• The Korean Journal of Quaternary Research
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• v.25 no.2
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• pp.17-24
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• 2011

We investigated the variation of $CaCO_3$ contents in cores PC1 and PC2 recovered from the continental slope area of the Ulleung Basin in the East Sea. $CaCO_3$ contents of cores PC1 and PC2 varied between 0.6 and 17.2% and between 0.3 and 43.0%, respectively. $CaCO_3$ contents in the upper part of core PC1 corresponding to MIS 1 are less than 5%, whereas those in the lower part of MIS 2 are more than 10%. Such variation of $CaCO_3$ contents in core PC1 confirms the previous results of $CaCO_3$ studies in the East Sea. In core PC2, $CaCO_3$ contents of the upper part are similar to those of core PC1. However, $CaCO_3$ contents in the lower part of core PC2 are more than 40%. According to XRD operation and SEM examination, the high $CaCO_3$ contents in the lower part of core PC2 are more attributable to the authigenic carbonate minerals rather than the biogenic carbonate composition. Such abundant authigenic carbonate minerals are closely related to the dissociation of methan hydrates which were observed in the Ulleung Basin.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.7
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• pp.515-520
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• 2009

This study investigated the influence of oxyanions (nitrate, carbonate, phosphate) on the attachment of bacteria (Bacillus subtilis) to Al-Fe bimetallic oxide-coated sand using column experiments. Results showed that bacterial attachment to the coated sand was independent of nitrate concentration. Bacterial mass recovery remained constant (10.9${\pm}$0.2%) with varying nitrate concentrations (0.1, 1, 10 mM). In case of carbonate, mass recovery increased from 25.6% to 39.0% with increasing carbonate concentration from 0.1 mM to 1 mM, and mass recovery also increased from 50.9% to 78.9% at the same concentration condition in case of phosphate. This phenomenon could be attributed to the hindrance effect of carbonate and phosphate to bacterial attachment to the coated sand. Meanwhile, with increasing carbonate/phosphate concentration from 1 mM to 10 mM, mass recovery decreased from 39.0% to 23.8% and from 78.9% to 52.6%, respectively. This phenomenon could be ascribed to the enhancement effect of free carbonate/phosphate ions present in solution phase due to increasing carbonate/phosphate concentration, which increase ionic strength and thus enhance bacterial attachment to the coated sand. In our experimental conditions, the effect of phosphate to bacterial attachment to the coated sand was the greatest among phosphate, carbonate, and nitrate.

• Proceedings of the Korean Quaternary Association Conference
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• 2004.11a
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• pp.4-13
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• 2004

제주도 북제주군 한림읍 협재리에는 대부분 탄산염퇴적물로 이루어진 해안사구가 분포하고 있다. 사구를 이루는 탄산염퇴적물은 연체동물과 홍조류의 조각이 약 80% 이상을 차지하며 그 외에 저서성 유공충, 성게류와 태선동물의 조각, 그리고 화산암편으로 이루어져 있어, 제주도에 분포하는 여러 탄산염 해빈퇴적물의 입자조성과 매우 유사한 경향을 나타낸다. 이러한 탄산염 입자들은 천해에 서식하던 해양생물들에 의해 생성되며, 그 각질이 해빈으로 운반되고 바람에 의해 재동되어 사구를 형성하였다. 특히 이 연구지역의 사구가 분포하는 지점에서 북쪽으로 약 1km 떨어져 있는 협재 해수욕장에는 현재에도 천해에서 생성된 많은 양의 탄산염 해빈퇴적물이 퇴적되어 있으며, 제주도의 타 지역에 비해 매우 빠른 북동${\sim}$북서방향의 바람이 불고 있어, 퇴적물을 해빈에서부터 사구형성지점으로 운반시키는 데 효과적인 역할을 했을 것으로 판단된다. 사구를 절개하여 그 단면을 관찰한 결과, 전반적으로 희미한 수평층리와 사층리가 발달하고 있으며, 그 외의 다른 뚜렷한 퇴적구조는 관찰되지 않는다. 퇴적물의 입자들은 주로 직경이 $0.27{\sim}0.40mm$로 중립질 모래에 해당한다. 이 크기의 입자들은 가장 침식이 잘 될 수 있는 입자크기에 해당하는 것으로 알려져 있으며, 따라서 해빈으로부터 퇴적물이 운반될 때에 특히 이 크기의 입자들이 차별적으로 더 많이 운반되었을 것이라고 생각된다. 또한 퇴적물 입자의 크기와 구성성분의 함량은 각 사구의 전 층준에서 크게 변화하지 않는 것으로 나타나며, 이는 사구가 형성되는 기간 동안 탄산염퇴적물을 운반한 바람의 세기가 어느 정도 일정하였음을 지시한다. 해안사구의 형성시기를 알아보기 위하여 사구의 기반을 이루는 고토양층과 사구 최하부와 최상부의 탄산염퇴적물에 대해 방사성탄소연대측정을 실시하였다. 그 결과, 사구의 형성시기를 지시하는 고토양의 연령은 $680{\sim}720\;BP\;(1,200{\sim}1,300\;AD)$로 측정되었으며, 사구를 이루는 탄산염퇴적물의 연령은 전 층준에서 모두 약 3,500 BP로 측정되었다. 따라서 약 3,500 BP에 천해에서 생성된 탄산염퇴적물이 해빈에 분포하다가 $1,200{\sim}1,300\;AD$에 바람에 의해 재동되고 현재의 위치에 쌓여 사구를 형성한 것이라고 해석할 수 있다. 사구가 형성되기 시작하던 시기는 전세계적으로 춥고 바람이 세었던 Little Ice Age ($1,300{\sim}1,820\;AD$)에 해당하며, 따라서 해빈에 분포하던 많은 양의 탄산염퇴적물이 이 시기에 집중적으로 운반된 것으로 사료된다.

