• Journal of the Korea institute for structural maintenance and inspection
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• v.26 no.5
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• pp.20-29
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• 2022

In this study, in order to improve the durability of the cement composite printed with the ME type 3D printer, PDMS, sodium silicate, and a surface hardener were employed. Post-treatment was performed on 3D-printed cement composite by coating after immersion, and the degree of improvement in durability was evaluated. As a result, in all evaluations, the durability performances of the post-processed specimens were improved compared to those of the plain specimens. Water absorption resistance, chloride penetration resistance, and carbonation resistance of the PDMS treated specimens were improved by 36.3 %, 77.1 %, and 50.4 % when compared to plain specimens. Freeze-thaw resistance of the specimens treated with sodium silicate was found to be the most excellent, with an average enhancement of 47.5% compared to plain specimens. It was found that PDMS was the most efficient post-treatment materials for 3D-printed cement composite. However, as suggested in this study, the post-treatment method by coating after immersion may not be applicable to cement composite structures printed with a 3D printer in field. Therefore, a follow-up study needs to be preformed on the durability enhancing materials suitable for 3D printing.

• Journal of the Korea Concrete Institute
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• v.19 no.1
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• pp.113-120
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• 2007

In this study, researches for the development of antibiotics and antimicrobial concrete were conducted to reduce biochemical corrosion of sewage concrete. First of all, desired performance, such as watertightness, antibiosis, homogeneity, workability and harmlessness, was proposed and performance of antibiotics and antimicrobial concrete were evaluated by them. As results of this study, dispersibility and antibiosis of liquid antibiotics superior to powdery antibiotics. Antibiosis of antimicrobial concrete was verified, and amount of elution of harmful and effective ingredients was little. In workability, setting time of antimicrobial concrete was delayed. Compressive strength and resistance to carbonation of antimicrobial concrete were more increased than ordinary concrete. Also, as little pore volume and closed structure of antimicrobial concrete were observed, watertightness of it was verified. Finally artificial accelerating test for biochemical corrosion was proposed, and its suitability was experimentally proved.

• Korean Journal of Heritage: History & Science
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• v.50 no.2
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• pp.40-61
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• 2017

This study investigated material characteristics of composition and variable strength measurement using physicochemical and petrographic analysis for lime-soil mixture barrier tombs of Guri Galmae site in Joseon Dynasty. The tomb barriers are composed mainly of microcrystalline calcite, quartz, feldspar and mica with lime matrix. The lime matrix shows compact sheet texture, and some samples show hydration aggregates with needle-shaped textures. Gypsum occurred as a secondary process where carbonization reactions were poor. Concentrations of CaO in the tomb barrier very widely ranged from 4.43 to 36.19 wt.%, specific gravity and absorption ratio of the materials show of 1.35 to 1.62 and 20.1 to 32.6%, respectively. As the rebound hardness, the materials ranged from 10.0 to 28.4 (mean 15.7). The values are higher in the $-90^{\circ}$ direction rather than in the $0^{\circ}$ direction with the consequence that the values indicate more strength toward the vertical direction. Difference in strength by directions was caused by the directions of the tomb barriers, which is related to the processes in each stage. In the tomb barriers, ultrasonic velocity and unconfined compressive strength ranged from 1,049.2 to 1,728.9m/s and under 5.00MPa, respectively. Variation patterns between the two are very similar in values. As the result of composition and strength, the materials of higher contents on CaO are higher in strength values. Generally, techniques and skills to make the lime-soil mixture barriers are interpreted as low qualities in relatively.

• Applied Chemistry for Engineering
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• v.33 no.4
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• pp.386-393
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• 2022

In this study, the surface modification of calcium carbonate (CaCO₃) nanoparticles by a silane coupling agent, octyltrimethoxysilane (OTMS), was investigated and characterized using Fourier transform infrared spectroscopy (FT-IR), differential scanning calorimetry (DSC), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and thermogravimetric analysis (TGA) analysis. Both floating tests and contact angle measurements were also conducted to study the effect of OTMS concentration on the hydrophobicity of CaCO₃ nanoparticles. It was found that the active ratio for the CaCO₃ nanoparticles modified by 1 wt% of OTMS was 97.0 ± 0.5%, indicating that OTMS is a very effective silane coupling agent in enhancing the hydrophobicity of the CaCO₃ nanoparticle surface. The most stable foam was generated with 1 wt% of CaCO₃ nanoparticles in aqueous solutions at 1 wt% of OTMS, where the contact angle of water was found to be 91.8 ± 0.7°. It was also found that the most stable emulsion drops were formed at the same OTMS concentration. These results suggest that CaCO₃ nanoparticles modified by a silane coupling agent OTMS are a powerful candidate for a foam stabilizer or an emulsifier in many industrial applications.

