• Applied Chemistry for Engineering
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• v.20 no.5
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• pp.486-492
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• 2009

Wet oxidations (WO) of quinoline in aqueous solution were carried out at $225^{\circ}C$ and $250^{\circ}C$. In the WO at $250^{\circ}C$, quinoline was degraded completely within 30 min and the reduction in total organic carbon (TOC) of 63% was achieved during 120 min. However, the rate of the reduction in TOC was only 13% within 240 min during the WO at $225^{\circ}C$. Nicotinic and acetic acid were found to be main intermediates formed during the oxidation of quinoline. With the addition of the homogeneous catalyst $CuSO_4$ or more easily oxidizable phenol, WOs of quinoline were also carried out under moderate conditions at $200^{\circ}C$. The catalytic WO with $CuSO_4$ of 0.20 g/L showed the destruction rates of quinoline and TOC comparable to those in the WO at $250^{\circ}C$. The WOs of quinoline-phenol mixture exhibited induction periods to degrade quinoline and phenol during which free radicals were produced to initiate WOs. With increasing initial concentrations of phenol at a given initial concentration of quinoline, the induction periods in the destructions of quinoline and phenol became shorter and the reduction in TOC increased from 60% to 75% during 180 min of the WOs. The reduction rate of an induction period decreased as increasing the initial concentration ratio of phenol to quinoline. On the other hand, phenol degradation in the WOs of quinoline-phenol mixtures required a longer induction period and proceeded slower compared to the case of the WO of phenol.

• Journal of the Korean Chemical Society
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• v.29 no.5
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• pp.482-489
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• 1985

The substituted quinolinium salts of pentachlorooxomolybdate (V) have been synthesized and characterized by means of the investigation of elemental analysis, infrared spectra, electron spectra, electric conductivity. The results of elemental analysis were well coincided with the theoretical value and all prepared salts were mononuclear complexes. The complexes were binary univalent electrolytes and analyzed d-d transition and charge transfer transition.

• Journal of Convergence for Information Technology
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• v.11 no.9
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• pp.109-114
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• 2021

Cr(VI)-quinoline compound[(C₉H₇NH)₂Cr₂O₇] was synthesized by the reaction between of quinoline and chromium(VI) trioxide, and structure was FT-IR, elemental analysis. The oxidation ability of benzyl alcohol greatly depends upon the dielectric constant of the used organic solvent, where carbon tetrachloride was worst and N,N'-dimethylformamide was best solvent. Noticeably, in N,N'-dimethylformamide solvent, Cr(VI)-quinoline compound oxidized substituted benzyl alcohols. The Hammett reaction constant(ρ)=-0.69(303K). As a resuit, Cr(VI)-quinoline compound was found as efficicent oxidizing agent that converted benzyl alcohol, allyl alcohol, primary alcohol and secondary alcohols to the corresponding aldehydes or ketones. Cr(VI)-quinoline compound was selective oxidizing agent of benzyl alcohol, allyl alcohol and primary alcohol in the presence of secondary alcohol ones.

• KSBB Journal
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• v.23 no.3
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• pp.245-250
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• 2008

The treatment of a model wastewater containing quinoline in an integrated wet oxidation-aerobic biological treatment was investigated. Partial wet oxidation under mild operating conditions was capable of converting the original quinoline to biodegradable organic acids such as nicotinic, formic and acetic acid, the solution of which was subjected to the subsequent aerobic biological treatment. The wet oxidation was carried out at 250$^{\circ}C$ and the initial pH of 7.0, and led to effluents of which nicotinic acid was oxidized through 6-hydroxynicotinic acid by a Bacillus species in the subsequent aerobic biological treatment. Either homogeneous catalyst of $CuSO_4$ or phenol, which is more degradable in the wet oxidation compared to quinoline, was also used for increasing the oxidation rate in the wet oxidation of quinoline at 200$^{\circ}C$. The oxidation of quinoline in the catalytic wet oxidation and the wet co-oxidation with phenol resulted in effluents of which nicotinic acid was biodegradable earlier in the aerobic biological treatment compared to those out of the non-catalytic wet oxidation at 250$^{\circ}C$. However, the lag phase in the biodegradation of nicotinic acid formed out of the wet oxidation at 250$^{\circ}C$ was considerably shortened after the adaptation of Bacillus species used in the aerobic biological treatment with the effluents of the quinoline wet oxidation.

