• KSBB Journal
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• v.18 no.6
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• pp.448-454
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• 2003

We studied on the removal of toluene vapors in a lab-scale biofilter. There are three biofilters packed with reticulated polyurethane foams of different porosities of 15, 25, 45 PPI (Pore Per Inch) as media. A toluene-degrading strain (Pseudomonas Putida KCCM 11348, ATCC 12633) was naturally immobilized on the filter media by circulating the culture media. Three biofilters were operated under different sets of continuous experiments, varying both the design and operation parameters such as the inlet toluene concentration and the flow rate. Maximum elimination capacity of 115.5g/㎥hr of biofilter packed with foams of 25 PPI was obtained for toluene degradation. The effect of operating conditions such as flow rate, inlet toluene concentration and porosity on the performance of the biofilter was investigated.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.37 no.12
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• pp.1541-1546
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• 2013

The stress concentration of lock-claws, which are one of the important parts for pneumatic fitting for a flexible tube connection, was investigated by finite element simulation. In this study, the generation of the local plastic deformation was predicted when the tube was hooked up to a pneumatic fitting in order to disperse the stress concentration, and design optimization was carried out using the Taguchi method. For the optimization, the outer width, bending angle, and inner radius of the lock-claws are used as main variables. As a result, their respective contribution ratios are revealed as 81.3%, 10.9%, and 1.5%. The ratio of the total stress distribution was improved by 4% compared with the initial design of the lock-claws.

• Journal of Korea Water Resources Association
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• v.53 no.2
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• pp.141-154
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• 2020

The accidents of toxic chemical spill into rivers are increasing in recent years due to expansion of heavy industries in Korea. In order to respond to the chemical spills, accident response systems have been established for both main rivers and tributary rivers. However, since these accident response system adopted the water quality models imported from the foreign countries, it is difficult to acquire the model parameters and to calibrate and validate the water quality models. Therefore, this study developed a depth-averaged two-dimensional river water quality model to analyze the behavior of hazardous chemicals in rivers and proposed an efficient simulation execution framework by identifying the significant reaction mechanisms considering the characteristics of the toxic chemicals. The depth-averaged two-dimensional river water quality model CTM-2D was upgraded by adding reaction terms representing mechanisms of the adsorption, desorption, and volatilization of toxic chemicals. In order to verify the model, the analytical solution was compared with the numerical solution, and results showed that the error was less than 0.1%. In addition, the model was applied to a virtual scenario which is a water pollution accident at the confluence of the Nakdong River - Kumho River, and model results showed that an efficient simulation could be carried out by activating only significant reactions which were assessed by the sensitivity analysis.

• Membrane Journal
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• v.5 no.1
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• pp.35-43
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• 1995

For several years lots of attempts have been made to establish the liquid membrane-based techniques for separations of gas mixtures especially containing carbon dioxide. A more effective system to separate $CO_{2}$ from flue gases, a circulatory hollow-fiber membrane absorber(HFMA) consisting of absorption and desorption modules with vacuum mode, has been considered in this study. Gas-liquid mass transfer has been modeled on a membrane module with non-wetted hollow-fibers in the laminar flow regime. The influence of an absorbent flow rate on the separation performance of the circulatory HFMA can be predicted quantitatively by obtaining the $CO_{2}$ concentration profile in a tube side. The system of $CO_{2}/N_{2}$ binary gas mixture has been studied using pure water as an(inert) absorbent. As the absorbent flow rate is increased, the permeation flux(i.e., defined as permeation rate/membrane contact area) also increases. The enhanced selectivity compared to the previous results, on the other hand, shows the decreasing behavior. It has been found obviously that the permeation flux depends on the variations of pressure in gas phase of desorption module. From an accurate comparison with the results of conventional flat sheet membrane module, the advantageous permeability of this circulatory HFMA can be clearly ascertained as expected. Our efforts to the theoretical model will provide the basic analysis on the circulatory HFMA technique for a better design and process.

• Composites Research
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• v.35 no.2
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• pp.98-105
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• 2022

In this study, polyvinyl alcohol (PVA)/graphene oxide (GO)/iron oxide (Fe₃O₄) magnetic microgels were prepared using a microfluidic approach and the dye adsorption capacity of the microgels was confirmed. The adsorption capacity (q_e) of the gels was evaluated by varying the dye concentration, pH, and contact time with the microgels. The dyes used in this work were methylene blue (MB), crystal violet (CV), and malachite green (MG), and microgels showed the highest adsorption capacity (191.1 mg/g) in methylene blue. The microgels exhibited the highest adsorption capacity in the dye aqueous solution at pH 10 due to the presence of atomic nitrogen ions (N⁺) on the dye molecules. The adsorption isotherm studies revealed that the Langmuir isotherm is the best fit isotherm model for the dye adsorption on the microgels, indicative of monolayer adsorption. The kinetic analysis exhibited that the pseudo-second order model fits better than the pseudo-first order model, confirming that the adsorption process is chemisorption. In addition, the magnetic microgels showed good reusability and recovery efficiency. It was confirmed that the adsorption capacity of the gels maintains more than 70% of the initial capacity after 5 times of cycle experiments.

