• Resources Recycling
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• v.20 no.3
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• pp.28-39
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• 2011

This review investigated theoretical principals and practical application examples on recirculation system of soil washing-wastewater treatment-treated water recycling. As for technologies which have attempted to remediating metals-contaminated soil in and around country, there are reactive barriers, encapsulation, solidification/stabilization, soil washing, and phytoremediation. Among those, in particular, this review covers soil washing technology which physicochemically removes contaminants from soils. The major drawbacks of this technology are to generate a large amount of wastewater which contains contaminants complexed with ligands of washing solution and needs additional treatment process. To solve these problems, many chemical treatment methods have been developed as follows: precipitation/coprecipitation, membrane filtration, adsorption treatment, ion exchange, and electrokinetic treatment. In the last part of the review, recent research and field application cases on soil washing wastewater treatment and recycling were introduced. Based on these integrated technologies, it could be achieved to solve the problem of soil washing wastewater and to enhance cost effective process by reducing total water resources use in soil washing process.

• Journal of the Korean GEO-environmental Society
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• v.9 no.4
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• pp.77-84
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• 2008

Soil purification theory is the method using the soil micro-organism like aerobic and anaerobic for treatment of wastewater. The soil has many kinds of micro-organism and it multiply as change of the environment. Unlikely other methods, the soil purification theory is adaptable to inflow water change; moreover, it can process the T-N, T-P without any special method and management. The top is covered with the improved soil which can remove the bad smell and is used for resting place according to planting the lawn. This study is focused on analysis of the treatment processing of wastewater comparing inflow with outflow water. As a results, removal rate of the processing the BOD, COD and SS is almost 90~100% and it is 60~80% in T-N, T-P.

• Journal of Conservation Science
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• v.35 no.2
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• pp.177-186
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• 2019

A Termiticide that is applied to the soil treatment method, one of the methods for preventing termites in Korea's wooden cultural properties, will be subjected to the leaching of the effective ingredient in treated soil by the moisture behavior of rain. As a result, termiticide is deteriorated and needs to be reprocessed, but the standards and evaluation methods are nonexistent in korea. Accordingly, a basic indoor evaluation measure was proposed for the evaluation of the effectiveness of the termiticide chamber and the calculation of the reprocessing period. First, avoidance and contact toxicity were assessed at two concentrations of the same termiticide as a method for assessing termiticide suitability. The evaluation of mortality revealed that the soil termiticide used in this experiment was non-repellent, and that death from contact was confirmed. Afterwards, artificial rainfall and soil penetration tests were conducted to determine efficacy of termiticide in soil and the approximate reprocessing period was calculated by comparing the weather data. Persistence evaluation revealed perforation by termites after continuous water exposure of more than about 160 to 170mm of water injection condition. Based on the results, compared with weather data for the last five years, the termiticide of concentration used in this experiment is expected to remain effective for about one year if treated after September. The purpose of this study was to provide basic data for the establishment of a manual for the selection of termiticide for soil treatment by calculating the efficacy for termite mortality and the duration of the leaching effectiveness by water behavior in soil.

• Proceedings of the KSEEG Conference
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• 2003.04a
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• pp.76-79
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• 2003

국내의 토양오염 공정시험방법에서는 Zn, Ni 추출시 산분해법에 가까운 방법을 사용하는 반면, Cd, Cu, Pb, $Cr^{6+}$ 추출시 0.1N HCl용액으로 산처리하여 1시간을 진탕한 후 이를 필터로 여과하여 분석용액을 추출하는 용출법을 사용하고 있다(환경부, 2001). 시료내에는 완충 물질이 존재하기 때문에 용출법 사용시 초기 pH 인 1(0.1N HCl)이 유지되지 않아 완충능력이 높은 토양의 경우 현재 국내 공정법상의 용출법이 중금속 오염정도를 추정하는데 적절치 않을 수 있다. (중략)

• Proceedings of the KSEEG Conference
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• 2002.04a
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• pp.25-27
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• 2002

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2005.04a
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• pp.219-222
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• 2005

유류로 오염된 토양에 대해 토양경작법(Landfarming)을 적용하여 복원효율을 평가하였다. 복원 초기에는 주로 휘발에 의한 오염물질의 저감이 이루어졌으며, 이 후 미생물성장에 필요한 토양뒤집기와 질소원 영양물질의 공급으로 인해 미생물수가 복원초기에 비해 약 200배 증가하면서 약 30여일 경과 후 초기 20,000ppm에서 복원목표인 TPH의 토양오염우려기준 2,000ppm의 이하인 1,910ppm으로 감소하였다. 시간이 경과할수록 탄소원 섭취기질 부족으로 완만한 오염물질 감소속도를 나타내면서 최종적으로 TPH를 측정한 결과 1,288ppm으로서 제거효율 94%이상을 나타내었다.

