• Journal of Korean Society of Environmental Engineers
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• v.22 no.11
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• pp.2007-2016
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• 2000

After kaolin clay was compulsorily contaminated with $Sr^{2+}$ ion. the remediation characteristics by electrokinetic method were analyzed. In the first experiment. NaCl solution was used as an electrolyte to raise the electric field strength. After remediation for 0.8 days. the pH of the cathode side of the soil column was elevated from 4.0 to 11.7. and thereby precipitation $Sr(OH)_2$, started to be formed in the side. Therefore. efficiency of soil remediation was reduced significantly and the 32% of total $Sr^{2+}$ ion in the column was decontaminated in 6.7 days. In the second experiment. ethanoic buffer was injected in the soil column and $CH_3COOH$ was continuously inputted in cathode reservoir to restrain the pH elevation. The pH of the cathode side of the soil column was only ascended from 4.0 to 6.0 in 3.8 days and $Sr(OH)_2$ was not formed. The 21% of total $Sr^{2+}$ in the soil column was decontaminated in 0.6 days. and the 33% of total $Sr^{2+}$ in 0.9 days. and the 84% of total $Sr^{2+}$ in 1.6 days. and the 92% of total $Sr^{2+}$ in 2.5 days. and the 97% of total $Sr^{2+}$ in 3.8 days. Meanwhile. the residual concentrations in the column calculated by the developed model were similar to those by experiment.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2000.11a
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• pp.334-335
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• 2000

울산지역의 고정배출 및 이동배출원과 같은 각종 배출원에서 발생되는 대기오염물은 건물, 도로, 토양 각종 식물 및 수목, 강, 호수, 바다 등과 같은 아주 다양한 수용체로 침적되고 있다. 최근의 연구에 의하면 울산지역은 대단위 산업공단을 가지고 있는 대형산업도시이므로 대기중의 중금속 농도는 타 지역에 비하여 매우 높고 상당한 정도의 산성비도 내리고 있는 것으로 나타났다. 따라서 본 연구는 울산지역의 수목의 잎에 침적되어 있는 중금속을 산성비수준의 pH로 조절한 산성용액으로 용출하여 그 성분을 분석하여 각종 대기 오염물이 나무를 비롯한 식물에 침적되는 정도를 각 특성지역별로 비교ㆍ분석하였다. (중략)

• Korean Journal of Soil Science and Fertilizer
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• v.16 no.4
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• pp.318-324
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• 1983

Electrochemical properties of Georgia kaolinite in aqueous suspension were studied by ion adsorption, potentiometric titration, and electrophoretic mobility measurements. Kaolinite in 0.001 M and 0.1 M NaCl solution showed qualitatively both pH independent and pH depender negative and positive charges through pH range 2.5-11.0 when dissolved aluminum ions from kaolinite were considered as well as $Na^+$ and $Cl^-$ as index ions. Electrophoretic mobilities (EM) of 0.02 wt. % kaolinite suspension in distilled water and 0.001 M NaCl solution were approximately constant against mobility measuring time consumed in the electrophoresis cell at different pH values, and isoelectric points(IEP) were around pH 4.7. EM values in 0.1 M NaCl solution were positive and constant against mobility measuring time below pH 4; but above pH 4, EM values were negative for the first 10 seconds followed by positive values which became approximately constant through stepped changes after 10 minutes. Hydrated cations may bind to the six- member oxygen ring sites having multiple partial negative charges on the exterior tetrahedral layer surface by both electrostatic and hydrogen bonding force while hydrated anions bind to the partially positively charged hydrogen atoms on the exterior octahedral layer surface. Parts of the aluminol groups on the exterior octahedral layer surface as well as edge faces may be involved in complex reactions and have both anion and cation exchange capacities in the electrolyte solution above pH 4.

