• Journal of the Korean Electrochemical Society
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• v.22 no.3
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• pp.112-121
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• 2019

In this study, silicon / carbon nanotube / carbon composite particles with high capacity were fabricated by using micro-sized silicon particles and carbon nanotubes as an anode material for lithium ion batteries. The silicon / carbon nanotube / carbon composite particles were prepared by spray drying method to prepare spherical composite particles. The composite particles have the network structure of the carbon nanotubes around the silicon particles, in which the silicon particles and the carbon nanotubes are bonded by amorphous carbon. It appears that the volume expansion of silicon is effectively buffered and the electrical contact is maintained in the network structure of the composite particles during charge-discharge cycles.

• Transactions of the Korean Society of Mechanical Engineers
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• v.12 no.5
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• pp.1104-1112
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• 1988

In this study the structure of a two phase detonation has been numerically investigated through the assumption of a steady and one-dimensional flow in the suspension of carbon particles and pure oxygen. The bow shock formation in front of carbon particles has been taken into consideration when the relative velocity of gas flow with respect to the particle exceeds the local speed of sound. But its effect was found to be very limited to the induction zone only. Furthermore the interior particle temperature distribution has been considered in this work. It was found that the inner temperature gradient was very steep in the region of high relative velocity. On the while the temperature distribution inside the particle was almost uniform in the region of low relative velocity. Overall, the effect of the interior particle temperature distribution has been significant in the two phase detonation.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2002.11a
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• pp.341-342
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• 2002

미세탄소입자는 원소탄소(elemental carbon)와 유기탄소(organic carbon)로 분류할 수 있다. 원소탄소는 불완전연소 과정에 발생하는 검댕(black soot), 원유의 정제과정에 발생하는 흑연(graphite), 자연상태에서 만들어진 다이아몬드의 3가지 형태로 존재한다. 이들 중 대기환경에 영향을 미치는 요소는 검댕입자로서 입경은 l$\mu\textrm{m}$이하이며, 일정한 형태를 지니고 있지 않다. (중략)

• 대한공업교육학회지
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• v.32 no.2
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• pp.188-198
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• 2007

Platinum nanoparticles loading on carbon nanotube was carried out by impregnation of hexachloro platinate(IV) from hydrogen hexachloro platinate(IV) hydrate dissolved solution without using reduction agents, and heating the hexachloro platinate(IV) impregnated carbon nanotube up to $400^{\circ}C$. The amounts of impregnated hexachloro platinate(IV) on to carbon nanotube were measured with UV-visible spectrophotometer. The TG, XRD, and TEM analysis were performed to confirm the platinum particles loading and distribution on carbon nanotube. The average platinum particles size on carbon nanotube was under 2 nm by heating the hexachloro platinate(IV) up to $400^{\circ}C$ in spite of non-using reduction agents, while the average size increased due to the agglomeration of some particles by heating them up to $800^{\circ}C$. Therefore, uniformly distributed platinum nanoparticles loading on carbon nanotube can be obtained from simple impregnation of hexachloro platinate(IV) from solution and heating it up to $400^{\circ}C$.

• Applied Chemistry for Engineering
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• v.27 no.4
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• pp.449-454
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• 2016

In this study, highly monodispersed porous carbon microcapsules with a hollow core were synthesized using polystyrene (PS) beads as a hard template. The surface of PS was first modified with polyvinylpyrollidone (PVP) for the easy attachment of inorganic silica sol. After coating the surface of PVP modified PS microspheres with SBA-16 sol, the carbon microcapsules with a hollow macroporous core were fabricated through reverse replication method by filling carbon sources in the mesopores of silica mold. The hollow carbons having a mesoporous shell structure and narrow particle size distribution could be obtained after the carbonization of carbon source and the dissolution of silica mold by HF solution. The mesoporous characteristics and electrochemical properties of hollow carbon microcapsules were characterized by XRD, SEM, TEM, $N_2$ adsorption/desorption analysis and cyclic voltammetry. They showed the high electric conductivity and capability for use as efficient electro-materials such as a supercapacitor.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 2009.04a
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• pp.18-20
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• 2009

