• Title/Summary/Keyword: 탄성고무

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Thermo-reversible Crosslinking Elastomer through Supramolecular Networks (초분자 네트워크를 이용한 열가역성 가교 탄성체)

  • Bae, Jong-Woo;Oh, Sang-Taek;Kim, Gu-Ni;Baik, Hyen-Jong;Kim, Won-Ho;Choi, Sung-Seen
    • Elastomers and Composites
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    • v.45 no.3
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    • pp.165-169
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    • 2010
  • Recently supramolecular network thermo-reversible crosslinking elastomer having flexibility, various functionality, and advantages of thermoplastic elastomer (TPE) such as recycle and easy processbility is introduced. Although thermo-reversible bonds such as hydrogen bond and ionic cluster is recognized as a common technology since 1990, control technology of bonding and dissociation of crosslink in supramolecular network is a recent technology. In this review, characteristics of thermo-reversible crosslinking elastomer having rheological properties of TPE and reinforcing behaviors of thermoset elastomer are summarized.

A Study on the Vulcanization Characteristics of SBR/BR Blends Containing Reinforcing Fillers (보강성 충전제가 첨가된 SBR/BR 블렌드의 가황특성에 관한 연구)

  • Lee, Seag
    • Elastomers and Composites
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    • v.33 no.4
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    • pp.274-280
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    • 1998
  • Order of reaction, rate constant, activation energy for vulcanization reaction, crosslinking density, and elastic constant of the network produced by sulfur curing were investigated on the SBR/BR blends containing silica and carbon black under same cure system. The reaction order was shown to be first order regardless of filler types. The carbon black filled rubber compounds showed higher rate constant compared to silica filled compounds. But activation energy appeared to be same regardless of filler type and rubber blend ratio. The crosslinking density and elastic constant is higher in the carbon black filled compound compared to silica filled compounds because of strong interaction between rubber and carbon black. On the other hand, crosslinking density and elastic constant were decreased with increasing the butadine rubber content in rubber blends. From the comparison of combined sulfur content in the vulcanized rubber, sulfur content in the silica filled compound become constant 20min later after reaction initiates but sulfur content in the carbon black filled compound become constant 10min later after reaction starts. The silica compound has a longer induction time ($t_2$) and optimum cure time($t_{90}$) compared to those of the carbon black filled compound.

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Shear Characteristics of Elastomeric Bearing Rubber Deteriorated by Accelerated Heat Aging(2): Chloroprene Rubber (가속열 노화로 열화된 탄성받침 고무재료의 전단 특성(2): 합성고무)

  • Sun, Chang-Ho;Kim, Ick-Hyun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.6
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    • pp.103-110
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    • 2021
  • Elastomeric bearings composed of flexible rubber materials and steel reinforcement plates are widely used for seismic retrofit of bridges due to their excellent vertical stiffness and flexible lateral stiffness. Especially, it has the advantages of simple construction and low cost. Chloroprene rubber, a type of rubber material, has greater resistance to aging than natural rubber, but its performance is also degraded due to various deterioration factors. Although these aging characteristics are not reflected in the seismic design standards and seismic performance evaluation guidelines, it is reasonable to reflect this when related studies are accumulated. For chloroprene rubber, accelerated heat aging test was performed with variables of heating temperatures and exposure time to analyze shear characteristics. As aging progresses the maximum shear stress and shear strain decrease. Also, the shear stiffness is greatly increased at the same shear strain.

2,6-Naphthalenedicarboxylate기를 함유하는 폴리에테르에스테르 탄성체의 열적, 동력학적성질에 관한 연구

  • 안태환;박연흠
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.04a
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    • pp.85-90
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    • 1998
  • 고무와 같은 유연성과 탄성을 가지면서 가유 필요없이 열가소성 성형기로 성형이 가능한 열가소성 탄성체는 1958년 E.I DuPont에 의해 폴리우레탄계 탄성섬유가 최초로 개발된 이래 낮은 생산원가와 대량생산이 쉬운 이점 때문에 많은 종류의 화합물이 개발되어 사용되고 있다.(중략)

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An Experimental Study on the Dynamic Characteristics of Rubber Isolator (실험에 의한 방진고무의 동특성에 관한 연구)