• Journal of the Korea Concrete Institute
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• v.19 no.1
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• pp.47-56
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• 2007

Recently, tunnels are increasingly constructed in this country with the increased construction of highways, high-speed railways and subways. Shotcrete is one of the major processes in the tunnel construction. Many problems, however, exist in the current shotcrete practice. The purpose of the study is, therefore, to explore the trobles in the current shotcreting practice, and to develop high-quality silica fume shotcrete. For the purpose of security a long-term durability of shotcrete, this study conducted combined deterioration tests. In this study, a combined deterioration test in consideration of a variety of deterioration factors were proceeded. Especially, micro-silica fume that was used frequently in overseas because of a outstanding strength-promotion effect was applied to combined deterioration test, and a long-term durability of shotcrete was investigated according to additions mixing. As a result of test, the shotcrete mixed Micro-silica fume showed a good deterioration quality compared with the other mixes. And is shows that the Micro-silica fume has an outstanding strength-promotion effect and is effective to secure a long-term durability of shotcrete by means of decreasing a deterioration caused by steel fiber mixed.

• Journal of the Korea Institute of Building Construction
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• v.15 no.3
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• pp.265-271
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• 2015

This study is intended to produce a PC (Precast Concrete) member without a steam curing process in developing the high early strength concrete satisfying the condition of 10MPa in compressive strength at the age of 6 hours, and is intended to ensure economic feasibility by increasing the turnover rate of concrete form. Hence, high early strength cement with high $C_3S$ content and the hardening accelerator of powder type accelerating the hydration of $C_3S$ was used. And the properties of concrete were evaluated according to the hardening accelerator mixing ratio (0, 1.2, 1.6, 2.0). No big difference was found from the tests of both slump and air content. When 1.6 % or higher amounts of the hardening accelerator were mixed, the compressive strength of 10MPa was achieved at the age of 6 hours. From the test results of autogenous (drying) shrinkage and plastic shrinkage, it can be seen that there was a difference according to hydration reaction rate due to the addition of the hardening accelerator. However, it was shown that no problem arose with crack and durability. And it was shown that resistance to freezing-thawing, carbonation, and penetration were excellent.

• Journal of the Korean Geotechnical Society
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• v.22 no.10
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• pp.77-91
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• 2006

Domestic practices in shotcrete use have developed in many respects even now, but it still has issues about material, construction, quality standard and so on. In overseas, the construction using high strength shotcrete with $39.2{\sim}58.8 MPa$ of compressive strength is becoming common based on the shotcrete technology of high strength and durability. However, domestic shotcrete design strength is low at around 20.6 MPa of compressive strength and a long term durability is also insufficient. In this paper, field tests using high-quality additives and accelerators were performed to obtain the improvement of shotcrete strength and EFNARC standard was used to evaluate the field test results. In addition, deterioration test combined with the freezing-thawing and carbonation was also performed in order to investigate a long-term durability of high-strength shotcrete. As a result of the field test, the promotion ratio of early strength was $90{\sim}97%$ in case of using alkali-free accelerators. And the compressive strength of the shotcrete using Micro-silica fume was $45.2{\sim}55.8MPa$ and flexible strength was $5.01{\sim}6.66MPa$, so the promotion ratio of strength was $37{\sim}79%$ and $17{\sim}61%$ respectively. The promotion effect of strength by silica fine additives ratio of $7.5{\sim}10%$ for cement mass was much superior to the other cases. It was especially examined that using Micro-silica fume reduced deterioration due to mixed steel fiber and improved a long-term durability of shotcrete.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.3
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• pp.88-93
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• 2011

To resolve the problem which is demand and supply imbalance of fine aggregate by the shortage of natural fine aggregate and the environment regulations, the studies for the application of recycled fine aggregate made from waste concrete have been recently carried out. The objective of this study is to shed light on the mechanical properties and durability performance of concrete using recycle fine aggregate with various water to cement ratios and unit water contents. And it is intend to propose the fundamental data for structural application of recycled concrete. In particular, the effects according to the variations of water to cement ratios and unit water contents in recycled concrete with recycled fine aggregate replacement of 100 percent are discussed by the test results, such as air content, slump, time of set, compressive strength, tensile strength, carbonation, chloride penetration.

• Journal of the Korean Recycled Construction Resources Institute
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• v.1 no.3
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• pp.233-239
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• 2013

This study is interested in manufacturing the self-cleaning silicate concrete surface impregnant including tetra ethyl ortho silicate, lithium silicate for the repair of the exposed concrete surface and the color concrete requiring the advanced function in view of the concrete appearance. The concrete surface layer change and static contact angel was tested for the review of application. The result of this study shows that the effective silicate is tetra ethyl ortho silicate and lithium silicate. The adhesion in tension is satisfied with performance requirement of KS standard but the reinforcement of concrete substrate is slight. So, The self-cleaning silicate concrete impregnant of this study is more desirable for the improvement of durability rather than the reinforcement.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.1
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• pp.120-127
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• 2011

Recently, there are problems due to the exhaustion of natural aggregate resources, and strict restrictions. In this study, the possibility of using Water Granulated Ferro-Nickel slag as a substitutive material of fine aggregate is determined from the properties of mechanical and durability for the concrete that is made with Water Granulated Ferro-Nickel slag. According to the test results, when the mixing rate of Water Granulated Ferro-Nickel Slag aggregates concrete is adjusted, up to 50% of its aggregates by mixing rate can be mixed with general aggregates. The optimum mix ratio is considered to be 40%. The freezing and thawing resistance of Water Granulated Ferro-Nickel Slag aggregates concrete is identical to that of general aggregates concrete, while the carbonation resistance is found to be same as or lower than that of general aggregates concretes.