• Journal of the Korean Chemical Society
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• v.30 no.1
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• pp.69-75
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• 1986

8-Hydroxyquinoline-resorcinol(8-HQR) and 8-hydroxyquinoline-resorcinol-salicylic acid (8-HQRS) chelate resins were prepared by the condensation reaction of 8-hydroxyquinoline, or 8-hydroxyquinoline-salicylic acid, in the presence of resorcinol with formaldehyde. The ion exchange capacities of 8-HQR and 8-HQRS resins were 4.1 meq/g and 5.4 meq/g, respectively. The adsorption and distribution coefficient of metal ions, such as Fe(III), Cu(II), Pb(II), Co(II) and Ni(II) on these resins were discussed. The adsorption of metal ions on these chelate resins showed that the maximum adsorption condition is pH 7. And the distribution coefficient of metal ions on these resins was increased with decreasing of hydrochloric acid concentration.

• Journal of the Korean Chemical Society
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• v.29 no.4
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• pp.372-381
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• 1985

Oxo molybdenum (V) complexes of substituted 8-quinolinols were synthesized and characterized by means of the investigation of elemental analysis, infrared spectra, electron spectra, electric conductivity and mass spectrometry compared with oxo molybdenum (VI) complexes. Oxo molybdenum(V) complexes were nonelectrolyte and one strong band of stretching mode of molybdenum and terminal oxygen appeared approximately $940cm^{-1}$. Oxo molybdenum(VI) complexes gave two peaks corresponding molybdenum containing ions, a molecular ion (I) of a 2 : 1 (ligand : metal) chelate and a fragment ion (II) of a 1:1 chelate due to the loss of ligand radical from ion (I). Molybdenum(V) complexes were observed the fragment ion(II) of a 1 : 1 chelate partly. The electronic spectra corresponding to d-d transition and charge transfer transition were observed and interpreted.

• Proceedings of the Korean Fiber Society Conference
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• 1992.06b
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• pp.118-119
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• 1992

• Geotechnical Engineering
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• v.13 no.2
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• pp.55-64
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• 1997

Laboratory tests were performed to desorb organic contaminants spiked onto soil particles by using surfactants. Nonionic and anionic surfactants were tested as potential desorbing solvents for extracting quinoline and 2-napthol adsorbed on soil particles. Ahionisc stirfactant remediated approximately 80% and 90% of quinoline and 2-napthol respectively and appeared to be more effective than nonionic surfactant in remediating those compounds, Comparison between simple deionized water washing of the organic contaminated soil and a given surfactant technique evaluated the improvement by the application of a Burfactant to the promotion of desorption.

• Journal of the Korean Chemical Society
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• v.46 no.5
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• pp.412-429
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• 2002

Chiral separation of gemifloxacin, an quinolone antibacterial agent, using (+)-(18-crown-6)-tetracar-boxylic acid $(18C6H_4)$ as a chiral selector was performed by capillary electrophoresis (CE). Direct analysis of quinolone antibacterial agent in body fluid is beneficial in terms of fast analysis time, multicomponent analysis. However, high con-centration of sodium ion in body fluid can prevent gemifloxacin from interacting with $18C6H_4$ since sodium ion has high affinity with $18C6H_4$ due to the strong charge interaction. Ethylenediaminetetraacetic acid (EDTA), as a chelating ligand, was added in the running buffer in order to reduce the interaction between sodium ion and the chiral selector. Increased separation efficiency and reduced migration time were observed while sodium ion exists in the sample solution at the concentration up to 150 mM.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2003.04a
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• pp.60-65
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• 2003

식물성 황색계 천연염재인 황벽, 황련 성분은 이소퀴놀린 유도체이며 베르베린을 함유하고 있는 염기성 염료에 속한다. 황련(Barberry root)은 지역에 따라 깽깽이풀, 왕련, 수련, 지련, 천련이라는 이명이 있다. 우리나라 전국의 산에 야생하고, 일본, 중국에 분포하고 있으며, 미나리아재비과(Ranunculaceae)의 여러해살이풀이다. (중략)