• Title/Summary/Keyword: 탄화수소연료

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Compatibility Assessment of Copper Alloy and Hydrocarbon Fuel for Regeneratively Cooled Combustion Chamber (재생냉각 연소기용 구리합금과 연료 적합성 검증시험)

  • Lim Byoung-Jik;Kim Jong-Gyu;Kang Dong-Hyuk;Kim Hong-Jip;Kim Hui-Tae;Han Yeoung-Min
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.05a
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    • pp.100-109
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    • 2006
  • In the regeneratively cooled combustion chambers using hydrocarbon fuels, coking occurs as the wall temperature increases which generates compounds deposition on the wall. This phenomenon reduces cooling capability of the coolant, finally it can cause damage to combustor by overheating of chamber wall. In this paper electrical heating equipment which is used for the coking experiments and the test results are introduced. The compatibilities of copper alloy with let A-1 were assessed at each condition based on the test results.

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Synthetic Strategies for High Performance Hydrocarbon Polymer Electrolyte Membranes (PEMs) for Fuel Cells (고성능 탄화수소계 고분자 전해질막의 합성 전략)

  • Lee, So Young;Kim, Hyoung-Juhn;Nam, Sang Yong;Park, Chi Hoon
    • Membrane Journal
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    • v.26 no.1
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    • pp.1-13
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    • 2016
  • Fuel cells are regarded as a representative energy source expected to replace fossil fuels particularly used in internal combustion engines. One of the most important components is polymer electrolyte membranes (PEMs) acting as a proton conducting barrier to prevent fuel gas crossover. Since water channels act as proton pathways through PEMs, many researchers have been focused on the 'good phase-separation of hydrophilic moiety' which ensures high water retention under low humidity enough to keep the water channel for good proton conduction. Here, we summarized the strategies which have been adopted to synthesize sulfonated PEMs having high proton conductivities even under low humidified conditions, and hope this review will be helpful to design high performance hydrocarbon PEMs.

Thermal Decomposition of High Speed Aircraft Fuel in Supercritical Phase (고속비행체 연료의 초임계조건에서 열분해반응 연구)

  • Kim, Joong-Yeon;Park, Sun-Hee;Chun, Byung-Hee;Kim, Sung-Hyun;Jeong, Byung-Hun;Han, Jeong-Sik
    • Journal of the Korean Society of Propulsion Engineers
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    • v.15 no.5
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    • pp.1-9
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    • 2011
  • Researches on hypersonic aircraft technologies have been carried out to increase flight speeds. However, increase in flight speeds causes heat loads that could lead structural change of aircraft's component. Researches on cooling technologies using endothermic fuels are progressing in the USA, France and Russia to treat the heat loads. Endothermic fuels are liquid hydrocarbon aircraft fuels which are able to absorb the heat loads by undergoing endothermic reactions, such as thermal and catalytic cracking. In this study, methylcyclohexane, n-octane, and n-dodecane were selected as model endothermic fuels and experiments in endothermic properties were implemented. Experimental conditions were supercritical condition of each model fuels in which actual endothermic fuels were exposed. The object of this study is to identify endothermic properties of the model endothermic fuels and to predict endothermic properties of actual fuels such as kerosene fuels.

Thermal Decomposition of High Speed Aircraft Fuel in Supercritical Phase (고속비행체 연료의 초임계조건에서 열분해반응 연구)

  • Kim, Joong-Yeon;Park, Sun-Hee;Chun, Byung-Hee;Kim, Sung-Hyun;Jeong, Byung-Hun;Han, Jeong-Sik
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.11a
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    • pp.279-286
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    • 2010
  • Hypersonic aircraft technologies have been developed with increase in flight speeds. As hypersonic flight speeds increase, heat loads on an aircraft and it's engine increase. Researches on cooling technologies using endothermic fuels are progressing in the USA, France, and Russia to treat the heat loads. Endothermic fuels are liquid hydrocarbon aircraft fuels which are able to absorb the heat loads by undergoing endothermic reactions, such as thermal and catalytic cracking. In this study, methylcyclohexane, n-octane, and n-dodecane were selected as model endothermic fuels and experiments in endothermic properties were implemented. Experimental conditions were supercritical phase of each model fuels in which actual endothermic fuels were exposed. The object of this study is to identify endothermic properties of the model endothermic fuels and to predict endothermic properties of actual fuels such as kerosene fuels.

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The Reduction of Unburned Hydrocarbons on the Direct-Injection Stratified-Charge Combustion Method by Hydrogen Addition (직접분사 성층연소방식에서 수소 첨가에 의한 미연 탄화수소의 저감)

  • 홍명석;김경석
    • Transactions of the Korean Society of Automotive Engineers
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    • v.4 no.4
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    • pp.46-57
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    • 1996
  • The direct injection stratified charge(DISC) engine enhances the fuel tolerance and the antiknock tendency. This enhanc3d antiknock tendency allows use of a higher compression ratio which results in higher thermal efficiency. But its actual utilization is prevented by high emission combustion time and wall quenching will be the main causes of increasing unburned hydrocarbons in DISC system. In order to solve this problem, small aount of hydrogen was added to the charging air or injected fuel. The effects of hydrogen addition were examined experimentally by radial fuel injection using a pancake-type constant volume bomb. In case of the hydrogen addition to the charge of air, the combustion the amount of hydrogen. In case of the hydrogen addition to the fuel, the combustion pressure was significantly increased.

