• Title/Summary/Keyword: 탄소함량

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Nondestructive Damage Sensitivity of Carbon Nanotube and Nanofiber/Epoxy Composites using Electro- Micromechanical Technique and Acoustic Emission (전기적-미세역학 시험법과 음향 방출을 이용한 탄소 나노튜브와 나노섬유 강화 에폭시 복합재료의 비파괴 손상 감지능)

  • 김대식;박종만;김태욱
    • Polymer(Korea)
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    • v.28 no.4
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    • pp.285-290
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    • 2004
  • Nondestructive damage sensitivity of carbon nanotube(CNT) and nanofiber (CNF)/epoxy composites with their adding contents was investigated using electro-micromechanical technique. Carbon black (CB) was used only for the comparison with CNT and CNF. The fracture of carbon fiber was detected by acoustic emission (AE), which was correlated to the change in electrical resistance, ΔR under double-matrix composites (DMC) test. Stress sensing on carbon nanocomposites was performed by electro-pullout test under uniform cyclic loading. At the same volume fraction, the damage sensitivity for fiber fracture, matrix deformation and stress sensing were highest for CNT/epoxy composite, whereas for CB/epoxy composite they were the lowest among three carbon nanomaterials (CNMs). Damage sensitivity was correlated with morphological observation of carbon nanocomposites. Homogeneous dispersion among CNMs could be keying parameters for better damage monitoring. In this study, damage sensing of carbon nanocomposites could be evaluated well nondestructively by the electrical resistance measurement with AE.

Interlaminar Shear Strength and Impact behavior of Low Density 2-D Carbon/Carbon Composites according to Additives (첨가제에 따른 저밀도 2-D 탄소/탄소복합재의 층간전단강도 및 충격거동)

  • 손종석;정구훈;주혁종
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2000.11a
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    • pp.88-91
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    • 2000
  • 흑연분말, 카본블랙, 탄소섬유분말을 첨가제로 한 저밀도 2-D 탄소/탄소 복합재의 밀도 및 기 기공도에 피치는 영향과 ILSS, 굽힘강도 및 충격에너지와 같은 기계적 물성과의 상관관계에 대하여 연구하였다. 흑연분말을 약 9 vol.% 첨가한 경우 가장 큰 ILSS값과 굽힘강도 및 충격에너지 흡수 거동을 나타내었는데, 특히 흑연의 함량이 증가함에 따라 puncture mode로의 충격 거동을 나타내 띠 많은 충격에너지를 흡수하였고, 인성이 상당히 증가하였다 카본블랙이 첨가된 경우에는, 약 3 vol.%에서 ILSS 값이 증가하였으나 큰 개선을 보이지 못하였으며, 굽힘강도는 감소하였다. 탄소섬유분말의 첨가량이 증가함에 따라 층간분리에 의해 밀도가 현저히 감소하여 ILSS 및 굽힘강도의 감소를 보였다.

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Characteristics of Coal Ash Melting in Bench Scale Entrained Coal Gasifier (Bench Scale급 기류층 석탄가스화기에서 회분의 용융 특성)

  • 정봉진;이중용;이계봉;윤용승
    • Journal of Energy Engineering
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    • v.8 no.1
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    • pp.127-136
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    • 1999
  • Bench Scale급 기류층 석탄가스화기에서 배출된 슬form의 특성을 파악하기 위해서 Drayton 석탄과 Kideco 석탄으로부터 생성된 슬래그의 조성, 형상, 잔존탄소함량 및 중금속 성분들을 분석하였다. Drayton 석탄 슬래그의 형상은 표면이 매끄럽고 단단하며 다공성을 띄면서 crack이 거의 없고 결정구조가 비정형인 반면에, Kideco석탄 슬래그의 경우는 표면이 거칠고 crack이 상당히 많이 존재하며 주결정상은 pyroxene과 anorthnite 등으로 이루어져있다. 슬래그의 재활용시 판단 기준이 되는 잔존탄소함량은 두 대상탄 모두 1% 이하를 나타내어 재활용이 가능하며, 슬래그의 용출수 분석결과 석탄중에 함유된 중금속은 슬래그중에 용융되어 안정한 화합물로 존재하므로 중금속 유출로 인한 2차적인 환경오염 문제는 없을 것으로 판단된다.

