• Journal of the Microelectronics and Packaging Society
• /
• v.8 no.2
• /
• pp.25-29
• /
• 2001

This study examined the effects of carbon surface modification by the epoxy resin coating on the electrochemical performance. The mesocarbon microbeads(MCMB) carbon was surface-modified by coating the epoxy resin and its electrochemical properties as an anode was examined. The surface coating of MCMB was carried out by refluxing the MCMB powders in a dilute H2SO4 solution, and mixing them with the epoxy resin-dissolved tetrahydrofuran(THF) solution. Under heat-treatment of the coated MCMB at the temperature over $1000^{\circ}C$, the epoxy-resin coating layer was converted into amorphous phase which was identified by a high resolution transmission electron microscope (HRTEM). The epoxy resin coated MCMB has higher Brunauer-Emmett-Teller (BET) surface area, higher charge/ discharge capacity and better cycleability than a raw MCMB without coating. The reason for the enhancement of cell performance by the epoxy resin coating were considered as the epoxy resin coating layer plays an important role to be a barrier for carbon reacting with electrolyte and to retard the formation of passivation layer.

• Composites Research
• /
• v.28 no.4
• /
• pp.168-175
• /
• 2015

Recently, the applications of carbon fiber reinforced plastics (CFRPs) have become broader than ever when it comes to such industries as automotive, ships, aerospace and military because of their lightweight-ness and high mechanical properties. Thermosetting plastics like epoxy are frequently used as the binding matrix in CFRPs due to their high hardness, wetting characteristics and low viscosity. However, they cannot melted and remolded. For this reason, thermosetting plastic wastes have caused serious environmental problems with the production of fiber reinforced plastics. Thus, many studies have focused on the carbon fiber reinforced thermoplastics (CFRTPs) and recycling carbon fiber. In this study, recycled carbon fiber (RCF) was prepared from CFRPs using a pyrolysis method, which was employed to separate resin and carbon fiber. The degree of decomposition for epoxy resin was confirmed from thermal gravimetric analysis (TGA) and scanning electron microscope (SEM). The RCF was cut and ground to prepare a carbon fiber composite sheet (CFCS). CFCS was manufactured by applying recycled carbon fibers and various thermoplastic fibers. Various characterizations were performed, including morphological analyses of surface and cross-section, mechanical properties, and crystallization enthalpy of CFCS at different cooling conditions.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.11 no.5
• /
• pp.89-98
• /
• 2007

This study investigates the deformation behavior, related to debonding failure, of adhesion and repairing-strengthening materials of RC construction. A strain-stress curve shows that when the stress of specimens reached the highest and then fails, the strain value of cement mortar is $2.0{\times}10^{-3}$, while concrete was indicated at around $1.3{\times}10^{-3}$, epoxy resins are $0.8{\times}10^{-3}$, polymer mortar is $2.5{\times}10^{-3}$, steel plate is $2.5{\times}10^{-3}$, and carbon bar was $9.1{\times}10^{-3}$, respectively. For a thermal expansion coefficient with temperature variation, those basis materials, cement mortar and concrete, exhibited around $10{\mu}{\varepsilon}/{^{\circ}C}$, but adhesive materials, such as epoxy resins and polymer mortar, were $41{\sim}54{\mu}{\varepsilon}/{^{\circ}C}$ and $-0.5{\sim}0.7{\mu}{\varepsilon}/{^{\circ}C}$, respectively. In the case of steel plate is similar to basic materials but carbon fiber is indicates at $-1.7{\mu}{\varepsilon}/{^{\circ}C}$, which is the lowest value. Especially, between basic and adhesive materials, the thermal expansion coefficient was highly different. Although the coefficient depends on the type of epoxy resins, it is clear that the epoxy resins are susceptible to be debonded in nature, when the difference of environmental temperature varies more than $20{\sim}35{^{\circ}C}$.

• Fire Science and Engineering
• /
• v.22 no.2
• /
• pp.44-48
• /
• 2008

In this paper, we measured a contact angle, surface resistivity and XPS to study the thermal aging characteristics of the epoxy resin for cast resin transformer. As a result of this experiment, we found that the contact angle increases up to $200^{\circ}C$ as it causes a re-crosslinking on the surface, but starts decreasing at $250^{\circ}C$ as it causes heat condensation. As a result of examining the oxygen/carbon peaks through the XPS analysis, we obtained a higher oxygen peak vs. carbon in the first untreated sample, but it showed the opposite trend after heat treatment. That rise in the carbon peak continued up to $200^{\circ}C$, but decreased again at the temperatures above. That's because it kept forming a stable surface structure up to $200^{\circ}C$ but its carbon combination got destroyed due to a rapid oxidization at $250^{\circ}C$. And a conduction path was formed easily with the hydrophile property caused by rapid surface activation.

