• Analytical Science and Technology
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• v.12 no.3
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• pp.230-234
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• 1999

Barium titanyl oxalates (BTO) has been homogeneously prepared by thermal decomposition of dimethyl oxalate (DMO) in hydrochloric solution containing $Ba^{2+}$ and $Ti^{4+}$. Particles of BTO settled on the bottom of the beaker were collected at the aging time of 120 min using hydroxy propyl cellulose (HPC) as a dispersant. The reaction temperature, the concentration ratio of $[DMO]_0/([Ba^{2+}]_0+[Ti^{4+}]_0)$ and the existence of HPC were found to influence on morphologies of BTO, chemical yields and characteristics of barium titanates formed from their precursors.

• Journal of the Korean Chemical Society
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• v.39 no.7
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• pp.578-584
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• 1995

An aqueous solution of $Ca(OH)_2$ containing a small amount of dissolved $Sr(OH)_2$ was carbonated with $CO_2$ gas, and the effects of the reaction temperature and $Sr(OH)_2$ on the carbonation were investigated. The higher the reaction temperature and the larger the ratio of $Sr(OH)_2(aq)$ to $Ca(OH)_2(aq)$, which amounts to the larger the ratio of $OH^-$ to $CO_2(aq)$, the better pillar aragonite was formed. $Sr(OH)_2$ played an important role in the formation of pillar aragonite, because it is easily formed itself into rhombic $SrCO_3$ during the initial period of carbonation process and acting as a seed for the pillar aragonite of similar morphology. In addition, due to its substantially higher solubility compared with $Ca(OH)_2$, $OH^-$ concentration in the carbonation mixture and subsequently $CO_3^{2-}$ necessary for the crystal growth are increased.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.14 no.3
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• pp.110-114
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• 2004

Formation behavior of aragonite precipitated calcium carbonate was investigated with changed the concentration of $Na_2CO_3$ solution and addition method which added in the $Ca(OH)_2$ slurry at $75^{\circ}C$. In this reaction, we found that $Na^+$ ions were substituted into $Ca^{2+}$ion site then disturb the growth of calcite, and while proceed the crystal growth in a certain direction and promote the formation of aragonite. Also, a decrease of reaction rate by control the concentration of $CO_3^{2-}$ ion, induce the homogeneous precipitate reaction and increase substitution ability of $Na^+$ ions, consequently it was promote the formation and growth of aragonite.

• Journal of the Korean Applied Science and Technology
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• v.33 no.2
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• pp.239-246
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• 2016

In this study, recycling sludge water of Ready-mixed concrete, and was carried out to optimize the system for recycling of the $CO_2$. The most important process in the liquid phase using a carbonation reaction can be recovered ready-mixed concrete is a process for the $Ca^{2+}$ release. $Ca^{2+}$ concentration of the experiment relative to the pH being lowered by the acidic substance during elution was performed. $CO_2$ was trapped in the MEA solution using a generator flue gas. In ready-mixed concrete can be synthesized $CaCO_3$ up to 11kg/1ton. The resulting $CaCO_3$ analysis results show that it is possible to use paper industry.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.30 no.2
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• pp.291-296
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• 1997

The dietary fiber contents of seaweeds including Drown algae (Undaria pinnatifida, Laminaria japonica, Hizikia fusiforme), red algae (Gelidium amansii, Gracilaria verrucosa) and green algae (Ulva lactuca) and the extraction condition of the fiber was investigated. The dietary fiber contents of Undaria pinnatifida, Laminaria japonica, Hizikia jusiforme, Gelidium amansii, Gracilaria verrucosa and Ulva lactuca were $47.2\%,\;50.7,\;42.6\%,\;48.8\%,\;44.5\%\;and\;40.0\%$, respectively. It was effective to extract soluble dietary fiber with sodium salts such as disodium carbonate and disodium EDTA in brown algae. In red algae, it was effective to extract soluble dietary fibre with disodium EDTA. Also, the extraction time and temperature affected the yields of dietary fiber.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.3
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• pp.2301-2307
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• 2015

The aim of this study was to evaluate the feasibility of application of the high voltage impulse (HVI) technique to the control of scale formation by calcium carbonate, which is pointed out as an important issue in industrial water treatment. The HVI system consisted of the power supply, high voltage generator, capacitors, switch and impulse generator was designed and made in laboratory scale, which can make 17kV impulse. HVI was introduced to the reactor that was filled with synthetic water containing $Ca^{2+}$ion. The concentration of calcium ion decreased only 3.0% after 5 minutes of contact time. However, it decreased up to 13.7% after 60 minutes of HVI contact time. Temperature and pH increased but conductivity decreased due to precipitation of the calcium carbonate. Although the decrease in concentration of calcium ion was not sufficient, it was verified that the HVI technique could be applicable for the softening and desalting processes.