• Economic and Environmental Geology
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• v.52 no.5
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• pp.381-393
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• 2019

Carbonate breccias occur sporadically in the Middle Cambrian Daegi Formation on the southern limb of the Baegunsan Syncline, Taebaeksan Basin. These carbonate breccias have been largely interpreted either as sedimentary breccias or as tectonic, fault-related breccias. Recent study, however, indicates that the majority of these breccias are a solution-collapse breccia which is causally linked to the paleokarstification. Extensive karstification is attributed to prolonged subaerial exposure of the carbonate platform. The exposed surface is a record of interruption in sedimentation on the carbonate platform. In the stratigraphic record, such karst-related post-depositional features are recognized as meteoric diagenetic features, paleosols, and solution-collapse breccias. Solution-collapse breccias are particularly well preserved and most profound in the carbonate rocks below the major unconformities, which also are evidence of prolonged subaerial exposure. The Middle Cambrian Daegi Formation provides an example of solution-collapse breccias. The formation and preservation of the solution-collapse breccias imply that a stratigraphic discontinuity surface (unconformity) can be designated within the Daegi Formation.

• Economic and Environmental Geology
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• v.45 no.3
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• pp.317-333
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• 2012

The Yeongweol Group is a Lower Paleozoic mixed carbonate-siliciclastic sequence in the Taebaeksan Basin of Korea, and consists of five lithologic formations: Sambangsan, Machari, Wagok, Mungok, and Yeongheung in ascending order. Sequence stratigraphic interpretation of the group indicates that initial flooding in the Yeongweol area of the Taebaeksan Basin resulted in basal siliciclastic-dominated sequences of the Sambangsan Formation during the Middle Cambrian. The accelerated sea-level rise in the late Middle to early Late Cambrian generated a mixed carbonate-siliciclastic slope or deep ramp sequence of shale, grainstone and breccia intercalations, representing the lower part of the Machari Formation. The continued rise of sea level in the Late Cambrian made substantial accommodation space and activated subtidal carbonate factory, forming carbonate-dominated subtidal platform sequence in the middle and upper parts of the Machari Formation. The overlying Wagok Formation might originally be a ramp carbonate sequence of subtidal ribbon carbonates and marls with conglomerates, deposited during the normal rise of relative sea level in the late Late Cambrian. The formation was affected by unstable dolomitization shortly after the deposition during the relative sea-level fall in the latest Cambrian or earliest Ordovician. Subsequently, it was extensively dolomitized under the deep burial diagenetic condition. During the Early Ordovician (Tremadocian), global transgression (viz. Sauk) was continued, and subtidal ramp deposition was sustained in the Yeongweol platform, forming the Mungok Formation. The formation is overlain by the peritidal carbonates of the Yeongheung Formation, and is stacked by cyclic sedimentation during the Early to Middle Ordovician (Arenigian to Caradocian). The lithologic change from subtidal ramp to peritidal facies is preserved at the uppermost part of the Mungok Formation. The transition between Sauk and Tippecanoe sequences is recognized within the middle part of the Yeongheung Formation as a minimum accommodation zone. The