• Title/Summary/Keyword: 탄소종이

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Preparation and Electrical Properties of Carbon Paper Using Chopped Carbon Fiber (탄소 단섬유를 이용한 탄소종이 제조 및 전기전도도 특성)

  • Lee, Ji-Han;Yoo, Yoon-Jong;Park, Soo-Jin
    • Applied Chemistry for Engineering
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    • v.24 no.2
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    • pp.121-125
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    • 2013
  • In this work, we prepared the carbon paper from chopped carbon fibers using a gas diffusion matrix in polymer electrolyte membrane fuel cells by wet processing. The process of making carbon paper using wet processing is consisted of the three steps involving the dispersion of chopped carbon fibers, the preparation of the carbon fiber web, the impregnating of phenol resin. This work was focused on finding the optimal surfactant to make the carbon paper with 2D orientation of carbon fibers by investigating the dispersion state of carbon fibers in different dispersion solutions. Furthermore, the effect of phenol resin and carbon black contents on properties of electric conductivity was analyzed. As a result, it is confirmed that the carbon fiber was well dispersed when using sodium dodecyl sulfate as a surfactant, and the carbon paper with 8 wt% of phenol and 5 wt% of carbon black contents showed the most excellent electrical property.

Fabrication and Characterization of Carbon Nanotube-modified Carbon Paper-based Lactate Oxidase-catalase Electrode (탄소나노튜브로 개질된 탄소종이 기반 젖산산화효소 - 카탈레이즈 전극 제작 및 특성 분석)

  • Ke Shi;Varshini Selvarajan;Yeong-Yil Yang;Hyug-Han Kim;Chang-Joon Kim
    • Korean Chemical Engineering Research
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    • v.61 no.4
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    • pp.576-583
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    • 2023
  • This study aimed to investigate the impact of enhancing the electrode conductivity and mitigating the production of hydrogen peroxide - a by-product arising from lactate oxidation - on the performance of lactate electrodes. The electrical conductivity of the electrode was improved by modifying the surface of carbon paper with single-walled carbon nanotubes. Catalase was introduced to effectively eliminate the hydrogen peroxide produced during the lactate oxidation reaction. The carbon paper electrode, with simultaneous immobilization of both lactate oxidase and catalase, yielded a current 1.7 times greater than the electrode where only lactate oxidase was immobilized. The electrode in which lactate oxidase and catalase were co-immobilized on the surface of carbon paper modified with single-walled carbon nanotubes, produced a current of 171 µA, which was more than twice as much current as the carbon paper with only lactate oxidase immobilized. The optimized electrode showed a linear response up to lactate concentration of 20 mM, confirming that it can be used as a sensor electrode.

Characterization of Milled Carbon Fibers-filled Pitch-based Carbon Paper for Gas Diffusion Layer (미분쇄 탄소섬유가 첨가된 피치계 탄소섬유기반 기체확산층용 탄소종이 특성)

  • Ham, Eun-Kwang;Yoon, Dong-Ho;Kim, Byoung-Suhk;Seo, Min-Kang
    • Composites Research
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    • v.29 no.5
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    • pp.262-268
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    • 2016
  • In this work, the pitch-based carbon paper (P-CP) was prepared by re-impregnating of binder pitches and PAN-based milled carbon fibers (MCF) at low temperature carbonization process. The influence of MCF content on physicochemical properties of MCF/P-CP was investigated. As a result, the tensile strength of MCF/P-CP was increased sharply from 10 wt.% to 20 wt.% of MCF. Also, the increase of MCF content led to the decrease of interfacial contact resistivity and the improvement of electrical and thermal conductivity of MCF/P-CP. These results were probably due to the increase of density of MCF/P-CP, resulting in the formation of electrically and thermally conductive paths of the carbon paper.

