• Journal of Korean Society of Forest Science
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• v.86 no.3
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• pp.324-333
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• 1997

The research has been made for the effects of the pollution by the abandoned coal mine drainage on the physical and chemical properties of soil, stream sediment and soil water. The soils overspreaded by the abandoned coal don't develop solum and the bulk density is $1.83g/m^3$, compared with $1.14-1.38g/m^3$ in the other forest soils. The soil pH range in coal bearing region ie, from 4.01 to 4.11 and non-coal bearing soil range is from 5.03 to 5.13. Heavy metals such as As, Cr, Ni, Mo and Ba of coal bearing soils and polluted stream sediments have larger concentration than those of non-coal content and non-polluted. Especially As and Mo concentrations are largely high in coal bearing. The relative ratios $K_2O/Na_2O$ of geochemical elements are higher in coal bearing soil and polluted stream sediments than those of non-coal bearing soils and non-polluted stream sediments as well as black shales of the Changri Formation. However, $MgO+Fe_2O_3+TiO_2/CaO+K_2O$ are the opposite trends, so that the ratios are lower in the polluted regions. The soil water pHs in the polluted regions are the strong acid(pH3.4-4.2) and buffer capacity of the polluted soil is low because canons such as $Na^+$, $K^+$, $Mg^{+2}$are leached by the acidification.

• Journal of Korean Society of Forest Science
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• v.87 no.2
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• pp.188-193
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• 1998

Soil pH change is an important factor which determines soil chemical properties. It is an indicator of the effect of urban environmental pollution on soils and plant growth. The objective of this study was to assess the effect of air pollution on the soil of Seoul urban forests during the course of the air pollution being dipersed toward suburb area. Study sites were divided into four sections of concentric circles with 5km interval. Soil samples were collected from A and B horizons in the urban forests, and analyzed for soil pH, soil buffer capacity, cation exchange capacity, and base saturation. Soil pH ranged from 3.96 to 5.08 for A horizon and from 4.10 to 5.25 for B horizon, which were not significantly different among the sections. However, there was a trend of soil pH lowered at the sections close to the urban center. Soil buffer capacity was lower at 0-5km and 5-10km sections compared to that at the outer sections. Cation exchange capacity and base saturation were not different significantly among the sections. Following the pattern of air pollutants being dispersed from urban center to suburb, soil acidification was observed at the urban forests in Seoul area. Low level of soil buffer capacity toward the urban center was an indicator of soil acidification at the urban forests.

• Journal of Soil and Groundwater Environment
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• v.13 no.5
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• pp.8-19
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• 2008

The physicochemical properties of soils having high uranium content, located around Duckpyungri in Korea, were investigated and the lab scale soil washing experiments to remove uranium from the soil were preformed with several washing solutions and on various washing conditions. SPLP (Synthetic Precipitation Leaching Procedure), TCLP (Toxicity Characteristic Leaching Procedure), and SEP (Sequential Extraction Procedure) for the soil were conducted and the uranium concentration of the extracted solution in SPLP was higher than Drinking Water Limit of USEPA (30 ${\mu}g$/L), suggesting that the continuous dissolution of uranium from soil by the weak acid rain may generate the environmental pollution around the research area. For the soil washing experiments, the uranium removal efficiency of pH 1 solution for S2 soil was about 80 %, but dramatically decreased as pH of solution was > 2, suggesting that strong acidic solutions are available to remove uranium from the soil. For solutions with 0.1M of HCl and 0.05 M of ${H_2}{SO_4}$, their removal efficiencies at 1 : 1 of soil vs. washing solution ratio were higher than 70%, but the removal efficiencies of acetic acid, and EDTA were below 30%. At 1 : 3 of soil vs. solution, the uranium removal efficiencies of 0.1M HCl, 0.05 M ${H_2}{SO_4}$, and 0.5M citric acid solution increased to 88%, 100%, and 61% respectively. On appropriate washing conditions for S2 soil such as 1 : 3 ratio for the soil vs. solution ratio, 30 minute for washing time, and 2 times continuous washing, TOC (Total Organic Contents) and CEC (Cation Exchange Capacity) for S2 soil were measured before/after soil washing and their XRD (X-Ray Diffraction) and XRF (X-Ray Fluorescence) results were also compared to investigate the change of soil properties after soil washing. TOC and CEC decreased by 55% and 66%, compared to those initial values of S2 soil, suggesting that the soil reclaimant may need to improve the washed soils for the cultivated plants. Results of XRF and XRD showed that the structural change of soil after soil washing was insignificant and the washed soil will be partially used for the further purpose.