global eustatic fall in the earliest Middle Ordovician and the ensuing rise of relative sea level during the Darrwillian to Caradocian produced broadly-prograding peritidal carbonates of shallowing-upward cyclic successions within the Yeongheung Formation. The reconstructed relative sea-level curve of the Yeongweol platform is very similar to that of the Taebaek platform. This reveals that the Yeongweol platform experienced same tectonic movements with the Taebaek platform, and consequently that both platform sequences might be located in a body or somewhere separately in the margin of the North China platform. The significant differences in lithologic and stratigraphic successions imply that the Yeongweol platform was much far from the Taebaek platform and not associated with the Taebaek platform as a single depositional system. The Yeongweol platform was probably located in relatively open shallow marine environments, whereas the Taebaek platform was a part of the restricted embayments. During the late Paleozoic to early Mesozoic amalgamations of the Korean massifs, the Yeongweol platform was probably pushed against the Taebaek platform by the complex movement, forming fragmented platform sequences of the Taebaeksan Basin.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.29 no.6
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• pp.329-337
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• 2019

We synthesized potassium titanates having splinter and plate shape and evaluated frictional and wear properties of brake pad using them as reinforcements in friction materials. For splinter-shaped potassium titanates, potassium tetratitanate (K₂O·4TiO₂, PT4) with plate shape was prepared, then K ion of the titanate was leached by acid to make potassium hexatitanate (K₂O·6TiO₂, PT6), which was transformed to splinter-shaped PT6 by thermal treatment at 800℃. Plate-shaped potassium magnesium titanate (K_0.8Mg_0.4Ti_1.6O₄, PMT) was prepared by adding Mg in the potassium titanate using KCl as a flux. Using PT6 and PMT as reinforcements in friction materials of brake pad, we evaluated frictional and wear properties using 1/5-scale dynamometer. According to dynamometer test results, both reinforcements shows similar friction coefficient and fade & recovery behavior to conventional material and plate-shaped PMT exhibits higher wear resistance than splinter-shaped PT6.

• Journal of the Mineralogical Society of Korea
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• v.13 no.1
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• pp.22-36
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• 2000

중원지역 지열수의 CO2 가스의 용축과 수반된 탄산염 침전물의 광물학적 특성을 밝히기 위하여 탄산염 침전물에 대해 광물학적 및 지구화학적 분석방법을 적용하여 보았다. 이들은 매년 수 mm의 두께로 저수조내에 침전되며 미세한 층상으로 결정화되어 있고, 검은 갈색의 얇은 층들이 반복적으로 존재하고 있다. 침전물은 비교적 순수한 방해석으로 되어 있으며 1M HCl로 처리하여 잔류물을 XRD 분석한 결과는 카올린 광물 및 일라이트질 광물이 확인되었다. 전자현미분석에 의하면 검은 갈색층은 주로 방해석과 Fe나 Mn 산화광물의 집합체이며 소량의 점토광물도 함께 섞여 있는 것으로 추정된다. Fe의 경우에는 주로 방해석내 Ca자리를 치환하여 존재하며 일부 산화광물로 함께 침전된 것으로 보인다. 반면에 Mn의 경우는 일부는 Fe처럼 방해석결정구조 내에서 Ca를 치환하면서 존재하기도 하지만 주로 산화물의 형태로 존재하는 것으로 보인다. 후방산란전자상(BSEI) 관찰에 의하면 Fe와 Mn 모두 매우 미세한 입자의 산화광물들로 밀집해 있는 부분이 관찰되기도 한다. 중원지역 탄산수로부터 방해석이 침전되는 과정은 CO2 가스가 방출되면서 pH가 증가하면서 방해석 및 Fe, Mn 산화물이 과포화상태가 되어 침전되는 것으로서 해석할 수 있다. 또한 지하 심부를 순환하면서 활발한 물-암석반응의 결과로 Si나 Al 및 기타 이온들의 함량이 상대적으로 높았던 탄산수가 pH가 높아지면서 카올린 광물이나 일라이트질 광물, 석영등의 규산염 광물들이 함께 침전하였을 것이다. 그러나 방해석의 침전과정이 이루어지는 과정 동안에, 온천공으로부터 채수되는 탄산수의 양이 수요에 따라 매우 불규칙해서 탄산수의 수요가 많은 경우 탄산수가 지속적으로 과잉 채수되면 주변 천층지하수가 탄산수에 혼합되어 Fe, Mn 등의 농도를 상대적으로 낮추게 되어 산화물형태로 침전되기가 어려워져서 거의 순수한 방해석만이 침전하게 된다. 결과적으로 거의 순수한 방해석 층에 검붉은 층이 불규칙하게 반복되고 있는 중원지역 탄산염침전물은 침전작용이 일어나는 대부분의 기간 동안 지속적으로 주변 전층지하수의 유입이 일어났음을 지시하고 있다. 또한 Fe, Mn 등의 함량이 높은 탄산수로부터의 침전은 매우 짧은 기간동안 단속적으로 일어났음을 지시한다.