Preparation and Characterization of Pitch-based Carbon Paper for Low Energy and High Efficiency Surface Heating Elements (저전력 및 고효율 면상발열체를 위한 피치기반 탄소종이 제조 및 특성)

  • Yang, Jae-Yeon;Yoon, Dong-Ho;Kim, Byoung-Suhk;Seo, Min-Kang
    • Composites Research
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    • v.31 no.6
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    • pp.412-420
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    • 2018
  • In this work, phenolic resins containing conductive carbon fillers, such as, petroleum coke, carbon black, and graphite, were used to improve the surface heating elements by impregnating a pitch-based carbon paper. The influence of conductive carbon fillers on physicochemical properties of the carbon paper was investigated through electrical resistance measurement and thermal analysis. As a result, the surface resistance and interfacial contact resistivity of the carbon paper were decreased linearly by impregnating the carbon fillers with phenol resins. The increase of carbon filler contents led to the improvement of electrical and thermal conductivity of the carbon paper. Also, the heating characteristics of the surface heating element were examined through the applied voltage of 1~5 V. With the applied voltage, it was confirmed that the surface heating element exhibited a maximum heating characteristic of about $125.01^{\circ}C$(5 V). These results were attributed to the formation of electrical networks by filled micropore between the carbon fibers, which led to the improvement of electrical and thermal properties of the carbon paper.

플라즈마 처리에 의한 원뿔형 다중벽 탄소나노튜브 다발의 형성기전

  • Im, Seon-Taek;Kim, Gon-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.129-129
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    • 2010
  • 플라즈마 처리를 통하여 수직 합성된 다중벽 탄소나노튜브가 원뿔형 다발이 될 수 있으며 원뿔형 탄소나노튜브 다발은 기존의 구조적, 기계적 성질의 향상과 더불어 향상된 전계방출 능력을 가질 것으로 기대되어 이를 X-선원, 전계방출디스플레이(FED), 유기발광다이오드(OLED) 백라이트 등의 전자빔 원으로 적용하기 위한 연구가 진행되고 있다. 원뿔형 탄소나노튜브 다발의 형상 제어를 통하여 전계방출특성을 향상시킬 수 있으며 이를 위해 원뿔형 탄소나노튜브 다발이 생성되는 메커니즘과 조사되는 플라즈마의 역할에 대해서 이해하는 것이 중요하다. 본 연구에서는 플라즈마 생성부와 조사부를 분리한 유도결합형 플라즈마 원을 사용하여 입사되는 이온의 에너지, 조사량, 입자 종을 독립적으로 제어하였고 이를 통하여 원뿔형 탄소나노튜브 다발이 형성되는 메커니즘과 플라즈마의 역할을 밝혀내었다. 알곤 및 수소 플라즈마 처리에서는 원뿔형 탄소나노튜브 다발이 형성되지 않았으나 질소 및 산소 플라즈마 처리에서는 원뿔형 탄소나노튜브 다발이 형성되었다. 특히 산소 플라즈마 처리가 원뿔형 탄소나노튜브 다발 형성에 효과적이었다. 원뿔형 탄소나노튜브 다발의 형성 메커니즘은 탄소나노튜브의 분극과 쉬스 전기장의 상호작용을 이용한 모델을 사용하여 설명하였다. 질소 및 산소 플라즈마 처리에서는 탄소나노튜브 끝단에 생성되는 C-N, C-O 결합에 의해 향상된 유도 쌍극자와 쉬스 전기장에 의해 탄소나노튜브 끝단이 모여 원뿔형 탄소나노튜브 다발이 생성됨을 밝혀내었다. 산소 플라즈마 처리에서 입사되는 이온의 에너지 조절에 의한 쉬스 전기장 조절과 조사량 조절을 독립적으로 수행하여 원뿔형 탄소나노튜브 다발의 직경 및 높이가 쉬스 전기장 및 조사량에 따라 조절 가능함을 보였다. 이로부터 입사되는 이온의 입자 종, 쉬스 전기장 및 조사량 조절 등의 플라즈마 인자 조절을 통하여 원뿔형 탄소나노튜브 다발의 형상 제어가 가능함을 보였다. 탄소나노튜브의 형상 제어와 더불어 세슘 입자 삽입을 통한 탄소나노튜브의 일함수 감소를 통하여 향상된 전계 방출 특성을 갖는 탄소나노튜브 팁의 제조 가능성을 확인하였다.