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Research of Cross-linked Hydrocarbon based Polymer Electrolyte Membranes for Polymer Electrolyte Membrane Fuel Cell Applications (고분자 전해질 막 연료전지 응용을 위한 탄화수소계 기반 가교 전해질 막의 연구동향)

  • Ko, Hansol;Kim, Mijeong;Nam, Sang Yong;Kim, Kihyun
    • Membrane Journal
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    • v.30 no.6
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    • pp.395-408
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    • 2020
  • Polymer electrolyte membrane fuel cells (PEMFCs) have gained much attention as eco-friendly energy conversion devices without emission of environmental pollutant. Polymer electrolyte membrane (PEM) that can transfer proton from anode to cathode and also prevent fuel cross-over has been regarded as a key component of PEMFCs. Although perfluorinated polymer membranes such as Nafion® were already commercialized in PEMFCs, their high cost and toxic byproduct generated by degradation have still limited the wide spread of PEMFCs. To overcome these issues, development of hydrocarbon based PEMs have been studied. Incorporation of cross-linked structure into the hydrocarbon based PEM system has been reported to fabricate the PEMs showing both high proton conductivity and outstanding physicochemical stability. This study focused on the various cross-linking strategies to the preparation of cross-linked PEMs based on hydrocarbon polymers with ion conducting groups for application in PEMFCs.

Detonation Wave Simulation of Thermally Cracked JP-7 Fuel/Oxygen Mixture using Induction Parameter Modeling (Induction Parameter Modeling을 이용한 열 분해된 JP-7 연료 /산소 혼합기의 데토네이션 파 해석)

  • Cho, Deok-Rae;Shin, Jae-Ryul;Choi, Jeong-Yeol;Yang, Vigor
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.37 no.4
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    • pp.383-391
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    • 2009
  • The detonation wave characteristics of JP-7 and oxygen mixture is investigated by one-step induction parameter model (IPM) obtained from a detailed chemistry mechanism. A general procedure of obtaining reliable one-step kinetics IPM for hydrocarbon mixture from the fully detailed chemistry is described in this study. The IPM is obtained by the reconstruction of the induction time database obtained from a detailed kinetics library. The IPM was confirmed by the comparison of the induction time calculations with that from detailed kinetics. The IPM is later implemented to a fluid dynamics code and applied for the numerical simulation of detonation wave propagation. The numerical results show the detailed characteristics of the detonation wave propagation in JP-7 and oxygen mixture at affordable computing time, which is not be possible by the direct application of the detailed chemical kinetics mechanism of hydrocarbon fuel combustion.

Mixture Fraction Analysis on the Combustion Gases of the Full-Scale Compartment Fires (실규모 구획화재의 연소가스에 대한 혼합분율 분석)

  • Ko, Gwon-Hyun;Hwang, Cheol-Hong
    • Fire Science and Engineering
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    • v.24 no.5
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    • pp.128-135
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    • 2010
  • In this study, a mixture fraction analysis was performed to investigate the characteristics of chemical species production in compartment fires burning hydrocarbon fuels such as methane, heptane, and toluene. A series of fire experiments was conducted in the ISO 9705 standard room, and gas species concentration and soot fraction were measured at two locations in the upper layer of the compartment. The mass fractions of measured chemical species, such as unburned hydrocarbons (UHC), carbon monoxide (CO), carbon dioxide ($CO_2$), oxygen ($O_2$), and soot were presented as a function of mixture fraction and compared with state relationships based on the idealized reaction of hydrocarbon fuels. The mixture fraction analysis made it possible to rearrange hundreds of species measurements, which were done under various fire conditions and at two locations of the upper layer, in term of the unified parameter, i.e. the mixture fraction. The results also showed that inclusion of soot in the mixture fraction calculation could improve the performance of analysis, especially for the sooty fuels such as heptane and toluene.

A Study on the Manufacture of Bio-SRF from the Food Waste by Hydrothermal Carbonization (HTC) Process (열수가압탄화 공정에 의한 음식물폐기물로부터의 Bio Solid Reuse Fuel (Bio-SRF) 연료제조에 관한 실증연구)

  • HAN, DANBEE;YEOM, KYUIN;PARK, SUNGKYU;CHO, OOKSANG;BAEK, YOUNGSOON
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.4
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    • pp.426-432
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    • 2017
  • Hydrothermal carbonization (HTC) is an effective and environment friendly technique; it possesses extensive potential towards producing high-energy density solid fuels. it is a carbonization method of thermochemical process at a relatively low temperature ($180-250^{\circ}C$). It is reacted by water containing raw material. However, the production and quality of solid fuels from HTC depends upon several parameters; temperature, residence time, and pressure. This study investigates the influence of operating parameters on solid fuel production during HTC. Especially, when food waste was reacted for 2 hours, 4 hours, and 8 hours at $200^{\circ}C$ and 2.0-2.5 MPa, Data including heating value, proximate analysis and water content was consequently collected and analyzed. It was found that reaction temperature, residence time are the primary factors that influence the HTC process.

Production of Biofuel Energy by High Temperature Pyrolysis of Sewage Sludge Using Microwave Heating (마이크로웨이브 가열 하수 슬러지 고온 열분해에 의한 바이오 연료 에너지 생산)

  • Jeong, Byeo Ri;Chun, Young Nam
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.1
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    • pp.34-39
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    • 2017
  • The recent gradual increase in the energy demand is mostly met by fossil fuel, but the research on and development of new alternative energy sources is drawing much attention due to the limited fossil fuel supply and the greenhouse gas problem. This paper assesses the feasibility of producing fuel energy from a dewatered sewage sludge by microwave-induced pyrolysis with sludge char and graphite receptor. Both receptors produced gas, char, and tar in order from product amount. The gas produced for the sludge char receptor contained mainly hydrogen and methane with a small amount of light hydrocarbons. The graphite receptor generated higher gravimetric tar and generated higher light tar. Through the results, the product gas from the microwave processes of wet sewage sludge might be possible as a fuel energy. But the product gas has to be removed the condensable PAH tars.