• Journal of Soil and Groundwater Environment
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• v.10 no.5
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• pp.45-51
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• 2005

The sorption/desorption characteristics of phenanthrene on the natural manganese oxide (NMD) were investigated in the presence of phenolic compounds. 4-chlorophenol (4-CP) was effectively oxidized by NMD catalyzed reaction and transformed into humic-like macromolecular compound through inter-or cross-coupling reaction between byproducts. As 4-CP was degraded with time, sorbed amount of phenanthrene on NMD was significantly increased, resulting from the formation of oxidative coupling products. These results imply that NMD can be used for simultaneous treatment of phenolic contaminants and polycyclic aromatic hydrocarbons (PAHs) in soils, sediments, or water. Also, sorbed phenanthrene on NMD in the presence of 4-CP showed high degree of desorption resistance, indicating that sequestration process of phenanthrene was ongoing with time.

• Journal of Korea Soil Environment Society
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• v.2 no.3
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• pp.69-80
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• 1997

This investigation was conducted to provide information for characteristics of environmental pollution by the heavy metals from the abandoned gold mine in order to characterize the distribution patterns and environmental damages of the contaminants to the surrounding environment. Through analysis of CN, Cd, Cu, Pb, Zn, As, Cr, and Hg in a mine tailings, paddy soils, and stream sediments, the physico-chemical properties of the mine tailings and paddy soils were measured. The pH's were 5.4, 8.4 for the paddy soil and mine tailing, respectively. The maximum contents of CN, Pb, Cd, and As the in mine tailing were 99.98, 1,752.72, 31.88, and 298.50 mg/kg, respectively. The amounts of these ions were higher than the standard level of industrial area in Korea. The average content of CN and heavy metals in the paddy soils were higher than the background level of heavy metals in the unpolluted paddy soils around the mine. Especially, the contents of heavy metals in the paddy soils along the adjacent stream were higher compared to the paddy soil that was not influenced by the mine tailings. The contents of CN and heavy metals in the stream sediment close to the mine area were similar to those of the mine tailings, but decreased along the distance of the stream farther away from the tailings that was the source of these pollutants.

• Journal of Soil and Groundwater Environment
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• v.7 no.3
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• pp.71-77
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• 2002

This research was carried out from 2001. 4 until 2001. 5 in order to examine the level of soil contamination in the vicinity of Nanjido. The sampling was done at near the Nanjido soil. At the each sampling site we did the sampling at different depth- surface(0~15cm deep), 1m deep, 2m deep, 3m deep. The contamination of Cd, Cu, Pb, As, $Cr^{+6}$, and Hg were tasted and analysed by spectra AA. The examination showed that the average concentration level of the entire sampled soil was Cd, 0.229mg/kg, Cu 8.349mg/kg, Pb : 11.083mg/kg, As : 0.298mg/kg, $Cr^{+6}$ : 0.124mg/kg, and Hg : 0.134mg/kg. The concentration level of at the depth of 0-l5cm, came out to be Cd : 0.305mg/kg, Cu : 8.464mg/kg, Pb : 11 383mg/kg, As : 0.128mg/kg, $Cr^{+6}$ : 0.153mg/kg, and Hg : 0.092mg/kg. It shows that in the cases of Cd and C $r^{+6}$ the average concentration level of the whole sampled soil was about 80% of that of 0-l5cm depth. And as for Hg and As. the average concentration level of the entire sampled soil came out to be approximately twice as high as the sample soil from the depth surface, As for Cu and Pb, there was not much difference between the entire samples average concentration level and the concentration level of surface. It was hard to find much relationship between the depth of each site where sampling was done and the level of concentration, the concentration level of Pb and Cu at the sampling site C and E was quite high, which suggests that it has been affected by the polluted the hyang-dong stream and fill random up waste.