• Journal of the Korean Chemical Society
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• v.55 no.3
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• pp.454-462
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• 2011

A study on the adsorption characteristics of Pb(II) and Cr(III) cations onto C-methylcalix[4]resorcinarene (CMCR) has been conducted. CMCR was produced by one step synthesis from resorcinol, acetaldehyde, and HCl. Most parameters in batch system confirm that CMCR is a good adsorbent for Pb(II) and Cr(III). Cr(III) uptake was bigger than that of Pb(II), but Cr(III) adsorption rate was slower than Pb(II). The adsorption kinetic of Pb(II) and Cr(III) adsorptions in batch followed pseudo $2^{nd}$ order kinetics model, but the kinetic of Pb(II) adsorption in fixed bed column system followed first order model. Desorption studies to recover the adsorbed Pb(II) was performed sequentially with distilled water and HCl, and the results showed that the adsorption was dominated by chemisorption.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.2
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• pp.554-560
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• 2013

This study proposes an structure that fixes the shielding device to two parts of the board by its two arranged clips. Said structure evenly distributes its loading/unloading load of the board and maintains the flatness of soldering area of the board. The structure of this study comprises a base part fixed to a printed circuit board and a clip part fixing a side wall of a shield can to the board, wherein the clip part is constituted with two clips fixable to two part of the shield can. Also, the structure of this study comprises a dented groove in order to easily solder the base part of clips and the printed circuit board. A mechanism is established and a design parameter was determined by a structure analysis and a vibration mode analysis. A single purpose machine for the production of the product was developed, the final workpiece was produced and the measuring-data and the computered-data was compared and reviewed.

• Microbiology and Biotechnology Letters
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• v.17 no.1
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• pp.19-23
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• 1989

A sequential system composed of hydroxylapatite chromatography and gel permeation chromatography was developed to purify the IgM type monoclonal antibody against the colon cancer cell SC-1 from the ascitic fluid of mice injected with the murine hybridoma CH07E02. In the hydroxylapatite chromatographic step the band dilution could be reduced by controlling the gradient and flow rate of the eluent, the sodium phospate buffer, the optimum values for these variables being 5.82$\times$10$^{-3}$M/cm and 0.2$m\ell/\textrm{cm}^2$/min, respectively. A degree of purity better than 99.99% as judged from silverstaining of the SDS-PAGE bands, was obtained by adding the gel permeation chromatographic step in tandem.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.4
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• pp.1466-1473
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• 2012

Soft icecream is made by scraping an ice formed on the inside of the cylindrical evaporator, where R-404A is evaporating in the annulus. The heat transfer characteristics of the refrigerant evaporation and those during icecream formation were experimentally investigated. Results show that the refrigerant-side heat transfer coefficients are highly dependent on the location in the evaporator due to the complex annulus configuration. The heat transfer coefficient at the inlet is generally lower than those of other locations. The average heat transfer coefficient increases as heat flux increases or saturation temperature decreases. A correlation is developed to predict the refrigerant-side heat transfer coefficient. The icecream-side heat transfer coefficient oscillates continuously due to the periodic removal of ice formed on the surface. The average heat transfer coefficient during icecream formation is approximately 280 W/$m^2K$, and that during single-phase cooling increased from 150 W/$m^2K$ to 250 W/$m^2K$.

• Applied Chemistry for Engineering
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• v.10 no.3
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• pp.343-348
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• 1999

The iron silicide films were prepared by chemical vapor deposition method using rf-plasma in variations of substrate temperature. rf-power, and ratio of $SiH_4$ and Fe-precursor. While iron silicide films are generally grown by ion beam synthesis (IBS) method of multi-step process, it is confirmed that iron silicide or $\beta$-phase consolidated $Fe_aSi_bC_cH_d$ was formed by one-step process in this study. The characteristics of films is variable because the different amounts of carbon and hydrogen was involved in the films as a function of dilute ratio of Fe-precursors and silane. It was shown that the different characteristics of films in carbon and hydrogen following the ratio of Fe-precursor and silane. The optical gap energy of films fabricated according to substrate temperature was invariant because active site brought in desorption of hydrogen was limiled. When rf-power was above 240 watt, the optical gap energy turned out to have high values because of dangling bonds increased by etching.