• 보존과학연구
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• s.35
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• pp.87-98
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• 2014

Fourier transform infrared spectroscopy(FTIR-ATR) was applied to chemical analysis for conservation status of 10 human bone remains from Joseon Dynasty. The result of crystallinity index (CI) is $4.25{\pm}0.78$, carbonate to carbonate ratio (C/C) is $0.91{\pm}0.04$ and cabonate content (C/P) is $0.19{\pm}0.06$. The higher histological index (HI) confirmed CI and C/P value was increased and C/C value was reduced. While C/C or C/P values analysis is possible. While DNA analysis can be extracted from the bone, C/C values are lower or C/P values are higher was found to the analysis is possible. Chemical assessment of FTIR and histological index consequence is expected to be applicable as a basis for comprehensive understanding of the conservation status excavated bones.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.30 no.2C
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• pp.133-140
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• 2010

A series of triaxial test was performed in order to determine critical state parameters of calcareous Jeju sand, which comprises angular shape particles with many pores in the surface. It is observed that Jeju sand mainly shows the contractive behavior during triaxial shear due to high extreme void ratios and large compressibility. The peak friction angle of Jeju sand decreases slightly with increasing mean effective stress due to the particle crushing of carbonate materials. However, the peak friction angle of Jeju sand is higher than that of other silica sands because of the more angular particle shape. The critical state friction angle of Jeju sand gradually decreases when the mean effective stress at a critical state increases. Whereas, there is not a clear influence of void ratio on the critical state friction angle. Critical state parameters of Jeju sand are similar to those of calcareous sands, but significantly larger than those of common sands.

• The Journal of the Petrological Society of Korea
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• v.10 no.1
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• pp.1-12
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• 2001

A small of carbonate rocks and spatially-associated ultramafic rocks uniquely occur in the ulsan iron-serpentine mine of the sourtheastern Kyungsang basin. The study of field geology, core drilling data and stable isotope analysis suggest that the carbonate rocks are carbonatite formed from the melt reflecting intrusive natures. Based on this study, the geology of the Ulsan iron-serpentinite mining area consists of Cretaceous sedimentary, volcanic, granitic ultramafic and carbonate rocks in ascending order. The carbonate and ultramafic rocks show concentric and ellipsoidal shapes at the outcrop and a funnel shape in the cross sectional view. Carbon and oxygen stable isotope analysis show a bimodal pattern rather than a typical mantle pattern, which may indicate that the melt was a secondary melt generated within the crus not in the mantle directly. The uprising of ultramafic melts would have melted lime-contained rocks forming a secondary carbonate melt in the upper crus. Then, the intrusion of the ultramafic melts would have melted lime-contained rocks forming a secondary carbonate melt in the upper crust. Then, the intrusion of the ultramafic melt was followed by the intrusion of the carbonate melt along deep-seated fractures. Well-developed major fractures in this area, fluid inclusion characteristics of the carbonate rocks, the spatial relation between the ultramafic and carbonate rocks and stable isotope data support interpreting the Ulsan carbonate rocks as carbonatite.