• Proceedings of the Computational Structural Engineering Institute Conference
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• 2010.04a
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• pp.770-772
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• 2010

기존의 연구는 열화에 의한 물리적 평가 및 열화에 영향을 미치는 수화생성물의 존재여부에 대한 연구는 활발하게 이루어지고 있으나, 그에 따른 수화생성물의 정량화에 대한 연구는 미흡한 실정이다. 본 논문은 XRD 분석 기법을 이용하여 원전 콘크리트 구조물에 대해 열화요인 중 탄산화와 황산염에 대한 상대적 정량화에 대한 연구를 실시하였다. 두 열화인자는 콘크리트 내의 수산화칼슘과 반응하여 에트린가이트와 탄산칼슘을 생성하게 되는데, 본 연구에서 열화인자에 대한 노출기간이 증가할수록 열화에 영향을 미치는 수화 생성물이 증가하는 것을 확인 할 수 있었다. 그에 따른 수산화칼슘의 양이 감소하는 것도 확인 할 수 있었다.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.22 no.5
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• pp.254-259
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• 2012

The mechanical property enhancement was studied using fly ash produced from fluidized bed type boiler in power plant, which contains a lot of Ca component being used to carbonate for $CO_2$ fixation in the lightweight aggregates made of cement and some portion of fly ash as a cement substitution under the supercritical condition. Specimens having various fly ash substitution rates and curing periods were carbonated under the supercritical condition at $40^{\circ}C$. The weight change rate, carbonation rate by TG/DTA analysis, 1% Phenolphthalein test, specific gravity and mechanical compression strength test were performed to observe the mechanical property enhancement of the cemented materials after carbonation under the supercritical condition and to make sure those could be classified as lightweight aggregates having specific gravity under 2.0.

• Journal of the Korea Institute of Building Construction
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• v.14 no.1
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• pp.21-28
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• 2014

The purpose of this study is to investigate the mechanical properties and carbonation resistance of concretes using lightweight aggregate coated surface finishing materials. To evaluate the mechanical properties and carbonation resistance of concrete, slump, air amount, air-dried unit volume weight, compressive strength, and carbonation depth are tested. In terms of the unit volume weight of concrete, air-dried unit volume weight of concrete using coating lightweight aggregate was measured as $1,739{\sim}1,806kg/m^3$. When using coating aggregate, compressive strength of concrete at 28 days was measured as much as 82.7~95.9% of the compressive strength using non-coating aggregate. It is found that compressive strength tends to decrease with coating lightweight aggregate. However, all concretes using coating lightweight aggregate except O-LWAC satisfied the criteria for 28-day compressive strength suggested in KS. The measurement of carbonation depth when the water-repellent agent was used found that carbonation depth was reduced by as much as 2.6~6.1%. On the other hand, when using polymer waterproof agent, carbonation depth was reduced by as much as 8.6~12.0%. Consequently, to improve carbonation resistance, polymer waterproof agent was more effective than water-repellent agent. In particular, epoxy showed the most outstanding performance.

• Journal of the Korea institute for structural maintenance and inspection
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• v.14 no.5
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• pp.119-127
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• 2010

This paper provides a new approach for durability prediction of reinforced concrete structures exposed to carbonation. In this method, the prediction can be updated successively by a Bayes' theorem when additional data are available. The stochastic properties of model parameters are explicitly taken into account in the model. To simplify the procedure of the model, the probability of the durability limit is determined based on the samples obtained from the Latin Hypercube Sampling(LHS) technique. The new method may be very useful in design of important concrete structures and help to predict the remaining service life of existing concrete structures which have been monitored. For using the new method, in which the prior distribution is developed to represent the uncertainties of the carbonation velocity using data of concrete structures(3700 specimens) in Korea and the likelihood function is used to monitor in-situ data. The posterior distribution is obtained by combining a prior distribution and a likelihood function. Efficiency of the LHS technique for simulation was confirmed through a comparison between the LHS and the Monte Calro Simulation(MCS) technique.

• Economic and Environmental Geology
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• v.53 no.1
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• pp.1-9
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• 2020

Magnesium silicate minerals such as serpentine [Mg₃Si₂O₅(OH)₄] have a high potential for the sequestration of CO₂; thus, their reactivity toward dissolution under CO₂-free and CO₂-containing conditions in acidic solvents is a critical process with respect to their carbonation reactions. To examine the carbonation efficiency and dissolution mechanism of serpentine, hydrothermal treatment was performed to the starting material via a modified direct aqueous carbonation process at 100 and 150℃. The serpentine dissolution experiments were conducted in H₂SO₄ solution with concentration range of 0.3-1 M and at a CO₂ partial pressure of 3 MPa. The initial pH of the solution was adjusted to 13 for the carbonation process. Under CO₂-free and CO₂-containing conditions, the carbonation efficiency increased in proportion to the concentration of H₂SO₄ and the reaction temperature. The leaching rate under CO₂-containing conditions was higher than that under CO₂-free conditions. This suggests that shows the presence of CO₂ affects the carbonation reaction. The leaching and carbonation efficiencies at 150℃ in 1 M H₂SO₄ solution under CO₂-containing conditions were 85 and 84%, respectively. The dissolution rate of Mg was higher than that of Si, such that the Mg : Si ratio of the reacted serpentine decreased from the inner part (approximately 1.5) to the outer part (less than 0.1). The resultant silica-rich layer of the reaction product ultimately changed through the Mg-depleted skeletal phase and the pseudo-serpentine phase to the amorphous silica phase. A passivating silica layer was not observed on the outer surface of the reacted serpentine.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.1
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• pp.85-93
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• 2017

