• Title/Summary/Keyword: 토양 양이온 함량

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Physicochemical Properties of Forest Soils Related to Sulfate Adsorption (황산이온의 흡착에 관여하는 산림토양의 물리화학적 특성)

  • Lee, Seung-Woo;Park, Gwan-Soo;Lee, Choong-Hwa;Kim, Eun-Young
    • Korean Journal of Soil Science and Fertilizer
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    • v.37 no.6
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    • pp.371-377
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    • 2004
  • Sulfate adsorption in forest soils is a process of sulfur dynamics playing an important role in plant uptake, cation movement, acid neutralization capacity and so on. The relationship between sulfate adsorption and some physicochemical properties of four forest soils was investigated. Extractable sulfate contents and sulfate adsorption capacity (SAC) in the forest soils varied much among study sites. Extractable sulfate contents were more in sub-surface soils with lower organic matter and greater Al and Fe oxides than in surface soils. The average contents of $Al_d$ and $Fe_d$ in the sub-surface soils were 8.49 and $12.45g\;kg^{-1}$, respectively. Soil pH, cation exchange capacity and clay content were positively correlated with the extractable sulfate contents and SAC. Organic carbon content, however, was negatively correlated with the extractable sulfate contents, implying the competitive adsorption of sulfate with soil organic matter. Considerably significant correlation was found between inorganic + amorphous Al and Fe oxides and the sulfate adsorption, but crystalline Al and other fractions of Fe oxide showed no correlation. Relatively close relationship between the adsorbed sulfates and soil pH, cation exchange capacity, or amorphous Al oxides indicates that the accelerated soil acidification may substantially reduce the potential for sulfate adsorption contributing to sulfur flux in forest ecosystems.

The Patterns of Inorganic Cations, Nitrogen and Phosphorus of Plants in Moojechi Moor on Mt. Jeongjok. (정족산 무제치늪 식물의 무기이온, 질소 및 인의 양상)

  • 배정진;추연식;송승달
    • The Korean Journal of Ecology
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    • v.26 no.3
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    • pp.109-114
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    • 2003
  • To investigate ecophysiological characteristics of plants species adapted to moor habitat, we selected 22 species plants and analyzed inorganic cations (K, Ca, Mg), heavy metals (Al, Fe, Mn) and total nitrogen and phosphorus quantitatively. Moojechi moor indicated typical acidic and oligotrophic conditions with pH of 5.0∼5.6 (pH 4.3∼5.1 in soil) and EC of 15∼30μ S/cm, and contained very low contents of soil divalent cation such as Ca and Mg but high contents of heavy metals (esp. Al). With respect to inorganic cation contents, investigated plants species showed remarkable interspecific difference. Plant species belonging to J. effusus var. decipiens, M. japonica, I. globosa, M. sacchariflorus, R. mucronulatum, R. yedoense var. poukhanense, H. micrantha, D. rotundifolia showed very low contents of inorganic cation below 400 μ M/g DW, but plant species of C. palustris var. spontanea, L. sessilifolia, P. mandarinorum, C. lineare, S. austriaca sub. glabra, V. mandshurica, A. decursiva showed high cation contents in leaves. Especially, S. austriaca sub. glabra (Compositae) and V. mandshurica (Violaceae) showed pattern accumulating Ca and Mg with plant growth, but I. ensata var. spontanea (Iridaceae) and S. officinalis (Rosaceae) showed decreasing tendency. Meanwhile, most plant species showed low contents of soluble metal ions in leaves in spite of high heavy metal contents on soil, and indicated remarkable interspecific differences in the total contents and composition of heavy metals accumulated. Despite low contents of N and P on soil, most plant species indicated relatively high contents of N and P in leaves at the early stage of growth, and showed slowly decreasing pattern according to growth. Consequently, it seems that plant species inhabited on Moojechi moor cope with acidic-oligotrophic conditions, accumulating inorganic cations and nitrogen at the early growing stage and reutilizing them in the course of growth, and developing heavy metal excluding mechanism.

Acid/Base Buffer Capacity of Clays (점토의 산/염기 완충능)

  • 김건하;김길홍
    • Journal of the Korean Geotechnical Society
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    • v.16 no.6
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    • pp.97-103
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    • 2000
  • 지반내 중금속의 저류와 이동에 대한 가장 중요한 인자는 토양 간극수의 pH이다. 점토의 완충능을 kaolinite, hectorite, attapulgite, Na-bentonite와 같은 4가지 점토에 대하여 연구하였다. 완충능의 크기는 hectoriteattapulgite>kaolinite의 순으로 나타났다. 완충능의 크기는 지반내 탄산염 함량과 양이온 교환능력이 완충능의 크기에 가장 영향을 미치며 유기물 함량과 비표면적의 영향은 적었다. 토양의 완충능을 모델링하기 위하여 수소 이온과 토양표면의 화학반응 기간의 화학반응을 정전흡착 모델을 이용하여 모델링하였다. 또한 탄산염 함량과 양이온 교환능력을 함수로 하는 회귀식을 제안하였다. 모델 검증을 위하혀 모델 예측치와 실험치를 비교하였는데 정전 흡착모델을 이용한 예측치가 실험치와 근사한값을 나타냈다.