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Analysis of Thin Films for Semiconductor (반도체소자 박막 분석)

  • Oh, Teresa
    • Proceedings of the KAIS Fall Conference
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    • 2010.11a
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    • pp.73-75
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    • 2010
  • 층간 절연막으로 사용 가능한 SiOC 박막에 대하여 유전상수가 낮아지는 원인을 이온에 의한 분극과 전자에 의한 분극에 대하여 측정하였다. MIS 구조를 이용하여 전형적인 C-V 측적법에 의하여 유전상수를 구하였으며, 굴절률을 측정하여 전자에 의한 분극의 효과에 의한 유전상수를 측정하고 서로 비교하였다. SiOC 박막의 화학적인 특성은 FTIR 분석을 이용하였으며, FTIR 분석에서 디컨벌류션한 데이터는 탄소의 함량에 대한 변화를 구하였다. 탄소의 함량변화는 굴절률의 변화와 비슷한 경향성을 나타내었으나, 유전상수와는 반비례하였다. 전자에 의한 분극의 효과는 유전상수가 떨어지는 것에 큰 영향을 주지는 않았으며, 이온에 의한 분극의 효과가 SiOC 박막의유전상수를 낮게 하는 효과가 더욱 크게 나타났다.

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Determination of Wood Flour Content in WPC Through Thermogravimetic Analysis and Accelerator Mass Spectrometry (열중량 분석기와 질량가속기를 이용한 목재·플라스틱 복합재의 목질섬유함량 분석)

  • Gwon, Jae-Gyoung;Lee, Dan-Bee;Cho, Hye-Jung;Chun, Sang-Jin;Choi, Don-Ha;Lee, Sun-Young
    • Journal of the Korean Wood Science and Technology
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    • v.45 no.5
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    • pp.572-579
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    • 2017
  • Determination of the wood content in wood plastic composite (WPC) is crucial to form reliable WPC market. WPC with simple formulation consisting of only two components (wood flour and polypropylene) was examined using thermogravimetric analysis (TGA) and accelerator mass spectrometry (AMS) for determining wood content in the WPC. TGA method using derivative peak temperature (DTp) of polypropylene under low heating rate ($5^{\circ}C/min$) showed more reliable calibration curve and lower error factor compared to method of using the percentage of weight loss of wood flour. In addition, AMS using bio-based carbon content showed greater reliability for the determination of wood content in the WPC in comparison with the TGA method.

Effect of Graphite Nanofibers Addition on the Electrochemical Behaviors of Platinum Nanoparticles Deposited on Activated Carbons (활성탄소에 담지된 백금나노입자의 전기화학적 거동에 대한 그라파이트 나노섬유 첨가효과)

  • Jo, Wonbin;Oh, Misoon;Kim, Juhyun;Kim, Seok
    • Korean Chemical Engineering Research
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    • v.48 no.6
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    • pp.673-678
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    • 2010
  • In the present study, mixed carbon-supported platinum(Pt) nanoparticles were prepared by a chemical reduction method of Pt precursor solution on two types of carbon materials such as activated carbons(ACs) and graphite nanofibers(GNFs). Average crystalline sizes and loading levels of Pt metal particles could be controlled by changing a content of GNFs. The highest electroactivity for methanol oxidation was obtained by preparing the carbon supports having 15 wt% GNFs. Furthermore, with an increase of GNFs content from 0% to 15%, an electrical conductivity was changed from $10^{-4}S/cm$ to $10^{-1}S/cm$. By an introduction of 10 wt% GNFs additive, the electroactivity of platinum particles was enhanced, but was saturated in the case of 15 wt% GNFs contents. This was related with the fact that the electroactivity change was dependent on the electrical conductivity of mixed carbon supports and Pt particle deposition content or deposition morphology.