This paper presents mechanical properties and carbonation behavior of the recycled aggregate concretes(RAC) in which natural aggregate was replaced by recycled coarse aggregate and fine aggregate by specified concrete strength levels(21, 35, 50MPa). A total of 18 RAC were produced and classified into six series, each of which included three mixes designed with three specified concrete strength levels of 21MPa, 35MPa and 50MPa and three recycled aggregate replacement ratios of 0, 50 and 100%. Physical and mechanical properties of RAC were tested for slump test, compressive strength, and carbonation depth. The test results indicated that the slump of RAC could be improved or same by recycled coarse aggregate replacement ratios, when compared with natural aggregate. But slump of RAC was decreased as the recycled fine aggregate replacement ratios increase. Also, the test results showed that the compressive strength was decreased as the recycled aggregate replacement ratios increased and it had a conspicuous tendency to decrease when the content of the recycled aggregate exceeded 50%. Furthermore, the result indicated that the measured carbonation depth increases by 40% with the increase of the recycled aggregate replacement. In the case of the concrete having low level compressive strength, the increase of carbonation depth tends to be higher when using the RCA. However, the trend of carbonation resistivity in high level compressive strength concrete is similar to that obtained in natural aggregate concrete. Therefore, an advance on the admixture application and mix ratio control are required to improve the carbonation resistivity when using the recycled aggregate in large scale.

• Journal of the Korea Concrete Institute
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• v.28 no.3
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• pp.341-348
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• 2016

At present, about 40 million tons of concrete is dismantled each year, which accounts for the largest portion of the total amount of construction waste with 60.8%. It is known about 97.5% of it is recycled. However, most of the usage of waste concrete is limited to lower value-added business areas, and considering the increasing amount of waste concrete generated due to the deterioration of structures, the need for converting waste concrete to structural concrete is urgent. Therefore, this study aims at estimating the period for the optimum carbonation reforming to improve the quality of recycled aggregate, by making use of the method of accelerated carbonation reforming of the bonding heterogeneous (cement paste and mortar) for the purpose of converting recycled aggregate to structural concrete. Based on the period appropriate for the heterogeneous thickness and each bonding thickness of recycled aggregate which was drawn from previous studies, the changes in the characteristics and physical properties of pore structure according to progress of accelerated carbonation were analyzed. The result shows that with the progress of carbonation, the pore volume and the percentage of water absorption of the bonding heterogeneous decreased and the density increased, which indicates improvement of the product quality. But after certain age, the tendency was reversed and the product quality deteriorated. Synthesizing the results of previous studies and those of the present study, this study proposed 4 days and 14 days respectively for the period for the optimum carbonation reforming of recycled fine aggregate and recycled coarse aggregate.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.4
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• pp.324-331
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• 2023

In this study, the hydration and carbonation properties of circulating fluidized bed boiler (CFBC) ash with different free-CaO contents were investigated. In addition, the possibility of utilizing CFBC ash with a high free-CaO content as a cementitious material was investigated by carbonation curing as a pretreatment. The CFBC ash with high free-CaO content exhibited rapid setting behavior and low early compressive strength when mixed with cement. For CFBC ash with high free-CaO content, carbon dioxide capture increased with the duration of carbonization curing. In addition, the free-CaO value decreased together, indicating that the free-CaO reacted with carbon dioxide. When the CFBC ash with high free-CaO content was pretreated by carbonation, no fresh set appeared, and the initial compressive strength was improved. From the results of this study, it is confirmed that CFBC ash with high free-CaO content has a high potential to be utilized as a cementitious material through proper carbonation curing.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.1017-1020
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• 2008

Carburization at concrete structures is being processed independently or compositively and each unique Carburization will appear depending on the condition of circumstance. Therefore, the depletion rate was being estimated at this research for buildings and civil construction structures of different environments and of more than 10 - 60 years old by calculating the depth of carburization and the density of Alkali. As the results of the test, buildings (interior) had a deeper and a faster carburization than civil construction structures being exposed to open air as closer to the shore. And also, concrete structures being used as an underdrain of sewage were proven to have a deeper carburization than utility-pipe conduits or underground tunnels.

• Magazine of the Korea Concrete Institute
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• v.7 no.4
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• pp.149-156
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• 1995

The fracture process zone in concrete is a region ahead of a traction-free crack, in which two major mechanisms, microcracking and bridging, play important roles. The toughness due to bridging is dominant compared to toughness induced by microcracking, so that the bridging is dominani: mechanism governing the fracture process of concrete. Fracture mechanics does work for concrete provided that the fracture process zone is being considered, so that the development of model for the fracture process zone is most important to describe fracture phenomena in concrete. In this paper the bridging zone, which is a part of extended rnacrocrack with stresses transmitted by aggregates in concrete, is modelled by a Dugdale-Barenblatt type model with linear tension-softening curve. Two finite element techniques are shown for the analysis of progressive cracking in concrete based on the discrete crack approach: one with crack element, the other without crack element. The advantage of the technique with crack element is that it dees not need to update the mesh topology to follow the progressive cracking. Numerical results by the techniques are demonstrated.