• Korean Journal of Environmental Agriculture
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• v.24 no.2
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• pp.132-138
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• 2005

Objective of this research was to evaluate the fate of nitrogen and phosphorous in hydroponic waste solution from the plastic film house cultivation applied to the upland soil by column leaching and field experiment. The pH and EC of leachate were decreased by the reaction with the upland soil in the column leaching experiment. The EC and concentrations of $H^+,\;K^+,\;and\;{NH_4}^+$ of leachate were decreased as the column length (soil depth) was increased. But these were increased as the amounts of the hydroponic waste solution were increased field experiment growing red pepper (Capsicum annum L.) to monitor the nutrients movement using ion exchange resin capsule demonstrated that the nutrient concentration of soil solution was increased in the orders of $PO_4-P. Nitrate concentration of resin capsule inserted into the soil was relatively higher than other nutrients $(NH_4-N\;and\;PO_4-P)$ at the 45 cm of soil depth. The overall results demonstrated that the hydroponic waste solution could be recycled as plant nutrients to enhance fertility of soils. But nitrate leaching was a major factor for safe use of the hydroponic waste solution in soil.

• Journal of The Korean Society of Grassland and Forage Science
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• v.12 no.1
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• pp.1-5
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• 1992

The purpose of this experiment was to determine the effect of soil phosphorus level on plant length, dry matter yield and competition in annual and perennial plants.The effect of phosphorus fertilizer on the plant length and dry matter yield was low in the perennial plant of Miscanthus sinensis, SaSa palmata and ilrtemlsia princeps, but was high in the annual plant of Polygonwn thunbergii and Echinochloa crus-galli.The plant length, density and dry matter yield of Italian ryegrass in individual natural community did not depend on relative photosynthetic photon flux density but on total and available phosphorus of soil.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.04a
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• pp.168-171
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• 2003

연속주입추적자시험이 실시된 현장사이트의 규모는 4.5m$\times$4.5m$\times$6.0m 정도이다. 시험 사이트내에서 실시된 추적자시험은 주입공(Pl)에서 Rhodamine WT 50ppm 용액을 1.8$\ell$/min의 주입율로 6일 동안 연속적으로 주입함과 동시에 관측공(P2, P3, Il, I2, I3)에서 일정한 시간간격으로 지하수를 채수하여 추적자농도를 산출하였다. 시험결과, 지하수면 하부를 포함하는 관측공(P2, P3)의 최대추적자농도는 초기주입농도의 10% 정도이며, 지하수면 상부에 위치한 지하수공(Il, I2, I3)들에서의 최대추적자농도는 초기농도의 75% 정도로서 추적자의 농도차이가 상대적으로 매우 크게 나타났다. 본 연구에서는 자유면대수층내에서 포화대를 포함한 관측공과 비포화대만을 포함한 관측공에서의 수리분산특성에 대해 비교.분석한 결과, 오염물이 연속적으로 토양에 유입되는 경우 비포화대 구간에서는 이류기작에 의한 농도희석이 거의 없으므로 오염물농도가 매우 클 것으로 판단된다.

• Korean Journal of Soil Science and Fertilizer
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• v.45 no.6
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• pp.1108-1113
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• 2012

The changes of soil organic carbon (SOC) content in paddy soils (sandy loam) were assessed from data of the 59 years fertilization plots in which the continuous rice cropping experiment started in 1954. The treatments were no fertilization(no fert.), NPK fertilization (N, NPK), NPK plus rice straw compost (NPK+C), and NPK plus rice straw compost, silicate fertilizer and lime (NPK+CLS). After 41 years, SOC content in NPK+C and NPK+CLS treatment in surface soils (0~15 cm) reached at the highest, followed by maintaining a plateau level for 8 years. After 51 years, they showed a tendency to decrease. Peak concentrations of soil organic carbon were $20.1g\;kg^{-1}$ in NPK+CLS, $19.1g\;kg^{-1}$ in NPK+C, $13.3g\;kg^{-1}$ in NPK, $11.9g\;kg^{-1}$ in N, and $11.6g\;kg^{-1}$ in control. Dissolved organic carbon(DOC) contents in surface soil solution were about 2.3 times higher in NPK+C than that in NPK+CLS. Therefore, SOC in subsurface soil(15~30 cm) was greater in NPK+C than the other treatments. These results indicate that continuous application of rice straw compost and silicate fertilizer affected significantly on the level of SOC in surface soils, subsurface soils, and soil solutions. Thus, the combined applications of NPK fertilizers with organic compost and silicate as a soil amendment are recommended as the best fertilization practice for soil carbon accumulation, environment conservation, and enhancement of soil fertility status in the continuous rice cropping system.