입자 강화 복합재료 내에서의 다양한 손상 메커니즘은 복합재료의 전체 거동을 예측에 상당한 영향을 미친다. 이에 본 연구에서는 입자 강화 복합재료 내에서의 누적 손상을 고려한 미세역학 기반 탄소성 모델(Kim and Lee, 2009)을 소개하고자 한다. Kim and Lee (2009)에 의해서 입자 강화 복합재료의 탄소성 모델을 위해 입자 강화 복합재료 내 계면에서의 누적 손상 및 기지재의 연성 거동이 고려되었다. 제안된 모델을 이용한 입자 강화 복합재료의 탄소성 거동 예측값은 관련된 실험값 (Llorca et al., 1991)과의 비교를 통해 수치해석을 수행하였다.

• Korean Chemical Engineering Research
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• v.54 no.4
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• pp.568-573
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• 2016

We investigated the charging characteristics of a conducting solid sphere (glassy carbon sphere) comparing with that of a water droplet and check the applicability of the perfect conductor theory. For the systematic research, sphere size, applied voltages, viscosity of the medium were changed and the results were compared with that of corresponding water droplets and the perfect conductor theory. Basically, a glassy carbon sphere follows the perfect conductor theory but the charging amount was lower as much as 70~80% of theoretical prediction value due to oil film formed between electrode and a carbon sphere. We hope this result provides basic understandings on the solid sphere contact charging phenomenon and related applications.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.568-568
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• 2012

뛰어난 물리적, 전기적 특성을 가진 단일벽 탄소나노튜브는 여러 분야에서 응용 가능성이 매우 높은 물질이다. 그러나 단일벽 탄소나노튜브의 전기적 특성은 나노튜브의 직경과 카이랄리티(chirality)에 매우 강하게 의존되기 때문에 균일한 직경과 카이랄리티를 갖는 단일벽 탄소나노 튜브만의 사용은 나노튜브 기반의 전자소자 응용에서 매우 중요하다. 균일한 직경과 카이랄리티의 단일벽 탄소나노튜브를 얻는 방법은 나노튜브 합성을 통한 직접적인 방법과 후처리 기술을 통해 가능하며, 최근에는 금속 나노입자를 촉매로서 화학기상증착(Chemical vapor deposition, CVD)을 이용하여 좁은 직경 분포를 갖는 단일벽 탄소나노튜브의 합성이 보고되었다. 화학기상 증착은 용이하게 단일벽 탄소나노튜브를 합성하며, 성장된 나노튜브의 직경은 촉매금속 나노입자의 크기에 의해 결정된다. 본 연구는 크기가 제어된 산화철 나노입자를 촉매금속으로 사용하여 열화학기상증착법을 이용해 직경분포가 매우 좁고 균일한 단일벽 탄소나노튜브를 합성하였다. 합성된 단일벽 탄소나노튜브 직경과 카이랄리티는 라만 분광법(Raman spectroscopy)과 투과 전자현미경(Transmission electron microscope)을 이용하여 분석하였다.

• Journal of the Korean Chemical Society
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• v.27 no.5
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• pp.376-381
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• 1983

Dispersed nickel particles on Spherocarb were prepared at 540$^{\circ}C$ in various reaction atmosphere. Magnetic properties of these samples were determined, and results were compared with those of unsupported and MgO supported nickel particles. It was shown that nickel react primarily with carbon regardless of reducing atmosphere. In addition, apparent possibility of nickel-carbon interaction was discussed.

• Korean Chemical Engineering Research
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• v.46 no.6
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• pp.1025-1028
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• 2008

With the assistance of thermal pyrolysis process for hydrocarbon gases, the formation and growth of particulate carbon was systematically investigated as a function of temperature in the gas phase. The yield and average size of pyrocarbon particles were found to increase with increasing pyrolysis temperature. The difference in the yield of carbon particles generated by pyrolizing acetylene and ethylene gas posed a question about the role of hydrogen in the pyrolysis of hydrocarbon gases. In order to reveal the role of hydrogen, controlled amount of hydrogen was added to the acetylene pyrolysis, and then hydrogen addition was observed to suppress the formation and growth of carbon particles. One can control the size of pyrocarbon particles by controlling the hydrogen gas addition.