• Title/Summary/Keyword: 컬럼 실험

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Electrokinetic Remediation of Cobalt Contaminated Soil using Acetic Acid (초산을 이용한 동전기적 방법에 의한 코발트 오염토양 복원)

  • 김계남;김길정;손종식;배상민;오원진
    • Journal of Soil and Groundwater Environment
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    • v.6 no.1
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    • pp.13-21
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    • 2001
  • The characteristics of $Co^{2+}$ removal in the kaolinite column were analyzed by electrokinetic remediation. Ethanoic buffer was injected in the kaolinite column and $CH_3$COOH was continuously added to the cathode reservoir to restrain the pH increase. The pH of the cathode of the kaolinite column was 4.0 at first. Since it was controlled to be under 6.5 after 43.6 hours due to ethanoic buffer, precipitation of ${Co(OH)}_2$ was not formed in the column. Effluent rate increased with time and $Co^{2+}$ removal in the column at initial time was mainly controlled by ion migration. 13.1% of total $Co^{2+}$ in the column was removed after 10 hours, the 46.8% of total $Co^{2+}$ after 20.8 hours, and the 71.7% of total $Co^{2+}$ after 30.1 hours, the 94.6% of total $Co^{2+}$ after 43.6 hours, Meanwhile, the residual concentrations in the column calculated by the developed model were similar to experiment results.

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Increase of Electrokinetic Soil Remediation Efficiency using Ethanoic Buffer (초산완충액에 의한 동전기적 토양복원 효과 증진 연구)

  • Kim, Gye-Nam;Oh, Won-Zin
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.11
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    • pp.2007-2016
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    • 2000
  • After kaolin clay was compulsorily contaminated with $Sr^{2+}$ ion. the remediation characteristics by electrokinetic method were analyzed. In the first experiment. NaCl solution was used as an electrolyte to raise the electric field strength. After remediation for 0.8 days. the pH of the cathode side of the soil column was elevated from 4.0 to 11.7. and thereby precipitation $Sr(OH)_2$, started to be formed in the side. Therefore. efficiency of soil remediation was reduced significantly and the 32% of total $Sr^{2+}$ ion in the column was decontaminated in 6.7 days. In the second experiment. ethanoic buffer was injected in the soil column and $CH_3COOH$ was continuously inputted in cathode reservoir to restrain the pH elevation. The pH of the cathode side of the soil column was only ascended from 4.0 to 6.0 in 3.8 days and $Sr(OH)_2$ was not formed. The 21% of total $Sr^{2+}$ in the soil column was decontaminated in 0.6 days. and the 33% of total $Sr^{2+}$ in 0.9 days. and the 84% of total $Sr^{2+}$ in 1.6 days. and the 92% of total $Sr^{2+}$ in 2.5 days. and the 97% of total $Sr^{2+}$ in 3.8 days. Meanwhile. the residual concentrations in the column calculated by the developed model were similar to those by experiment.

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토양컬럼을 이용한 합성폐수증 $NH^{4+}$의 질산화

  • 정경훈;정오진;최형일;박상일;김해연
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2004.05a
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    • pp.329-331
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    • 2004
  • 본 연구에서는 토양을 충진한 컬럼을 사용하여 질산화 반응을 촉진시키기 위한 첨가제에 따른 효과를 검토하였다. 토양만을 충진한 컬럼에서는 $NH_{4-}$/N의 약 26%가 질산화 되었으며 제올라이트를 첨가 하였을 때 실험초기에는 $NH_{4-}$/N가 유출되지 않다가 20일 이후부터 $NH_{4-}$/N의 농도가 증가 하기 시작하였으며 이는 제올라이트에 의한 흡착능력의 저하로 사료된다. 폐굴껍질 20% 충진한 토양컬럼에서는 실험 95일까지 99.7%의 질산화율을 보았다. 위의 결과로부터 알 수 있듯이 토양컬럼에 폐굴껍질과 제올라이트를 첨가제로 충진하였을 경우 질산화 반응을 촉진시켜서 질산화율을 높일 수 있음을 확인 할 수 있었다.