• Proceedings of the Korea Water Resources Association Conference
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• 2006.05a
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• pp.483-487
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• 2006

본 연구는 비점오염원에 의한 수질오염현상을 억제하기 위한 수변지역의 관리기법 중 하나인 식생여과대를 효과적으로 설치하기 위하여 식생에 의한 오염물질의 저감능력을 파악하고 효율적 설치방안을 모색하기 위하여 수행되었다. 연구결과 T-N과 T-P의 깊이별 오염물질 저감효과는 나대지에서 표면유출이 각각 17.6%, -23.9%, 단면유출이 각각 51.7%, 91.0%, 하부유출이 각각 38.4%, 89.3%인 것으로 나타나 표면층을 통한 유출보다는 토양층에 침투될수록 오염물질의 저감효과가 높아지는 것으로 나타났다. 잔디로 표면층을 식재한 실험에서는 표면, 단면, 하부유출에서의 T-N이 각각 16.0%, 57.1%, 38.4%의 오염물질 저감효과를 보였고, T-P의 저감효과는 각각 -9.7%, 83.6%, 88.8%인 것으로 조사되었다. 또한 돌미나리로 표면층을 식재한 실험에서는 표면, 단면, 하부유출에서의 T-N 처리효율이 각각 -2.6%, 62.1%, 71.2%로 나타났으며, T-P는 각각 -7.2%, 94.5%, 84.5%인 것으로 조사되었다. 결론적으로 식생을 한 경우 전체적으로 오염물질의 저감효율이 비교적 안정되게 유지되는 것으로 나타났으나, T-P의 표면층을 제외하면 전체적인 저감효과에 크게 영향을 미치지 않은 것으로 판단된다. 그러나 일반적으로 알려져 있는 식생에 따른 오염물 저감효과에 대한 순기능 즉 토양입자의 침식방지, 토양용액의 저류작용 및 공극확대에 따른 침투능력 증대, 토성의 개량 등과 같은 기능을 무시할 수 없으므로 오염저감효과를 극대화하기 위해서는 처리대상이 되는 하천유역의 자생적 식생을 보다 효과적으로 활용할 수 있는 방안마련이 비용적 측면이나 생태 보존적 측면에서 유리할 것으로 판단된다.one)을 설치하는 대책이 필요하다. 저수지 관리를 효과적으로 수행하기 위해서는 저수지 내부의 탁도 거동을 정확히 예측할 수 있어야 한다. 따라서 추후 동수역학 및 열역학에 기초한 3차원 수치모형 연구와 성층흐름에 정밀한 밀도류 실험연구 및 이에 대한 적용이 필요할 것으로 판단된다.함으로써 정보의 질적보장과 정보전환의 표준화방안을 제시하는 정보분석시스템이다.이용, 수자원의 지속적 확보기술의 특성에 따른 4개의 평가기준과 26개의 평가속성으로 이루어진 2단계 기술가치평가 모형을 구축하였으며 2개의 개별기술에 대한 시범적용을 실행하였다.하는 것으로 추정되었다.면으로의 월류량을 산정하고 유입된 지표유량에 대해서 배수시스템에서의 흐름해석을 수행하였다. 그리고, 침수해석을 위해서는 2차원 침수해석을 위한 DEM기반 침수해석모형을 개발하였고, 건물의 영향을 고려할 수 있도록 구성하였다. 본 연구결과 지표류 유출 해석의 물리적 특성을 잘 반영하며, 도시지역의 복잡한 배수시스템 해석모형과 지표범람 모형을 통합한 모형 개발로 인해 더욱 정교한 도시지역에서의 홍수 범람 해석을 실시할 수 있을 것으로 판단된다. 본 모형의 개발로 침수상황의 시간별 진행과정을 분석함으로써 도시홍수에 대한 침수위험 지점 파악 및 주민대피지도 구축 등에 활용될 수 있을 것으로 판단된다. 있을 것으로 판단되었다.4일간의 기상변화가 자발성 기흉 발생에 영향을 미친다고 추론할 수 있었다. 향후 본 연구에서 추론된 기상변화와 기흉 발생과의 인과관계를 확인하고 좀 더 구체화하기 위한 연구가 필요할 것이다.게 이루어질 수 있을 것으로 기대된다.는 초과수익률이 상승하지만, 이후로는 감소하므로, 반전거래전략을 활용하는 경우 주식투자기간은 24개월이하의 중단기가 적합함을 발견하였