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Antioxidant Enzyme Activities and Soil Properties of Healthy and Declining Abies koreana (Wils.) in Mt. Halla (한라산 구상나무 건전개체와 쇠약개체의 항산화효소활성 및 토양특성)

  • Lim, Jong-Hwan;Woo, Su-Young;Kwon, Mi Jeong;Kim, Young Kul
    • Journal of Korean Society of Forest Science
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    • v.96 no.1
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    • pp.14-20
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    • 2007
  • In order to examine the differences in antioxidant enzyme activities which represent defence mechanism to stressful environments, and soil properties between healthy and declining (or unhealthy) trees, we selected three sites, Witseorum, Youngsil and Sungpanak (Jindallebat). Antioxidant enzymes including Ascorbate peroxidase (APX) and Glutathione Reductase (GR), forest soil properties including soil texture, soil pH, organic matter, total nitrogen, available phosphate, cation exchange capacity, exchangeable cation content and nutrient contents in leaves of Abies koreana (Korean fir) trees were analyzed. There were no significant differences between healthy and declining trees in GR activity. However, seasonal difference in antioxidant enzyme activity was observed. GR activity was lower in June and August than that of September. Soil chemical and physical properties of each site showed a tendency that organic content, total nitrogen content, available phosphorus, cation exchange capacity and cation content were lower at the site of declining trees than the site of healthy trees.

Changes in Soil Properties Related to Soil Function due to Chemical Spills with Strong Acid and Base (강산 및 강염기 토양 유출에 따른 토양의 생태기능 관련 토양특성 변화)

  • Jeon, Inhyeong;Jung, Jae-Woong;Nam, Kyoungphile
    • Ecology and Resilient Infrastructure
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    • v.4 no.4
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    • pp.193-199
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    • 2017
  • In this study, changes of soil properties including soil texture, specific surface area, organic matter content, pH, cation exchange capacity and exchangeable cations content were investigated in response to strong acid or base accident. The properties changed significantly when the soil reacted with 10 M HCl or 1 M NaOH (i.e., when one gram of soil received 50 and 5 mmol of HCl or NaOH), respectively. When the soil reacted with 10 M HCl or 1 M NaOH solution, soil texture changed from sandy loam to loamy sand and specific surface areas decreased from $5.84m^2/g$ to 4.85 and $1.92m^2/g$, respectively. The soil organic matter content was reduced from 3.23% to 0.96 and 0.44%, and the soil pH changed from 5.05 to 2.35 and 10.65, respectively. The cation exchange capacity decreased from 10.27 cmol/kg to 4.52 and 5.60 cmol/kg, respectively. Especially, high concentrations of $Al^{3+}$ or $Na^+$ were observed in acidic or basic spills, respectively, which is likely to cause toxicity to terrestrial organisms. The results suggest that restoration of soil properties, as well as soil remediation, needs to be carried out to maintain the soil function in chemical spill sites.

pH Dependence on EC in Soils Amended with Fertilizer and Organic Materials and in Soil of Plastic Film House (비료와 퇴구비를 처리한 토양과 시설재배지 토양에서 토양의 EC에 따른 pH변화)

  • Kim, Yoo-Hak;Kim, Myeong-Sook;Kwak, Han-Kang
    • Korean Journal of Soil Science and Fertilizer
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    • v.38 no.5
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    • pp.247-252
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    • 2005
  • Soil pH is an intensity factor of releasing hydrogen ion which is buffered by aluminum. It depends on pH buffer capacity of Al whether soil pH is governed directly by cations or not. A study was conducted to elucidate the pattern of pH changes by soil EC. Fertilizer and three kinds of organic manures composed of cow and pig and fowl dropping and one kind of rice straw compost were added independently into upland sandy loam soil. This treated soils and four upland soils under plastic film house having different levels in electrical conductivity (EC) were incubated with field capacity at $30^{\circ}C$ for 5, 10, 20 and 40 days. Soil pH varied directly as the cations contained in organic materials according to degree of saturating pH buffer capacity (pBC) of sandy loam soil. pH of the soils under plastic film house was lowered by soil EC due to governing by overplus of cation beyond pBC.