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Column-aware Polarization Scheme for High-Speed Database Systems (고속 데이터베이스 시스템을 위한 컬럼-인지 양분화 기법)

  • Byun, Si-Woo
    • Journal of Internet Computing and Services
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    • v.13 no.3
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    • pp.83-91
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    • 2012
  • Recently, column-oriented storage has become a progressive model for high-speed database systems because of its superior I/O performance. In this paper, we analysis traditional raw-oriented storage model and then propose a new column-aware storage management model using flash memory drive and assist drive to improve the effective performance of the high-speed column-oriented database system. Our storage management scheme called column-aware polarization improves the performance of update operation by dividing and compressing table columns into active-columns or inactive-columns, and balancing congested update operations using a assist drive in high workload periods. The results obtained from experimental tests show that our scheme improves the update throughput of column-oriented storage by 19 percent, and the response time by up to 49 percent.

Evaluation of Soil Flushing Column Test for Oil-contaminated Soil Treatment (유류오염토양 처리를 위한 컬럼식 토양세정기술 평가)

  • Kang, Hui-Cheon;Han, Byeong-Gi;Kim, Joung-Dae;Seo, Seung-Won;Shin, Chul-Ho;Park, Joon-Seok
    • Clean Technology
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    • v.23 no.3
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    • pp.302-307
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    • 2017
  • This study was conducted to evaluate the feasibility of in situ soil flushing for TPH-contaminated soil remediation with column test. The soil texture of the soil was sand and the initial TPH concentration was $9,369mg\; kg^{-1}$. 0.1% Tween-80 was selected as surfactant solution. And the acrylic and the glass syringe columns were used as reactors. In the acrylic column test, 35% of the initial TPH was removed in 1 PV of flushing and approximately 40% in 5 PV and finally 7 PV showed about 60%. The glass column test showed 3 ~ 12% higher removal efficiency than that of acrylic test until 5 PV of flushing. However, there was no difference in TPH removal efficiency when 7 PV of surfactant was finally flushed. Both of alum only and alum+polymer mixed surfactants showed also the best coagulation efficiency in $150mg\;L^{-1}$ of concentraion. When Tween 80 was newly dissolved in 0.1% to the recovered solution after the coagulation treatment, the removal efficiency was increased from 32.0% to 41.0% in comparison to the new 0.1% Tween 80 solution without reuse by coagulation treatment.

토양컬럼을 이용한 도금공장 유출수의 고도처리

  • Jeong, Gyeong-Hun;Kim, Se-Yeong;Im, Byeong-Gap;Choe, Hyeong-Il;Park, Sang-Il;Kim, Yeong-Ju
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2006.11a
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    • pp.377-381
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    • 2006
  • 실험실 규모의 토양컬럼을 사용하여 도금폐수처리장의 유출수를 대상으로 처리한 결과 다음과 같은 결론을 얻었다. 1) 유입수 $NH_4-N$의 대부분은 질산화 토양컬럼에서 질산화 되었으며 HRT가 단축되면 제거율이 낮아졌다. 2) 질산화 토양컬럼에서 생성된 $NO_3-N$은 탈질 토양컬럼에서 탄소원이 없으면 탈질이 이루어지지 않지만 탄소원으로 메탄올을 주입하면 대부분의 $NO_3-N$는 탈질되었다. 3) 탈질 토양컬럼에서 HRT 72시간일때 T-N 제거율은 81.5%이었고 HRT 48시간일 때는 77.8%이었다. 4) 유입수 평균 T-P농도는 13.06 mg/L이고 탈질 토양컬럼에서의 유출수 평균 T-P는 0.83 mg/L로 제거율은 96.83% 이었다. 5) 실험기간 동안의 COD변화는 탄소원으로 메탄올 주입했 때와 HRT 변화시를 제외하고는 25 mg/L이하로 처리되었으며, 질산화 토양컬럼에는 폐굴껍질을 충진한 결과 $NO_3-N$의 생성에도 불구하고 pH 8.5정도를 유지할 수 있었다.