Effect of Carbon and Nitrogen concentration on Lipid production by Rhodotorula sp. (Rhodotorula sp. 의 균체유지 생산에 미치는 탄소원과 실소원 농도의 영향)

  • 김진원;강신권;성낙계
    • Microbiology and Biotechnology Letters
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    • v.12 no.4
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    • pp.271-276
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    • 1984
  • Effect of C/N ratios on the cell growth, cell lipid, cell protein and fatty acids of Rhodotorula sp. was examined. At low concentration of nitrogen in cultural medium the growth of the yeast was retarded, whereas its growth was favorable at high concentration but lipid yield was decreased due to a high content of cell protein. In order to increase lipid yield, the optimum C/N ratio obtained was 45-50 (5% glucose, 0.0414% nitrogen). During the cultivation cell protein synthesis occurred mainly in initia stage and the lipid was accumulated rapidly at the late phase. The highest content of total fatty acid was observed at the optimum C/N ratio. The higher C/N ratio was the more unsaturation degree of fatty acid decreased. It was attributed principally to a decreased oleic acid with palmitic acid increased. No significant changes occurred in content of other fatty acids.

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Study on Characteristics of Change in Calorific Value and Carbon Emission Factor of Domestic Petroleum Energy Source (국내 석유계 에너지원의 열량 및 탄소배출계수 변화 특성 연구)

  • Doe, Jin-woo;Lim, Wan-gyu;Kang, Hyung-kyu;Hwang, In-ha;Ha, Jong-han;Na, Byung-ki
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.4
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    • pp.1046-1057
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    • 2017
  • Country-specific emission factors should be developed and used instead of IPCC defaults to improve national GHG inventories to Tier 2 and above. Since the country-specific emission factors depend on the type of energy source, energy process, and time trend, identifying the value of each energy source is an important part of building an accurate inventory. In this study, calorific value and carbon emission factor for petroleum energy sources on the basis of calorific value conversion standard for energy source, which are notified in Korea, are collected by 2013 and 2016, and calorific value, carbon content and carbon emission factor And a comparative analysis was conducted. In addition, net calorific values and carbon emission factors calculated for each petroleum based energy source are compared with those shown in 2006 IPCC Guideline.

Yields of oyster mushroom(Pleurotus ostreatus) on addition rate of Juglans mandshurica sawdust (가래나무(Juglans mandshurica) 톱밥의 첨가량이 느타리버섯의 수량에 미치는 영향)

  • Lee, Chan-Jung;Cheong, Jong-Chun;Jhune, Chang-Sung;Moon, Ji-Won;Kong, Won-Sik;Suh, Jang-Sun;Park, Gi-Chun;Shin, Yu-Su;Lee, Jeong-Hoon
    • Journal of Mushroom
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    • v.11 no.4
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    • pp.219-225
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    • 2013
  • This study was carried out to investigated optimum mixing ratio of Korean natural Juglans mandshurica using as functional plants. Total nitrogen and carbon source of J. mandshurica was 0.21% and 46.0%, respectively and C/N ratio was 219. Total nitrogen source and pH of substrate mixed with J. mandshurica was 2.3~2.9 and 5.0, respectively. The contents of CaO, MgO and $Na_2O$ at J. mandshurica media were higher at harvest media than inoculation media. Mycelial growth was the fastest at J. mandshurica 20%, and slower by increase of J. mandshurica substrate. Yields of fruiting body show the highest to 163 g/850 mL of medium which are addition 10% of J. mandshurica sawdust, and diameter and thick of pileus were the highest, too. The L value of pileus and stipes were increased by increase of J. mandshurica substrate, but there was no significant difference in the a-value and the b-value. The contents of $P_2O_5$ and $K_2O$ of fruiting body were increased at J. mandshurica substrate, but there was no significant difference in contents of CaO, MgO and $Na_2O$. The contents of Cu of fruiting body was decreased by increase of J. mandshurica substrate, but Fe, Mn and Zn were increased.