• Korean Journal of Materials Research
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• v.11 no.5
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• pp.339-344
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• 2001

An all solid-state thin film supercapacitor (TFSC) with Co$_3$O$_4$/LiPON/Co$_3$O$_4$ structure was fabricated on Pt/Ti/Si substrate using Co$_3$O$_4$ thin film electrode. Each Co$_3$O$_4$ film was grown by reactive dc reactive magnetron sputtering with increasing $O_2$/[Ar+O$_2$] ratio. Amorphous LiPON electrolyte film was deposited on Co$_3$O$_4$/Pt/Ti/Si in pure nitrogen ambient by using reactive rf magnetron sputtering. The electrochemical behavior of the Co$_3$O$_4$/LiPON/Co$_3$O$_4$ multi-layer structures exhibits a behavior of a bulk-type supercapacitor, even though much lower capacity (from 5 to 25 mF/$\textrm{cm}^2$-$\mu\textrm{m}$) than that of the bulk one. It was found that the TFSC showed a fairly constant discharge capacity with a constant current of 50 $\mu\textrm{A}/\textrm{cm}^2$ at the cut-off voltage 0-2V during 400 cycles. It is shown that the electrochemical behavior of the Co$_3$O$_4$/LiPON/Co$_3$O$_4$ TFSC is dependent upon the sputtering gas ratio. The capacity dependency of electrode films on different gas ratios was explained by different structural, electrical, and surfacical properties.

• Journal of the Korean Electrochemical Society
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• v.6 no.3
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• pp.169-173
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• 2003

Electrochemical capacitor made with metal oxide electrode uses rapid and reversible protonation/deprotonation of metal oxide material under the aqueous acidic solution, generally. Electrochemical stability window of aqueous electrolyte-type capacitor is narrow compared to that of organic electrolyte-type capacitor. Electrochemical characteristics of electrochemical capacitor made with metal oxide electrode and lithium or ammonium cation based organic electrolyte were evaluated. Electrochemical capacitor based on $RuO_2$ electrode material and 1M $LiPF_6$ in mixed solvents of EC, DEC, and EMC has anodic and cathodic specific capacitance of 145 and $142F/g-RuO_2{\cdot}nH_2O$, respectively, by using cyclic voltammetry with scan rate of 2mV/sec $g-RuO_2$ in potential range of $2.0\~4.2V(Li|Li^+))$.

• Journal of the Korean Ceramic Society
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• v.39 no.9
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• pp.822-828
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• 2002

Fabrication and electrical characterization of R. F. High-power unit capacitors were investigated to study on condition of fabrication processing for R. F. High-power unit capacitor and electrical characteristics according to addition of $ZrO_2$. The unit capacitors were fabricated using tape casting. The optimum mixture ratio of dielectrics and mixing binder for the slurry fabrication was 57.5∼60.0: 42.5∼40.0 wt%. The slurry viscosity was 4000∼5000 cps and casting state of green tape fabricated using these slurry was excellent. Optimum stacking was made by 200 kg/$cm^2$ pressure with 80$^{\circ}C$ heating. $ZrO_2$ was added to improve the electrical characteristics of unit capacitor, especially breakdown characteristics. The dielectric constant and loss factor of the unit condenser having different $ZrO_2$ amounts was not changed in the addition range of 1 to 5 wt%. Also, dielectric constant was not changed in the frequency range of 10 to 500 kHz. It was found that characteristics of resistance voltage was improved through the formation of $CaZrO_3$ and the reduction of particle size as about 3wt% $ZrO_2$ was added.

• The Transactions of the Korean Institute of Power Electronics
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• v.15 no.2
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• pp.150-158
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• 2010

The operational characteristics of a resonant DC/DC converter, which can harvest thermoelectric energy, is analyzed, depending on the relative magnitudes of the input voltage and the load voltage. The resonant converter consists of LC resonant circuit connected to DC input source and a resonant pulse converter in which the input energy is transferred to the load as the resonant capacitor voltage is peak. The resonant capacitor doubles the input voltage by the resonance phenomenon. By the relative magnitude between the input voltage and the output voltage, the resonant DC/DC converter operates in three different modes. For boost mode, the peak voltage of the resonant capacitor is smaller than the load voltage. For hybrid mode, the peak voltage of the resonant capacitor is bigger than the load voltage and every switching period has both the boost mode and the direct mode. For the direct mode, the input voltage is bigger than the load voltage and the converter transfers directly the input energy to the load without the switching operation. Operation principles and the feasibility of the converter for the thermoelectric energy harvesting are verified with PSPICE simulation and experiment.

• Proceedings of the Korean Fiber Society Conference
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• 1999.10a
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• pp.331-334
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• 1999

• Electrical & Electronic Materials
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• v.30 no.7
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• pp.10-19
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• 2017

• Proceedings of the Korean Institute of Communication Sciences Conference
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• 1987.04a
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• pp.136-139
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• 1987

• Proceedings of the Korean Vacuum Society Conference
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• 2001.02a
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• pp.100-100
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• 2001

• Proceedings of the Korean Institute of Communication Sciences Conference
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• 1992.06a
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• pp.549-554
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• 1992

• Proceedings of the Korean Vacuum Society Conference
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• 1995.02a
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• pp.047-48
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• 1995