated through the cathodic or anodic chamber of the electrolyzer depending on the type of the ion exchange membrane used, and some other portion of the solution in the pH-adjustment reservoir was discharged from the electrolytic system through the other counter chamber with its pH being controlled. The internal circulation of the pH-adjustment reservoir solution through the anodic chamber in the case of using a cation exchange membrane and that through the cathodic chamber in the case of using an anion exchange membrane could make the solution discharged from the other counter chamber effectively acidic and basic, respectively. The phenomena of the pH being controlled in the system could be explained by the electro-migration of the ion species in the solution through the ion exchange membrane under a cell potential difference between anode and cathode and its consequently-occurring non-charge equilibriums and electrolytic water- split reactions in the anodic and cathodic chambers.

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Development of a Continuous Electrolytic System for pH-control with Only One Discharge of Electrolytic Solution by Using Non-equilibrium Steady State Transfer of Ions across Ion Exchange Membranes (이온 교환막에서 이온의 비 평형 정상상태 이동을 이용한 단일 전해액의 배출만을 가지는 pH 조절용 연속식 전해 반응기 개발)

  • Kim Kwang-Wook;Lyu Je-Wook;Kim In-Tae;Park Geun-Il;Lee Eil-Hee
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.101-109
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    • 2005
  • In order to produce only a pH-controlled solution without discharging any unused solution, this work has developed a continuous electrolytic system with a pH-adjustment reservoir being placed before an ion exchange membrane-equipped electrolyzer, where as a target solution was fed into the pH-adjustment reservoir, some portion of the solution in the pH-adjustment reservoir was circulated through the cathodic or anodic chamber of the electrolyzer depending on the type of the ion exchange membrane used, and some other portion of the solution in the pH-adjustment reservoir was discharged from the electrolytic system through other counter chamber with its pH being controlled as acid or base. The phenomena of the pH being controlled in the system could be explained by the electro-migration of the ion species in the solution through the ion exchange membrane under a cell potential difference between anode and cathode and its consequently-occurring non-charge equilibriums and electrolytic water- split reactions in the anodic and cathodic chambers.

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A Study on Strength and Durability of Vibrated and Rolled Method Mortar Mixed with Desulfurized Gypsum and Ferronickel Slag Fine Powder (탈황석고와 페로니켈슬래그 미분말을 혼합한 진동전압방식 모르타르의 강도 및 내구성에 관한 연구)

  • Yoo, Jeong-Hwan;Park, Sang-Soon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.545-552
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    • 2021
  • In this study, strength and durability evaluations are performed on vibrated-rolled method mortar mixtures containing desulfurized gypsum and ferronickel slag powder. Desulfurized gypsum and ferronickel slag fine powders were substituted for 25% limestone fine powders u sed in the manu factu re of VR tu bes, and mortar specimens were prepared u sing vibrated-rolled method. Accordingly, flexural and compressive strengths were performed to evaluate the strength, and chlorine ion penetration resistance and sulfuric acid resistance tests were performed to evaluate durability. Flexural and compressive strength were improved in the range 20 to 60% of desu lfu rized gypsu m among admixtu res, and the amou nt of passing charge decreased in the choride ion penetration resistance test in the range of 20 to 80% of desulfurized gypsum. As for the resistance to su lfu ric acid, when the proportion of desu lfu rized in the admixtu re was 40%, the strength and weight change rate according to the immersion period was reduced. Appropriate use of desulfurized gypsum and ferronickel slag powder is expected to improve performance in terms of strength and durability.

Hand Motion Signal Extraction Based on Electric Field Sensors Using PLN Spectrum Analysis (PLN 성분 분석을 통한 전기장센서 기반 손동작신호 추출)

  • Jeong, Seonil;Kim, Youngchul
    • Smart Media Journal
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    • v.9 no.4
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    • pp.97-101
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    • 2020
  • Using passive electric field sensor which operates in non-contact mode, we can measure the electric potential induced from the change of electric charges on a sensor caused by the movement of human body or hands. In this study, we propose a new method, which utilizes PLN induced to the sensor around the moving object, to detect one's hand movement and extract gesture frames from the detected signals. Signals from the EPS sensors include a large amount of power line noise usually existing in the places such as rooms or buildings. Using the fact that the PLN is shielded in part by human access to the sensor, signals caused by motion or hand movement are detected. PLN consists mainly of signals with frequency of 60 Hz and its harmonics. In our proposed method, signals only 120 Hz component in frequency domain are chosen selectively and exclusively utilized for detection of hand movement. We use FFT to measure a spectral-separated frequency signal. The signals obtained from sensors in this way are continued to be compared with the threshold preset in advance. Once motion signals are detected passing throng the threshold, we determine the motion frame based on period between the first threshold passing time and the last one. The motion detection rate of our proposed method was about 90% while the correct frame extraction rate was about 85%. The method like our method, which use PLN signal in order to extract useful data about motion movement from non-contact mode EPS sensors, has been rarely reported or published in recent. This research results can be expected to be useful especially in circumstance of having surrounding PLN.