• Journal of Applied Biological Chemistry
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• v.58 no.2
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• pp.157-174
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• 2015

Stabilization of metals in contaminated soils using various waste materials has been reported. Alkaline materials (limes, shells, industrial byproducts, etc.), phosphorous (P) containing materials (animal bones, phosphate rock, etc.), organic materials (composts, manures, biochars, etc.) and others (zerovalent iron, zeolite, etc.) were widely evaluated to ensure its effectiveness/applicability of stabilization of metals in soils. Stabilization mechanisms of those materials above were partially revealed, but the related literatures are still lacked and not sufficient for approaching to long-term stability/applicability in the field. The aims of this review are to summarize current knowledge of metal stabilization in contaminated soils using various waste materials and to suggest a direction for future field research.

• Analytical Science and Technology
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• v.13 no.3
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• pp.357-367
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• 2000

The polycyclic aromatic hydrocarbon (PAH) content in sewage sludge and in farm soils were determined by gas chromatography linked to mass spectrometry (GC/MS) with use 2-ethylantracene as internal standards. Twelve PAH were identified in both sludges with naphthalene ($0.78{\mu}g/g$) being the most predominant in industrial sludge and pyrene ($0.26{\mu}g/g$) in municipal sludge. The total PAR content in industrial sludge and in municipal sludge were $1.74{\mu}g/g$ and $1.19{\mu}g/g$ respectively. PAH were contained in paddy soils and the concentration were very low in the range of $0.01-0.04{\mu}g/g$. The total PAH content in industrial and in municipal sludge were about 9.2 times and 6.3 times greater than in paddy soils ($0.19{\mu}g/g$).

• Journal of Korean Society of Environmental Engineers
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• v.22 no.1
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• pp.33-42
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• 2000

Adsorption onto the surfaces of solid particles is a well known phenomenon that causes the retardation effect of heavy metals in soils. For adequate remediation of soil and groundwater contamination, it is important to investigate the mobility of heavy metals that largely depends on pH conditions in the soil water since adsorption of heavy metals is pH-dependent. In this study, we investigated the transport of Zn ion under various pH conditions in a sandy soil by conducting batch and column tests. The batch test was performed using the standard procedure of equilibrating fine fractions collected from the soil with eleven different initial $ZnCl_2$ concentrations, and analysis of Zn ion in the equilibrated solutions using ICP-AES. The column test consisted of monitoring the concentrations of soil solutions exiting the soil column with time known as a breakthrough curve (BTC). We injected respectively $ZnCl_2$ and KCl solutions with the concentration of 10 g/L as a tracer in a square pulse type under three different pH conditions (7.7, 5.8, 4.1) and monitored the flux concentration at the exit boundary using an EC meter and ICP-AES. The resident concentration was also monitored at the 10cm-depth by Time Domain Reflectometry (TDR). The results of batch test showed that ion exchange process between Zn and other cations (Ca, Mg) was predominant. The retardation coefficients obtained from adsorption isotherms (Linear, Freundlich, Langmuir) resulted in the various values ranging from 1.2 to 614.1. No retardation effect but ion exchange was found for the BTCs under all pH conditions. This can be explained by the absence of other cations to desorb Zn ion from soil exchange sites under the conditions of ETC experiment imposing blank water as leachate in steady-state flow. As pH decreased, the peak concentration of Zn increased due to the competition of Zn with hydrogen ions ($H^+$) and the concentrations of other cations decreased. The peak concentration of Zn was increased by 12.7 times as pH decreased from 7.7 to 4.1.