• Journal of the Korean Crystal Growth and Crystal Technology
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• v.24 no.5
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• pp.207-212
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• 2014

An ultrathin sheet-like carbon nanostructure provides an important model of a two-dimensional graphite structure with strong anisotropy in physical properties. As an easy and cheap route for mass production, RF thermal plasma synthesis of freestanding carbon nanosheet from $CH_4$ (Methane) and $C_3H_8$ (Propane) is presented. Using vapor synthesis process with RF inductively thermal plasma, carbon nanosheets were obtained without catalysts and substrates. The synthesized carbon nanosheets were characterized using transmission electron microscopy (TEM), Raman spectroscopy, X-ray diffraction (XRD) and Brunauer-Emmett-Teller (BET) analysis. The carbon nanosheets synthesized using methane and propane generally showed 5~6 and 15~16 layers with a wrinkled morphology and size of approximately 100 nm.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2018.06a
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• pp.114-114
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• 2018

탄소 재료는 뛰어난 물성에서 다양한 재료로의 응용이 기대되고 있다. 특히, 이종 원소 함유 카본 재료는 전기적 특성과 촉매성의 발현 등 새로운 기능을 카본 재료에 부여할 수 있어서 연료 전지, 에너지 저장, 태양 전지 등에의 응용이 기대되고 있다. 최근, 용액 중의 저온 플라즈마인 솔루션 플라즈마(solution plasma process)를 이용하여 벤젠 용액 등에서 탄소 재료 합성에 성공하였다. 그러나 기존의 연구에서는 솔루션 플라즈마 프로세스를 이용하여 합성한 이종원소 카본은 전도성이 낮아 이종원소의 함유량을 낮추는 고온의 열처리가 필요했다. 따라서 본 연구에서는 우수한 물리적 전기적 특성을 갖는 그래핀(graphene)과 같은 이종 원소 카본 나노시트(heteroatom carbon nanosheets)의 합성 및 메커니즘(mechanism)에 대해 검토하였다. 다양한 이종원소를 포함한 유기용매 안에 바이폴라 펄스 전원에 의한 전압을 두 텅스텐 전극 간에 인가하고, 솔루션 플라즈마를 생성하여 이종원소 카본 재료를 합성했다. 플라즈마 생성은 텅스텐 봉을 전극으로 사용하고 전압을 2.0 kV, 펄스 주파수를 200 kHz, 펄스 폭을 $1.0{\mu}s$, 전극 간 거리를 1.5 mm에서 일정하게 유지하며 200 mL 유기용매 중에서 방전시키는 것으로 재료를 합성했다. 플라즈마 방전 후, 필터을 이용하여 흡인 여과한 뒤 $200^{\circ}C$에서 1 시간 동안 건조 시켰다. 건조 후의 이종원소 카본의 물리적 특성을 원소 분석, X선 회절 법(XRD), 저항률 측정, 투과형 전자 현미경(TEM) 및 라만 분광법, 전자 현미경(SEM), X-선광전자분광기(XPS)등을 이용하여 카본의 형상 및 특성을 분석하였다. 그 결과 다양한 이종원소를 포함한 유기용매 중 2-pyrrolidone을 사용했을 때, 이종 원소 카본 나노시트를 합성하는데 성공하였다. 또한, 이 연구방법을 통해서 솔루션 플라즈마 프로세스를 통한 카본 나노시트 합성의 메커니즘을 규명하였다.

• Journal of the Korea institute for structural maintenance and inspection
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• v.10 no.3
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• pp.152-159
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• 2006

An experimental research has been performed to investigate capacity of CFCST(Concrete Filled Carbon Sheet Tube) columns because column member is one of the most important structural members. Generally, two shapes of column sections, rectangular and circular shapes, are designed but the circular shape which has constant curvature was chosen for this study. Total 17 column specimens confined by carbon sheet tube were tested using 10,000kN universal test machine(UTM).

• Journal of the Korea institute for structural maintenance and inspection
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• v.20 no.6
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• pp.106-112
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• 2016

In this study, circular concrete column specimens confined by carbon sheet tube with different winding angles and different number of carbon sheet plies(3T, 5T and 7T) were tested to propose design equations and a strength reduction factor. Specimens were designed by 300 mm diameter and 600 mm height with $90^{\circ}{\pm}0^{\circ}$, $90^{\circ}{\pm}30^{\circ}$, $90^{\circ}{\pm}45^{\circ}$, $90^{\circ}{\pm}60^{\circ}$, $90^{\circ}{\pm}75^{\circ}$ and $90^{\circ}{\pm}90^{\circ}$ carbon fiber angles. A 10,000 kN UTM was used for compressive strength test of specimens by displacement control method with 0.01 mm/sec velocity. Estimation equations of compressive strength and ultimate strain of circular concrete column specimens confined by carbon sheet tube using a regression analysis and a strength reduction factor to apply ultimate strength design method of concrete were proposed. The strength reduction factor(${\phi}$) of circular concrete columns confined by carbon sheet tube was estimated as 0.64 by the Monte Carlo Analysis Method. Manufacture and construction process have to be perfectly managed by construction managers because the structural capacities of carbon tubes were depends on construction abilities of manufacturing operators.

