• Journal of Energy Engineering
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• v.25 no.2
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• pp.65-78
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• 2016

Initial studies of the photocatalyst has been developed from the field relating to the conversion and storage of solar energy. Recently, the study of the various organic decomposition compound and the water purification and waste water treatment by ultraviolet irradiation in the presence of light or a photocatalyst are being actively investigated. In addition, the oxidized material-carbon nanotubes, graphene-nanocomposites have been studied. Such a complex is suitable as a material constituting the solar cells and photolysis nanoelectronics, including the flexible element due to thermal and chemical stability.

• Transactions of the Korean Society of Automotive Engineers
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• v.23 no.6
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• pp.656-662
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• 2015

In the present study, multi-layered Si DLC (Silicon Diamond-Like Carbon) coatings with HMDSO (Hexamethyldisiloxane) buffer layers are applied on SKD 11 substrates by PECVD (Plasma Enhanced Chemical Vapor Deposition) with different HMDSO gas flow rates, while the gas flow rate of $C_2H_2$ is fixed to enhance the electric resistivity of forming dies for electrically assisted forming. The HMDSO buffer layer is introduced to increase adhesion between the base metal and Si-DLC layers. The result of evaluation of electric resistivity and adhesion strength shows that the properties are affected by the flow rate of HMDSO, while the flow rate of 80 sccm results in the coating with the highest electric resistivity and adhesion strength among the selected flow rates.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 2006.05a
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• pp.31-34
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• 2006

The characteristic of carbon nano fiber (CNF) as electron emitters was described. Carbon nano fiber (CNF) of herringbone was prepared by thermal chemical vapor deposition(CVD), mixed with binders and conductive materials, and then were formed by screen-printing process. In order to increase effectively field emissions, the surface treatment of rubbing & peel-off was applied to the printed CNF emitters on cathode electrode. The measurements of field emission properties were carried out by using a diode structure inline vacuum chamber. CNF of herringbone type showed good emission properties that a turn on field was as low as $2.5V/{\mu}m$ and current density was as large as $0.15mA/cm^2$ of $4.5V/{\mu}m$ with electric field. After the vacuum packaged panel of 5-inch in diagonal, the measured white brightness was as high as $7000cd/m^2$ at 1900V of anode and 700V of gate voltage.

• Journal of the Korean institute of surface engineering
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• v.41 no.3
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• pp.114-120
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• 2008

The pyrolysized carbon xerogel and aerogels were prepared from the sol-gel polymerization of resorcinol-formaldehyde(RF) followed by the dry process under ambient pressure and supercritical carbon dioxide condition respectively. The thermal behaviour of RF polymer xerogel was investigated with TGA analyzer to correspond with the pyrolysis process. The surface properties such as particle size, morphology and the point of zero charge of the pyrolysized porous carbon aerogels were studied for the precious metal catalyst supported media. It was found that the volume of the polymer aerogel decreased because of the significant linear shrinkage and weight loss of polymer gel during the carbonization. The point of zero charge of the carbon aerogel pyrolysized at $1050^{\circ}C$ under inert gas flow was about 10.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2006.04a
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• pp.41-42
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• 2006

Carbon nanotubes (CNTs) effects on physical properties of the liquid crystal and twisted nematic (TN) liquid crystal (LC) cells have been investigated. The minute doping of CNTs reduces rotational viscosity of the LC, and thus switching time of the TN cells is improved, especially in grey scale response time. In addition, the dielectric anisotropy and birefringence are not affected by such a small amount of CNT-doping and thus voltage-dependent transmittance remains the same.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.07a
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• pp.166-167
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• 2005

본 연구에서는 RF 플라즈마 화학기상증착 장비를 사용하여 동일조건에서 합성된 100 nm 두께의 DLC박막을 RTA 장비를 사용하여 $N_2$ 분위기로 여러 가지 온도에서 ($300\sim900^{\circ}C$) 후열처리된 DLC 박막들의 마찰특성 변화를 AFM (Atomic Force Microscopy)의 FFM (Friction Force Microscopy) 모드를 사용하여 관찰하였다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.07a
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• pp.236-237
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• 2005