• Journal of the Korean Institute of Gas
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• v.22 no.5
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• pp.53-61
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• 2018

Low-salinity water based polymerflooding (LSPF) is one of promising enhanced oil recovery (EOR) method that has the synergetic effect of combining polymer injection method and low-salinity water injection method. In order to maximize EOR efficiency, it is essential to design low-salinity water appropriately considering the properties of polymer. In this aspect, the main purpose of this study is to investigate the effect of pH and $SO_4{^{2-}}$ ion which one of PDI (Potential Determining Ion) on oil production when applying LSPF to carbonate oil reservoir. First, the stability and adsorption of polymer molecule were analyzed in different pH of injection water and $SO_4{^{2-}}$ concentration in injection water. As a result, regardless of pH and $SO_4{^{2-}}$ concentration, when $SO_4{^{2-}}$ ion was contained in injection water, the stability of polymer solution was obtained. However, from the result of polymer retention analysis, in neutral state of injection water, since $SO_4{^{2-}}$ interfered the adsorption of polymer, the adsorption thickness of polymer was thinner as $SO_4{^{2-}}$ concentration was higher. On the other hand, when injection water was acidic as pH 4, the amount of polymer adsorption increased with the injection of polymer solution, so the mobility of polymer solution was greatly lowered. From the results of wettability alteration due to low-salinity water effect, in the case of neutral injection water injected, as $SO_4{^{2-}}$ concentration was increased, more oil which attached on rock surface was detached, altering wettability from oil-wet to water-wet. On the other hand, in acidic condition, due to complex effect of rock dissolution and polymer adsorption, wettability of the entire core system was less altered relatively to neutral condition. Therefore, it was evaluated that better EOR efficiency was obtained when injecting low-salinity water based polymer solution containing high concentration of $SO_4{^{2-}}$ with neutral condition, enhancing the oil production up to 12.3% compared to low-salinity water injection method.

• Journal of the Mineralogical Society of Korea
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• v.2 no.2
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• pp.90-99
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• 1989

Manganese deposits ar the Dongnam mine occur as vein in the Pungchon limestone of Ordovician age. Manganese ore veins consist of the hydrothermal manganese carbonate ores in the deeper part and the supergene manganese oxide ores in the shallow part. Manganese carbonate ores consist mainly of rhodochrosite, with minor amount of proxmangite, garnet, calcite, quartz, pyrite, galena and sphalerite. Manganese oxide ores consist of rancieite, buserite, birnessite, vernadite, todorokite, pydrolusite, nsutite, hydrohetaerosite and goethite. Manganese oxide minerals were formed in the following sequences; 1) rhodochrosite ${\rightarrow}$ vernadite ${\rightarrow}$ birnessite ${\rightarrow}$ nsutite ${\rightarrow}$ pyrolusite, 2) pyroxmangite ${\rightarrow}$ birnessite, 3) Buserite ${\rightarrow}$ ransieite. Todorokite, buserite and hydrohetaerolite were precipitated from solution in the later stage. The natural analogue of synthetic buserite has been discovered from the mine. It has been disclosed that buserite transforms to rancicite by dehydration, and that distinction between buserite and todorokite is possible by X-ray diffraction studies combined with dehydration experiment. Minerals identified from the mine have been characterized using various methods including polarizing microscopy, X-ray diffraction, thermal analysis, infrared spectroscopy, X-ray diffraction, thermal analysis, infrared spectroscopy, elecrton microscopy and dehydration experiment.

• Resources Recycling
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• v.28 no.4
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• pp.30-36
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• 2019

In this study, Li powder was recovered from the by-product of LNO ($Li_2NiO_2$) process, which is the positive electrode active material of waste lithium ion battery, through the $CO_2$ thermal reaction process. In the process of recovering Li powder, the $CO_2$ injection amount is 300 cc/min. The $Li_2NiO_2$ award was phase-separated into the $Li_2CO_3$ phase and the NiO phase by holding at $600^{\circ}C$ for 1 min. After this, the collected sample:distilled water = 1:50 weight ratio, and after leaching, the solution was subjected to vacuum filtration to recover $Li_2CO_3$ from the solution, and the NiO powder was recovered. In order to increase the purity of Ni, it was maintained in $H_2$ atmosphere for 3 hours to reduce NiO to Ni. Through the above-mentioned steps, the purity of Li was 2290 ppm and the recovery was 92.74% from the solution, and Ni was finally produced 90.1% purity, 92.6% recovery.

• Journal of the Korean GEO-environmental Society
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• v.3 no.4
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• pp.37-49
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• 2002

In this study, it is performed that mix design of grouting materials which high strength, durability and environmentally safe materials for 2 types of suspension, solution grouting. The laboratory model tests such as permeation, solidification tests are performed to find injection effects by the injection pressure, soil condition. And environmental effects of the grouting materials is analyzed through the heavy-metal leaching tests. From the results, micro cement of suspension grouting superior permeation, solidification injection to Portland cement, and phosphoric acid and sodium hydrogen carbonate in solution grouting were similar to micro cement of suspension grouting. When compare to strength of grouted soils, micro cement of suspension grouting showed high compression strength to Portland cement. While, solution grouting showed very low compression strength comparing suspension grouting. Also, in the heavy-metal leaching tests results were satisfied with the environmental regulation standard for raw grouting materials and grouted soil by 7, 14, 28days curing.