  • Kim, W.D.;Kim, K.S.;Kwon, J.D.;Woo, C.S.
    • Elastomers and Composites
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    • v.37 no.3
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    • pp.183-191
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    • 2002
  • Rubber materials with excellent damping property are widely applied for vibration isolators. The dynamic characteristics of the rubber materials for vibration isolators were investigated. Dynamic tests for rubber materials with five different hardness were performed. In dynamic tests for test specimen, non-resonance method was used to obtain the dynamic storage modulus and loss factor. Moreover, the effect of dynamic vibration frequency, strain amplitude and temperature were investigated. As results, the storage modulus and loss factor generally increase when the hardness and frequency increase, and the glass transition temperature is $-50^{\circ}C$ by a large change in modulus and loss factor.

Olefinic Thermoplastic Elastomer and Styrenic Thermoplastic Elastomer (올레핀/스티렌 열가소성 탄성체 및 올레핀/$\alpha$-올레핀 열가소성 탄성체)

  • Kim, Dong-Hyun;Kim, Hyun-Joon;Lee, Bum-Jae
    • Elastomers and Composites
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    • v.45 no.3
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    • pp.152-155
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    • 2010
  • Olefinic thermoplastic elastomer and styrenic thermoplastic elastomer have broad hardness range, high flexibility, low density, and excellent recyclability. But, they are limited in applications due to their low elasticity and low operating temperature. To overcome these problems, olefin/styrene or olefin/$\alpha$-olefin copolymers have been developed. In this review, we described some examples of olefin/styrene or olefin/$\alpha$-olefin copolymer and introduced their properties. Although olefin/styrene or olefin/$\alpha$-olefin copolymer have various weaknesses, they have a great potential in the future.

Dynamic Behaviour of Resilient Mounting System for the Marine Diesel Engine (선박용 디젤엔진 탄성지지계의 동적거동)

  • 김성춘;이돈출;김의간
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 1993.04a
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    • pp.80-85
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    • 1993
  • 본 논문에서는 디젤 엔진의 탄성지지계에 작용하는 엔진 기진력에 대하여 검토하고, 탄성지지계의 진동 양상과 탄성지지를 통하여 선체로 전달되는 힘 을 계산하는 과정을 정식화하였다. 또한 이 결과를 고무형 탄성지지를 갖는 선박 추진용 디젤엔진과 발전기용 디젤엔진에 적용하여 탄성지지계의 자유 진동과 강제진동 해석을 수행하고 발전기용 디젤엔진의 탄성지지계에 대해 서는 계측을 행하여 계산 결과와의 비교 검토를 행하고자 한다.

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Dynamic Mechanical Properties of Natural Rubber/Polystyrene IPNs (천연고무/폴리스티렌 IPN의 동적기계적 성질)

  • Do, In-Hwan;Kim, Byeong-Gyu
    • Korean Journal of Materials Research
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    • v.6 no.2
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    • pp.197-203
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    • 1996
  • 천연고무/폴리스티렌계 semi- 및 full-IPN의 동적성질을 IPN 조성과 가교도의 함수로 조사하였고, 23$^{\circ}C$에서의 탄성율을 선택하여 복합모델과 비교하였다. Full-IPN이 semi-IPN에 비해 상분리를 억제시키는 효과가 컸으며, 23$^{\circ}C$에서의 탄성율에서도 Davies 모델에 더 근접하였다. Coran-Patel 모델해석에서, 상전이의 중심이 되는 조성은 full-IPN의 경우 $\Phi$2=0.75-0.8이었다.

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나일론 6/폴리우레탄 탄성체 블렌드의 열적거동

  • 김지혜;지동선
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.10a
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    • pp.272-275
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    • 1998
  • 나일론 6은 우수한 내마모성 및 내약품성의 장점을 가지고 있으나 내열성 및 저온 내충격성이 취약하여 타이어 코드와 같은 산업용 소재로 도입할 경우 많은 문제점이 있다 따라서 이러한 문제점을 개선시키려는 연구가 활발히 진행되고 있으며 그 중에서도 나일론 6의 내충격성을 향상시키기 위한 방법으로 나일론 매트릭스 내에 고무상의 물성을 갖는 고분자를 분산상으로 도입한 연구[1]가 있으며, 최근에는 고무상의 물성을 갖는 고분자 대신에 나일론의 분자 구조와 유사한 열가소성 탄성체를 도입한 연구가 있다. (중략)

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