Material Properties Evaluation of Cement Mortar Mixed with Organic/Inorganic Combined Water-repellent (유/무기 복합 발수제를 혼입한 모르타르의 재료특성 평가)

  • Kim, Wan-Su;Yoon, Chang-Bok;Cho, In-Sung;Lee, Han-Seung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.6
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    • pp.50-58
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    • 2020
  • When the concrete surface layer is damaged, The method of impregnating the concrete surface with a water repellent cannot secure the expected durability. Recently, various waterproofing and water-repellent materials were mixed into concrete or mortar to secure water repellency even inside cracks, but compressive strength was greatly reduced. In order to overcome the decrease in compressive strength, there has not yet been a study using the merits of organic and inorganic materials at the same time, so in this study, the physical properties and water repellency performance were evaluated by mixing an organic/inorganic composite water repellent appropriately mixed with an organic and inorganic material into the mortar. When mixed with organic/inorganic water repellent, the flow and air content were reduced by about 10% and 50% compared to the Liquid specimen. In the case of the P6L1 specimen, it was confirmed that the compressive strength decreased by about 3.5% compared to the non-mixed mortar at 39.5 MPa, the same as the existing water repellent, Powder. Water-repellent performance The organic-inorganic composite water repellent mixture specimen confirmed higher water repellency than the existing water repellent mixture powder, and the chloride penetration resistance evaluation result showed that the organic-inorganic composite water repellent mixture specimen reduced the passing charge by about 45% compared to the non-mixed mortar. In summary, it is judged that the P5L1 organic/inorganic composite water repellent mixed with a powder water repellent and a liquid water repellent in a ratio of 5:1 is the most reasonable to prevent the decrease in compressive strength and secure water repellency.

Characteristics of Chloride Diffusion and Compressive Strength in the Mortar containing C12A7 based Binder and Anhydrite (C12A7계 바인더와 무수석고를 혼입한 모르타르의 염화물 확산 및 압축강도 특성)

  • Byeong-Cheol, Lho;Yong-Sik, Yoon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.4
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    • pp.450-456
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    • 2022
  • In this study, as the preliminary research on the development of heating concrete members, compressive strength and accelerated chloride diffusion behavior in the mortar specimens containing C12A7 based binder and anhydrite was evaluated. Also, the effect of the mixing ratio of the citric acid based retarder was quantitatively evaluated by considering 4 levels of mixing cases. The compressive strength tests of the mortar specimen were performed referred to KS L ISO 679, and the accelerated chloride diffusion tests were performed according to NT BUILD 492 and ASTM C 1202. In the mortar with 0.3 % of retarder, the highest compressive strength was evaluated, which showed the strength development ratio of 127.6 % compared to the control case. It was considered that engineering performance was improved by effectively securing setting and curing time with 0.3 % of citric acid based retarder. As the result of the evaluation of the passed charge and the accelerated chloride diffusion coefficient, the evaluation results had similar behavior with the results of compressive strength. According to the previous study, the strength behavior and the chloride diffusion behavior had a linear relationship. The mixture showing the highest strength performance had the highest durability performance for chloride ingress, and the heating concrete development from this study will be performed in the future.

Evaluation of Chloride Ion Penetration Resistance of High Calcium Silicate Cement Concrete (High Sulfated Calcium Silicate 시멘트 콘크리트의 염소이온침투저항성 평가)

  • Jeong, Seok-Man;Yang, Wan-hee;Kim, Hyeon-Soo;Lee, Gun-Cheol
    • Journal of the Korea Institute of Building Construction
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    • v.22 no.1
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    • pp.35-43
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    • 2022
  • The aim of this work was to a comparative review the performance of high calcium silicate cement (HSCSC) and that of ordinary Portland cement(OPC) and blast furnace slag cement(S/C). The result of the compressive test confirmed that the compressive strength development rate of high calcium silicate cement concrete at the age of 3 days was 73.6% that of ordinary Portland cement concrete. However, at the age of 28 days, the strength development rate of high calcium silicate cement increased to about 107.0% compared to ordinary Portland cement. In addition, the test of the chloride ion penetration resistance of concrete showed that at the age of 28 days, the passed charge decreased by 73.4% and 93.0%, respectively, in blast furnace slag cement and high calcium silicate cement compared to ordinary Portland cement, and at the age of 56 days, it decreased by 79.1% and 98.3%, exhibiting excellent resistance to chloride ion penetration. In particular, it was confirmed that the rate of decrease in the passed charge with age was higher in high calcium silicate cement than in ordinary Portland cement and blast furnace slag cement.

Qualitative Analysis of $GeO_2$ in Germanium-Fortified Yeast. (게르마늄강화효모 내의 $GeO_2$ 정성분석)

  • Kim, So-Yeun;Kim, Myoung-Hee;Woo, Hee-Gweon;Kim, Bo-Hye;Sohn, Tsang-Uk;Jung, Jin-Wook;Baek, Dae-Heoun
    • Microbiology and Biotechnology Letters
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    • v.35 no.2
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    • pp.163-172
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    • 2007
  • This study was designed to investigate that inorganic germanium $(GeO_2)$ did not exist in germanium-fortified yeast or obtained to non-detectable value by current analytical methods and equipments. For this purpose, we achieved $GeO_2$ qualitative analysis protocol which could be the scientific basis of the study. Since reddish brown precipitate was formed from the reaction of $GeO_2$ with 1 equiv $NaBH_4$, and dark brown precipitate was also formed from the reaction of $GeO_2$ with 2 equiv $NaBH_4$, $GeO_2$ was qualitatively analyzed by observing these particular colored-precipitates. Because no color change was showed from the reaction between $NaBH_4$ and $SiO_2$, the color change could be caused by charge transfer transition on Ge-O and B binding properties. The reaction between $NaBH_4$ and germanium-fortified yeast did not show any color change and precipitate formation which meant no $GeO_2$ existed in germanium-fortified yeast. The reaction between $NaBH_4$ and supernatant specimen collected from the outside of dialysis membrane (MWCO 1,200 dalton) did not show any color change and precipitate formation. Therefore, we considered that the both germaniums in and outside of the dialysis membrane were organic germaniums. Germanium-fortified yeast which was biosynthesized organic germanium can be applied not only as a new functional material for improving health, prevention and treatment of chronic degenerative diseases including cancers, and the regulation of immune system, but also as a new materials.