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HPLC Study for Egg White Analysis (달걀 단백질 분석을 위한 HPLC 연구)

  • Jeon, Young-Ju;Lee, Eun;Kim, In-Ho
    • KSBB Journal
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    • v.22 no.2
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    • pp.119-122
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    • 2007
  • Since egg white contains various protein, it is important to research the protein distribution of egg white. Specially, lysozyme and ovalbumin important proteins, are used in medicine and food industry. Reversed phase high performance liquid chromatography has been used for separation of egg white, and column of RP-HPLC is available in variety. We have used C4, C8 and C18 columns to obtain chromatograms by varying carbon chain length of stationary phase. Long carbon chain length of stationary phase has good separation of egg white. Also, we have changed the composition of mobile phase (acetonitrile, water, and trifluoroacetic acid) to find optimum chromatograms. Acetonitrile and water composition of 50 : 50 show many peaks from egg white. Isocartic and gradient elution in RP-HPLC were used to compare the chromatography of egg white.

Development of Schiff Base Column and Glow Discharge Detector for HPLC : Preliminary Study I (HPLC용 Schiff Base 컬럼과 Glow Discharge 검출기의 개발에 관한 기초연구 I)

  • Kang, Mi-Ra;Kim, Eun-Soo;Shin, Jung-Sook;Park, Hyun-Kook;Yang, Jung-Sung;Lee, Sang C.
    • Analytical Science and Technology
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    • v.8 no.3
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    • pp.265-272
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    • 1995
  • Schiff base ligand columns and glow discharge detector have been developed for the trace analysis of metal ions desolved in water. Various types of hydrazide Schiff base ligands have been used and, additionally, they were examined as a filling material of a HPLC column. The hydrazide Schiff base ligands used were N, N'-oxalybis(salicylaldehydrazone) (OBSH), N, N'-malonylbis(salicylaldehydrazone) (MBSH), and N, N'-succinylbis(salicylaldehydrazone) (SBSH). A mixture of Schiff base ligand and poly(styrene divinylbenzene) was examined and it showed a smooth flow of solution. The OBSH-polymer column demonstrated different effluent factors for different metal ions. Metal ions in eluates were detected by Hollow Cathode Glow Discharge-Atomic Emission Spectrometry(HCGD-AES). HCGD-AES showed good sensitivity and selectivity. This is only the preliminary results of new OBSH-polymer column and glow discharge detector.

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The Development of Analysis System for Genes Related Disease Using Chemical Properties of DHPLC (DHPLC의 화학적 특성을 이용한 질병 유전자의 분석 시스템 개발)

  • Kim, Jong-Gyu;Nam, Yun-Hyeong;Park, Sang-Beom;Lee, Jae-Sik;Gang, Won
    • Journal of the Korean Chemical Society
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    • v.50 no.2
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    • pp.116-122
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    • 2006
  • In this study we extracted DNA from 100 tissues of breast cancer patients and 103 normals. Then we confirmed single-nucleotide polymorphism(SNP) using PCR-DHPLC(polymerase chain reaction-denaturing high performance liquid chromatogrphy).Also, we studied SNP of samples using several columns to identify relation between packing materials of column and resolution.As a result, we identified 4 C/A, C/G genotypes(4%) in exon 5 and 37 T del genotypes(37%) in exon 8 among 100 breast cancer tissues and 2 in exon 5, 9 in exon 8 among 103 normal samples.In resolution test, we confirmed that PS-DVB(poly styrene-divinylbenzen) column is more efficient than C18 column.

고분자 촉매를 이용한 용존산소 제거

  • 이한수;강희석;정홍석;안도희;백승우
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05a
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    • pp.577-581
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    • 1996
  • 고분자 촉매를 이용하여 용존산소를 제거하는 실험을 수행하였다. 고분자 촉매는 높은 비표면적과 좋은 금속의 분산도를 갖도록 제조하였다. 컬럼에서 제조된 촉매를 사용하여 용존산소-수소의 반응을 수행한 결과 용존산소를 35 ppb까지 감소시킴으로서 제조된 촉매의 용존산소제거에의 적합성을 확인하였다. 컬럼에서의 촉매의 거동을 적절한 모델을 통하여 해석하였으며 또한 활성탄에 담지된 금속 촉매 및 현재 상용화되고 있는 Lewatit촉매를 이용하여 실험을 수행함으로서 촉매성능을 비교하였다. 활성탄의 경우 초기에 활성탄의 표면에 산소가 많이 흡착되어 있기때문에 이를 제거하기 위하여 전처리가 필요한 것으로 나타났으며 Lewatit촉매의 경우 가장 우수한 성능을 보였다.

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