• Composites Research
• /
• v.27 no.3
• /
• pp.109-114
• /
• 2014

Manufacture of nancomposites has simple process for developing nanocomposites due to the increasing applications using nanofillers. This work studied nanofiller coated glass fiber for reinforcing material with good wetting and conductivity and the morphology of nanofiller coated glass fiber was analyzed by FE-SEM. The durability of reinforced glass fiber was investigated with different shapes of nanofillers using sonication rinsing method. Fatigue test was performed to evaluate the adhesion of reinforcing interface and stability of nanofiller coating layer for single fiber reinforced composites. Apparent modulus and conductivity of nanofiller coating layer were evaluated to realize multifunctional of nanocomposites. Fiber type of nanofiller was better than plate type due to better cohesion between fiber and nanofillers. At last, the stability of fiber type nanofiller of coating layer has better durability and conductivity than plate type case.

• Composites Research
• /
• v.26 no.5
• /
• pp.315-321
• /
• 2013

In this work, pitch-carbonized glass fibers were prepared for reinforcement of composites. The influence of acid functionalization of the fibers on the morphological, mechanical, and thermal properties of fiber-reinforced epoxy matrix composites was investigated. The acid functionalization of the fibers led to 10 and 150% increases in the mechanical and thermal properties, respectively, as compared to carbon fiber-reinforced composites. This can be attributed to the superior orientation of fiber structures and good interfacial interactions between fillers and epoxy matrix, resulting in enhanced degree of dispersion and formation of thermally conductive paths in the functionalized composites.

• Journal of the Korean Applied Science and Technology
• /
• v.33 no.4
• /
• pp.634-646
• /
• 2016

In this work, modified epoxy resins which were well melted in mild solvent were synthesized and solubility assessment was carried out for synthesized epoxy resins. Bisphenol-A type, phenol novolac type and ortho-cresol novolac type epoxy resins were used and fatty acid, dodecyl phenol (DP) and toluene diisocyanate (TDI) were added for synthesis of modified epoxy resins containing fatty acid (MEFA). Composition was epoxy resin/fatty acid = 1.0/0.5 and fatty acid/DP = 0.25/0.25 by equivalent weight and twelve MEFAs were synthesized according to epoxy resins. Viscosity and solubility were measured for twelve MEFAs. As a result, solubility of MEFA was excellent for mild solvent according to increasement of contents of benzene ring, glycidyl group and carbon number of alkyl group. And physical properties were measured for each coating of paints after preparing transparent paints of MEFA to melt well in mild solvent among twelve MEFAs. As a result, they showed an optimal performance on conditions of equivalent ratio of bisphenol-A type epoxy resin/fatty acid/DP/TDI; 1.0/0.25/0.25/0.5 and equivalent ratio of phenol novolac type epoxy resin/fatty acid/DP; 1.0/0.25/0.25 for drying time, adhesion, hardness, impact resistance and alkali resistance.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.1 no.1
• /
• pp.111-121
• /
• 1997

An investigation was performed to study the predicting the joint strength of mechanical fasteners. Bearing failure is most important failure mode for designing joint. So in this study, the prediction method in consideration with bearing failure was chosen. In the proposed method, the characteristic length is combined with the Yamada-Sun failure criterion, Tsai-Hill failure criterion and characteristic length for Tension and Compression is determined from investigation. Especially the length of compression is determined from the "bearing failure test" that newly conceived to take bearing failure into consideration. The proposed prediction method was applied to quasi-isotropic carbon/epoxy joint showing net-tension and bearing failure experimentally. Good agreement was found between the predicted and experimental result for each joint geometry. geometry.

• Journal of Hydrogen and New Energy
• /
• v.31 no.1
• /
• pp.49-56
• /
• 2020

Epoxy/carbon composite was used to prepare a bipolar plate for polymer electrolyte membrane fuel cell (PEMFC). Phenol novolac-type epoxy and diglycidyl ether of bisphenol A (DGEBA)-type epoxy mixture was used as a matrix and graphite powder, carbon fiber (CF) and graphite fiber (GF) were used as carbon materials. In order to improve the mechanical properties of the bipolar plate, surface-modified CF was incorporated into the epoxy/carbon composite. To determine the cure temperature of the epoxy mixture, differential scanning calorimetry (DSC) analysis was performed and the data were introduced to Kissinger equation in order to get reaction activation energy and pre-exponential factor. Tensile and flexural strength was obtained by using universal testing machine (UTM). The surface morphology of the fractured specimen and the interfacial morphology between epoxy matrix and CF or GF were observed by a scanning electron microscopy (SEM).

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.24 no.2 s.173
• /
• pp.338-346
• /
• 2000

Although the net-shape molding of composites is generally recommended, molded composites are frequently required cutting or grinding due to the dimensional inaccuracy for precision machine elements . During the composite machining operations such as cutting and grinding, the temperature at the cutting point may increase beyond the allowed limit due to the low thermal conductivity of composites, which might degrade the matrix of composite. Therefore, in this work, the temperature at the cutting point during cut-off grinding of carbon fiber epoxy composites was measured. The cutting force and surface roughness were also measured to investigate the cut-off grinding characteristics of the composites. The experiments were performed both under dry and wet grinding conditions with respect to cutting speed and feed rate. From the experimental investigation, the optimal conditions for the composite cut-off grinding were suggested.