• Proceedings of the Korean Society of Organic Agriculture Conference
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• 2009.12a
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• pp.302-302
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• 2009

유기농업에서 유기물은 양분의 공급, 토양의 이화학성 개선, 토양의 생물학적 건전성 유지 등 중요한 역할을 한다. 토양의 생물학적 건전성은 토양의 생태계적 기능을 지속적으로 유지시키는 토양미생물이 관여하고 있다. 따라서 본 연구는 유기물의 장기연용에 따른 밭토양 미생물의 다양성을 비교 분석하였다. 여러 가지 유기자원을 동일한 기준으로 매년 동일 장소에 처리하였다. 사용된 유기자원은 가축분퇴비, 채종유박인 유기질비료, 볏짚으로만 퇴비화한 볏짚퇴비와 겨울철 휴한기에 헤어리베치를 재배하여 이듬해 봄에 예취한 후 토양에 환원한 녹비처리구, NPK구, 가축분퇴비를 혼용처리한 NPK퇴비군, 양분을 전혀 시용하지 않은 무비구 등 총 7처리구였다. 각각의 처리구에서 토양(0-20 cm)을 채취하여 배양성 토양미생물은 희석평판법으로 해당 선백배지에 시료를 도말 하여 조사하였고 비배양성 미생물은 토양으로부터 genomic DNA를 추출하여 세균의 16S rDNA를 증폭시킨 후 denaturing gradient gel electrophoresis (DGGE)를 수행하여 분석하였다. 주요결과를 요약하면 밭토양에 서식하는 토양미생물의 균수는 처리별간의 차이를 보였으며 유기물처리구가 화학비료처리구보다 높았다. DGGE 분석을 통해 유기물 처리에 따른 군집의 다양성을 살펴본 결과 Fig. 1에서 보는바와 같이 Gel 상에서 다양한 위치의 밴드를 확인할 수 있었고 처리별로 특이 밴드가 있음을 확인할 수 있었다. Fig. 1에서 얻은 DGGE profile상의 밴드 강도와 수를 비교하여 Fig 2와 같은 dendrogram을 나타낼 수 있었다.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.10
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• pp.1072-1080
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• 2005

The extraction characteristics of heavy metals(HM) from a contaminated soil at existing lead smelters were investigated with ethylene diamine tetraacetic acid(EDTA), citrate and HCl as washing solutions. EDTA was more effective for Pb than for other heavy metals. As the mol ratio of EDTA/HM increased, the removal efficiency of heavy metals became higher. When the mol ratio of EDTA/HM approached to 6.5, it removed Pb most effectively. Citrate was effective especially in extracting Zn. The removal efficiency of HCl was comparatively high in almost all heavy metals, and at 0.3N concentration it was the highest. After soil washing process by the use of EDTA, the great part of exchangeable fractions and most of heavy metals of weakly adsorbed like carbonate fraction were extracted. For washing with citrate and HCl, four heavy metals showed the similar exchange of chemical partitioning and the exchangeable fractions of Pb which has weakly adsorbed to soil were more increased than before the process. As removal efficiency of citrate washing process depends upon the distribution of non-detrital fractions, so it can be contended that only the amount of non-detrital fractions could be removed from all the heavy metal content. EDTA and HCl could remove most of non-residual fractions in all heavy metals except Zn. As a result of EDTA washing, toxicity characteristic leaching procedure(TCLP) concentration of the processed soil met the USEPA Pb limit of 5.0 mg/L.

• The Korean Journal of Pesticide Science
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• v.18 no.4
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• pp.258-268
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• 2014

The test method of aerobic transformation in soil has established based on international test guideline (OECD TG 307). And then, the case study was conducted with [$^{14}C$]butachlor. Butachlor is commonly used herbicide in Korea. [$^{14}C$]Butachlor was treatrd $6.83mgKg^{-1}$ in loamy soil. The treated soil was incubated in flow-through system for 60 days. The mass balance of applied radioactivity (AR) ranged from 91.1 to 95.5% and from 93.0% to 97.7% for non-sterile and sterile soils, respectively. In non-sterile soil, the concentration of [$^{14}C$]butachlor was declined from 94.4% AR at 0 day to 8.4% AR at 60 days after treatment. 2-Chloro-2',6'-diethylacetanilide was the major degradation product detected in soil extract. The calculated $DT_{50}$ and $DT_{90}$ of butachlor were 10.4 days and 34.6 days, respectively. $^{14}CO_2$ and non-extractable soil residue were increased up to 3.5% and 43.5% AR at 60 DAT. There is no significant decrease of the [$^{14}C$]butachlor through the incubation period in sterile soil.

• Journal of Biosystems Engineering
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• v.22 no.4
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• pp.479-486
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• 1997

식물 뿌리에 대한 지식은 식물-토양 사이의 관계 이해, 토양의 호율적 관리, 식물에 의한 영양분과 수분의 흡수 과정 이해, 그리고 토양 등급 지수를 만드는데 있어서 아주 중요하다 식물 뿌리에 관한 정보를 정량화하기 위하여는 뿌리를 흙으로부터 씻어내고 뿌리의 길이, 표면적, 중량과 같은 식물 뿌리의 특성을 측정하여야 한다 하지만 이렇게 뿌리를 씻어 낸 다음 뿌리의 특성을 측정하는 기존의 방법을 이용할 경우 막대한 시간과 노동력이 필요하여 뿌리에 관한 많은 양의 정보를 얻는데 큰 어려움이 있다. 이 연구에서는 식물 뿌리를 관측하는데 필요한 시간과 노동력을 줄일 수 있는 식물 뿌리 측정법을 세선 작업과 자외선 명암 증진법을 이용한 영상 정보 처리 장치를 바탕으로 하여 개발하였다. 개발된 화상 정보 처리 장치를 이용하여 옥수수 뿌리의 길이를 재었을 때 기존의 뿌리 길이 측정 방법보다 2.5 배 발리 측정할 수 있는 것으로 나타났다.