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.04a
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• pp.168-171
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• 2003

연속주입추적자시험이 실시된 현장사이트의 규모는 4.5m$\times$4.5m$\times$6.0m 정도이다. 시험 사이트내에서 실시된 추적자시험은 주입공(Pl)에서 Rhodamine WT 50ppm 용액을 1.8$\ell$/min의 주입율로 6일 동안 연속적으로 주입함과 동시에 관측공(P2, P3, Il, I2, I3)에서 일정한 시간간격으로 지하수를 채수하여 추적자농도를 산출하였다. 시험결과, 지하수면 하부를 포함하는 관측공(P2, P3)의 최대추적자농도는 초기주입농도의 10% 정도이며, 지하수면 상부에 위치한 지하수공(Il, I2, I3)들에서의 최대추적자농도는 초기농도의 75% 정도로서 추적자의 농도차이가 상대적으로 매우 크게 나타났다. 본 연구에서는 자유면대수층내에서 포화대를 포함한 관측공과 비포화대만을 포함한 관측공에서의 수리분산특성에 대해 비교.분석한 결과, 오염물이 연속적으로 토양에 유입되는 경우 비포화대 구간에서는 이류기작에 의한 농도희석이 거의 없으므로 오염물농도가 매우 클 것으로 판단된다.

• Economic and Environmental Geology
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• v.37 no.1
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• pp.35-48
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• 2004

This paper provides a comprehensive overview of geochemical approaches for investigating and assessing heavy metal contamination in abandoned mine sites. Major sources of contaminants at the abandoned mine sites are mine water, waste rocks, tailings, and chemicals used in beneficiation and mineral processing. Soil, sediment, surface and ground water, and ecological system can be contaminated by heavy metals, which are transported due to erosion of mine waste piles, discharge of acid mine drainage and processed water, and dispersion of dust from waste rocks and tailings. The abandoned mine sites should be characterized using various methods including chemical analysis, mineralogical analysis, acid generation prediction tests, leaching/extraction tests, and field tests. Potential and practical environmental impacts from the abandoned mines should be assessed based on the site characterization.

• Journal of Soil and Groundwater Environment
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• v.7 no.4
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• pp.24-30
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• 2002

The laboratory adsorption batch tests were performed to investigate the adsorption characteristics of Pb on kaolinite. The characteristics such as adsorption equilibrium time, adsorption capacity, adsorption isotherm were studied, and also the effects of pH and the mixing ratio on the adsorption of Pb on kaolinite were investigated. Test results show that the adsorption equilibrium state was reached within 24 hours, and the adsorbed amount of Pb increased, but the adsorption efficiency over the initial concentration of 198 mg/l decreased, with increasing the initial concentration of Pb. And the adsorption constant, 1/n was obtained 0.9584 by Freundlich isotherm equation. Regardless of the initial concentration of Pb. the adsorbed amount of Pb as well as the adsorption efficiency were increased with increasing pH values and converged to a certain constant value above 8 of pH values. And also the adsorbed amount of Pb increased with the mixing ratio, but its efficiency increased with the mixing ratio up to 8 and then showed the decreasing tendency above that.