To measure surface roughness and smoothness of semiconducting materials in power cable, we have investigated the formation and growth process of carbon black showed by changing the content of carbon black. The specimens were primarily kneaded in material samples of pellet form for 5 minutes on rollers ranging between 70[$^{\circ}C$] and 100[$^{\circ}C$]. Then they were produced as sheets after pressing for 20 minutes at 180[$^{\circ}C$] with a pressure of 200[kg/cm]. The contents of conductive carbon black were the variable, and their contents were 20, 30 and 40[wt%], respectively. The surface roughness and smoothness of specimens were measured by SEM and AFM. From SEM experimental result, carbon black in specimens formed matrix as a particles. Also we showed growth process of carbon black according to an increment of the content of carbon black. From AFM experimental result, surface roughness of specimens decreased according to an increment of the content of carbon black.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2006.06a
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• pp.236-237
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• 2006

We have investigated volume resistivity showed by changing the content of Carbon nanotube and carbon black which is the component parts of semiconducting shield in underground power transmission cable. Specimens were made of sheet form with the six of specimens for measurement. Volume resistivity of specimens was measured by volume resistivity meter after 10 minutes in the preheated oven of both $23{\pm}1[^{\circ}C]$ and $90{\pm}1[^{\circ}C]$. The volume resistivity decreased by adding Carbon nanotube and carbon black. Also the volume resistivity had different properties because of PTC/NTC tendencies at between $23[^{\circ}C]$ and $90[^{\circ}C]$. We experimented with electric properties of semiconducting components with fewer Carbon nanotube than carbon black.

• Proceedings of the Korean Vacuum Society Conference
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• 2000.02a
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• pp.127-127
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• 2000

다이아몬드상 카본(Diamond-like Carbon, DLC) 필름은 비정질 재료로서 다이아몬드와 유사한 높은 경도, 내마모성, 화학적 안정성, 그리고 광학적 특성을 가지고 있으며, 낮은 마찰계수와 높은 탄성률 등으로 인해 많은 분야에서 응용이 연구되고 있는 재료이다. 그러나 DLC 필름이 이러한 우수한 특성이 가지고 있음에도 불구하고 수 GPa에 이르는 높은 압축 잔류 응력으로 인해 응용에 제약을 받고 있다. 이러한 압축 잔류 응력이 상당한 값에 이르게 되면 기판의 구속에서 벗어나게 되어, 기판으로부터 떨어지게 되고 굽힘을 받게 되는 delamination buckling 현상이 일어나기도 한다. 본 연구에서는 높은 잔류 응력으로 인해 자연적으로 발생하는 buckling 현상과 식각 과정을 통해 인위적으로 기판의 제한으로부터 필름을 완화시키는 freehang 방법을 이용하여 필름이 기판에 접착되는데 필요한 에너지를 평가하려고 한다. 본 실험에서는 rf-PACVD 장비를 이용하여 필름을 증착하였다. 이때 전극과 플라즈마 사이의 바이어스 음전압은 -100~700 Vb로 변화를 주었으며, 합성압력은 9mTorr로 고정하였다. 사용한 반응 가스는 메탄(CH4)이고, 아르곤(Ar)을 이용하여 모든 실험에서 동일하게 기판을 전처리 하였다. buckling 현상을 관찰하기 위해 사용된 기판은 slide glass이고, freehang을 제작하기 위해 사용된 기판은 (100) p-type Si wafer 이다. freehang 제작시 사용한 식각 용액은 KOH(5.6mol)이며 외부 요인을 제거하기 위해 7$0^{\circ}C$ 항온조를 사용하였다. Buckling 된 필름과 freehang은 광학 현미경과 전자 주사 현미경에 의해 관찰되었으며, 사인 함수 형태의 곡면을 가지고 있었다. 또한 freehang 제작시 각각의 주기와 진폭을 통해, 필름과 기판사이의 계면에너지와 buckling 되면서 새로 생성된 두 표면에너지 차이를 구할 수 있게 되고, 이를 통해 접착에너지를 평가할 수 있었다.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.18 no.8
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• pp.1-7
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• 2019

Materials that can be used for 3D printing have been developed in terms of phase and functionality. Materials should also be easily printed with high accuracy. In recent years, the concept of 4D printing has been extended to materials whose physical properties such as shape or volume can change depending on the environment. Typically, such high-performance 3D printing materials include bio-inks and inks for sensors. This study deals with the optimization of the manufacturing method to improve the functional properties of the pressure sensitive material, which can be used as a sensor based on change of the resistance according to the pressure. Specifically, the number of milling for dispersion, the ratio of hardener for controlling elasticity, and the content of MWCNTs were optimized. As a result, a method of manufacturing a highly sensitive pressure-sensitive ink capable of use in 3D printing was introduced.