• Journal of the Korea institute for structural maintenance and inspection
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• v.11 no.3
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• pp.143-150
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• 2007

Six full scale column specimens have been tested under the constant axial and cyclic lateral load. An equivalent stress block parameter was used to estimate flexural capacity of columns confined by carbon sheet tube. Through the non-linear regression analysis, behaviors of CFCST(Concrete Filled Carbon Sheet Tube) columns under the cyclic lateral load were estimated and compared with test results.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2010.06a
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• pp.107-107
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• 2010

IT 산업의 발달과 더불어 카메라, 휴대폰, 노트북, 캠코더 등 전기전자 응용분야에 복합기능성 실리콘 고무 시트가 사용되고 있다. 본 연구에서는 실리콘 고무의 사용시 발생하는 정전기를 방지하기 위해 습도와 온도 변화에 따른 정전기 대전전압을 측정하였다. 카본양의 증가에 따라서 대전전압이 감소하였으며 습도가 증가됨에 따라 정전기 대전량은 감소하였다. 12Phr카본 첨가시 대전과 동시에 완화가 일어남을 확인했다.

• Composites Research
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• v.33 no.6
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• pp.395-400
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• 2020

In this paper, we manufactured silsesquiaznae (SSQZ)-coated carbon nanotube (CNT) surface heating elements, which allowed stable heating at high temperatures. The prepared composite sheet was confirmed by FE-SEM that the SSQZ fully coated the surface of CNT sheet. Furthermore, it was also confirmed that the silicon carbonitride (SiCN) ceramic formed by heat treatment of 800℃ have no defects found and maintain intact structure. The CNT/SiCN composite sheet was able to achieve higher thermal stability than raw CNT sheets in both nitrogen and air atmosphere. Finally, the CNT/SiCN composite sheet was possible to heat up at a temperature of over 700℃ in the atmosphere, and the re-heating was successfully operated after cooling.

• Applied Chemistry for Engineering
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• v.20 no.6
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• pp.622-627
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• 2009

Using an alkali-solution developable photosensitive resin and a carbon black as a conductive filler, photo-patternable pastes for polymer thick film resistor were fabricated and evaluated. A photo solder resist (PSR), which is usually used as protecting layer of printed circuit board (PCB), was used as a photosensitive resin so that ultraviolet exposure and alkali-aqueous solution development of paste were possible. After fabricating the photosensitive polymer resistor paste, the electrical properties of thick film resistors were measured using PCB test boards. Sheet resistance was decreased with increasing amount of carbon black, but the developability was limited in excess loading of carbon black. The sheet resistance was also reduced by re-curing and the change rate was smaller in higher carbon black loading. Moreover, finely patterned meander-type thick film resistors were fabricated using photo-process and large resistance up to several tens of sheet resistance could be obtained in small area by this technique.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2006.06a
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• pp.228-229
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• 2006

본 연구에서는 PCB에 적용하기 위한 폴리머 타입 후막저항의 하나로서, 포토공정으로 저항 패턴의 형성이 가능한 페이스트를 제조하였다. 기존의 폴리머 후막저항은 스크린 인쇄를 패터닝의 주요 방법으로 하고 있어 패턴의 정밀성이 떨어지는 단점이 있었다. 이를 개선하여 고정밀 저항 패턴의 형성이 가능하도록 Photoimageable Resin을 저항 페이스트의 개발에 도입하였다. Acrylated oligomer 및 monomer, 그리고 Novolac Epoxy를 주 기지상 재료로서 사용하였으며, acrylate와 epoxy의 함량비에 따른 저항 페이스트의 현상성 및 시트저항을 평가하였다. 전도성 Filler 재료로 카본블랙을 이용하였는데, 그 물리적 특성차와 함량이 저항 페이스트의 현상성과 저항값에 미치는 영향을 평가하였다. 실험결과 Acrylate와 epoxy의 비가 2.5:1일 때 현상성이 가장 양호하였으며, 이 조성에 XC72R 카본블랙을 2g 첨가하였을 때 시트저항의 평균값은 약 $6\;k{\Omega}\{\square}$였다.

• KIEAE Journal
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• v.7 no.6
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• pp.119-126
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• 2007

In the field of composite structures, the use of carbon tube for the confinement of concrete has been arisen since 1990's. However, experimental and analytical studies were limited to those of reinforced concrete and concrete filled steel tube. The carbon tube provides excellent confinement capabilities for concrete cores, enhancing compressive strength and ductility of concrete significantly. The carbon tube has high tensile strength, light weight, corrosion immunity and high fatigue strength properties. Since carbon fiber is an anisotropic material, carbon tube could be optimized by adjusting the fiber orientation, thickness and the number of different layers. In this study, both experimental and analytical studies of axial and lateral behavior of full-scale CFCT (Concrete Filled Carbon Tube) columns subjected to monotonic axial load were carried out using Drucker-Prager theory. And, based on comparison results between experiment results and analytical results, k factor estimation was proposed for effective analysis.