낙동강 하구사주에서 갈대서식지역의 환경특성

  • Seong, Gi-Jun;Jang, Hye-Hyeon;Gwon, Hye-Ok;Jeong, Yong-Hyeon;Lee, Seok-Mo;Park, So-Yeong;Yeo, Un-Sang
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2007.05a
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    • pp.457-459
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    • 2007
  • 낙동강 하구의 맹금머리등, 백합등, 도요등의 세 개의 사주의 갈대분포와 관련된 토양 및 수질환경요인을 조사하였다. 대상지역의 갈대우점지역과 비우점지역에 대하여 토양 유기물 함량, 양이온 교환능력과 같은 토양 특성을 조사한 결과 이들 특성이 사주형성시기와 갈대의 분포유무와 관계있는 것으로 조사되었다. 유기물 함량은 갈대서식지역이 더 높게 나타났는데 이는 갈대의 성장으로 인한 토양의 유기물 축적 결과로 하구의 갈대가 사주의 토양환경에 영향을 미치고 있는 것으로 사료된다. 토양내 질소와 인 농도 역시 갈대우점지역에서 비우점지역에 비해 높게 나타났는데, 이는 토양 내 영양염류가 많은 곳을 갈대가 선호함과 동시에 갈대에 함유된 질소와 인성분이 토양에 집적된 두 가지 경우를 모두 고려할 수 있다. 수질조사 결과 현재 해수의 수질이 직접적으로 갈대의 분포에 영향을 주는 것은 아닌 것으로 나타났다. 하지만 토양양이온능력과 유기물 함량과 같은 토양특성 조사와 함께 고려하면 퇴적으로 인한 사주형성 및 토양유실과 갈대분포와 관련이 이는 사주에 형성된 식생이 사주의 영양물질 순환에 어떻게 영향을 미치는 가를 잘 설명해 주는 예라 할 수 있다.

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Influence of Gypsum, Popped Rice Hulls and Zeolite on Contents of Ca2+, Mg2+, Na+, K+ in Reclaimed Tideland Soils in Kyehwado (계화도 간척지에서 석고, 팽화왕겨 및 제올라이트 처리가 토양 중 양이온 함량에 미치는 영향)

  • Baek, Seung-Hwa;Lee, Sang-Uk;Lim, Hyo-Bin;Kim, Dae-Geun;Kim, Seong-Jo
    • Korean Journal of Environmental Agriculture
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    • v.28 no.1
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    • pp.25-31
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    • 2009
  • The effect of application of gypsum (G), popped rice hulls (PRH), and zeolite (Z) in exchangeable cations concentrations of reclaimed tideland soil in Kyehwado was investigated for 3 years from 2004 to 2006 in a pot experiment with bermuda grass (Cynodon dactylon). Treatments with three soil conditioner and with three applications were established with three replications; G1 (1,550 kg $10a^{-1}$), G2 (3,100), and G3 (6,200) for gypsum, H1 (1,000), H2 (2,000), and H3 (3,000) for PRH, and HZ1 (200), HZ2 (400), and HZ3 (800) for co-application of zeolite with PRH at the 1,500 kg $10a^{-1}$. At 60, 90, 120 days after treatment (DAT), exchangeable cations ($K^+$, $Na^+$, $Mg^{2+}$, and $Ca^{2+}$) were analyzed Gypsum application significantly decreased $k^+$, $Na^+$, $Mg^{2+}$ in the soil probably due to exchange and subsequent leaching of these cations by $Ca^{2+}$ from the gypsum applied. Overall, $K^+$ concentration was gradually decreased by continuous application of soil conditioners and was in the order of 2004>2005>2006 regardless of the kinds and application rate of soil conditioners. Comparing $K^+$ concentrations among the soil conditioners in the same year, its concentration was in the order of gypsum$Na^+$ concentration; i.e. $Na^+$ concentration was in the order of gypsum$\ll$PRH$Mg^{2+}$ also showed a similar pattern to $Na^+$. Gypsum application significantly increased $Ca^{2+}$ concentration and in the gypsum treated soil $Ca^{2+}$ concentration increased with years.

Comparison of Soil Ion, Plant Nutrient Contents and Growth in Quercus mongolica Forests in Seoul and Its Vicinity (수도권 일대 신갈나무 숲의 토양이온, 식물체 영양염류 함량 및 생장의 비교)

  • 김준호;임병선;김종욱
    • The Korean Journal of Ecology
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    • v.22 no.1
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    • pp.13-19
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    • 1999
  • To investigate and compare the effects of air pollution near Seoul on soil ion, plant nutrient contents and plant growth, 14 Quercus mongolica forests were studied from Mt. Namsan in Seoul to Mt. Maebongsan in Kangwon-Do along the line transect. Soil pH values decreased as approached to Seoul. Concentrations of basic cations such as exchangeable Ca/sup 2+/, Mg/sup 2+/ and Na/sup +/ and effective cation exchange capacity(ECEC) in forest soil decreased as approached to Seoul. Ca/sup 2+/ and Mg/sup 2+/ contents in l-year-old Q. mongolica twigs decreased, but their K/sup +/ and Na/sup +/ contents increased as approached to Seoul. Ca/sup 2+/ contents in l-year-old Q. mongolica leaves decreased, but their K/sup +/ and Mg/sup 2+/ contents increased as approached to Seoul. Length of l-year-old twigs generally decreased near Seoul. Tree-ring analyses of Q. mongolica trees in Mt. Namsan and Mt. Yebongsan showed that mean tree-ring width in Mt. Namsan was narrower than that of Mt. Yebongsan from early 1970's to late 1980's.

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