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False Positive of F-18 FDG-PET/CT due to Activated Charcoal Granuloma from Intraperitoneal Chemotherapy: A Case Report (복강 내 화학요법에 이용된 활성화 탄소 육아종에 의한 F-18 FDG PET/CT의 위양성 소견: 증례)

  • Lee, Se-Youl;Kim, Chan-Young;Yang, Doo-Hyun
    • Journal of Gastric Cancer
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    • v.6 no.4
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    • pp.291-294
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    • 2006
  • F-18 FDG-PET/CT could be used to evaluate the surveillance of recurrent stomach cancer, but some cases reported as false-positives. The authors found an activated charcoal granuloma from intraperitoneal chemotherapy by using a curative resection and mitomycin C for stomach cancer. A mass behind the right colon that showed on CT 6 months after an operation in a 46-year-old male patient had no progression in size, but 36 months after the operation, an increase was seen on F-18 FDG-PET/CT, and a metastatic tumor was suspected. The tumor was resected by an explorative laparotomy and was diagnosed as being an activated charcoal granuloma based on the histologic finding. Based on this case, we should be reminded of the possibility of a false-positive on analysis of F-18 FDG-PET/CT caused by an activated charcoal granuloma in a patient who has intraperitoneal chemotherapy.

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곤충병원성 선충과 공생박테리아의 지방산 함량 분석

  • Park, Seon-Ho;Kim, Hyo-Hyeon;Kim, Ji-Yeon
    • 한국생물공학회:학술대회논문집
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    • 2001.11a
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    • pp.910-913
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    • 2001
  • The fatty acid compositions of entomopathogenic nematodes Steinernema carpocapsae strain produced in vitro and in vivo were examined. Nematodes cultured both in vitro and in vivo revealed similar fatty acids compositions with respect to 16, 18, 20 carbons. However, the contents of lipids were varied by culture methods. Furthermore, it was distinctive that nematodes cultured in vitro contained fatty acids with 19 carbon. In the case of symbiotic bacterium Xenorhabdus nematophilus isolated from Steinernema carpocapsae, the major lipid component was palmitic (c16:0) fatty acids.

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On the Compsition of Triglyceride in the Oil of Walnut and Pine-nuts (호도와 잣기름중의 트리글리세리드 조성에 관하여)

  • Kim, Young Ho;Cha, Wol Suk;Kim, Jong Soo;Ryu, Seoung Ryul
    • KSBB Journal
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    • v.5 no.4
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    • pp.341-345
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    • 1990
  • The composition of triglyceride in the oil of walnut and pine-nut were analysed quantitatively by Tri-analysis column of HPLC. The results were as follows: 1. The compositions of triglyceride of pine-nut oil were $C_{52}=31.55%,\;C_{44}=20.72%,\;C_{54}=17.52%,\;C_{34}=15.24%,\;C_{56}=12.50%$ in order, respectively. 2. The compositions of triglyceride of walnut oil were $C_{44}=38.66%,\;C_{52}=29.47%,\;C_{54}=16.53%,\;C_{34}=11.12%,\;C_{50}=1.51%$ in order, respectively.

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Properties of the Sintered Eco-brick according to the Unburned Carbon Content of the Coal Briquette Ash (연탄재(煉炭滓)의 미연탄소(未燃炭素) 함량(含量)에 따른 소성(燒成) 에코벽돌 특성(特性))

  • Park, Hong-Kyu;Yoo, Seung-Woo;Jung, Moon-Young
    • Resources Recycling
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    • v.19 no.3
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    • pp.16-23
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    • 2010
  • Coal briquette use has dramatically increased because of high oil prices. Hence, it is necessary to develop an environment-friendly recycling technique of the coal briquette ash. The coal briquette ash contains a large amount of an unburned carbon content and a mullite with high thermal property, so it is considered to be used as raw materials of sintered eco-brick. This study aimed to investigate on how the unburned carbon affects properties of the sintered eco-brick. The eco-brick was mixed with the ratio of 50 wt% coal briquette ash having the unburned carbon 10.5 wt% and 50 wt% cullet, then being sintered at $950^{\circ}C$, which of the compressive strength was in line with the first class of the sintered clay brick standard(KS L 4201). In particular, the compressive strength of the sintered eco-brick was equal to the first class of the KS L 4201 despite the increase of mixing ratio for coal briquette ash with 1.0 wt% unburned carbon to 70 wt%.