• Journal of the Korea Organic Resources Recycling Association
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• v.10 no.1
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• pp.68-74
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• 2002

This study was performed to examine the availability of electrolysis for removal of remaining biologically refractoty humus and residual color of leachate which is biologically pretreated in domestic waste matter sanitary landfill by recycling to landfill. The obtained results were as follows; 1) The electrolysis of leachate through covered bed represented that the removal efficiency of CODcr and color range from 70~80%, in color removal the only electrolysis for a treatment of leachate meet the critia of effluent. 2) The highest removal efficiency was represented in pH 7~8. 3) At anode used Al, Fe, Stainless the removal efficiency of CODcr and color was high in order of Fe, Al, stainless, in considering the settled ability of reaction product in economic or after electro coagulation the removal efficiency was highest when anode was the Fe electrode. 4) In this study conditions for removed both CODcr and Color ar the same time represented thar anode was used Fe, electrode-distance was 2cm and reaction time was 40min in 8volts.

• Journal of Korea Soil Environment Society
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• v.2 no.3
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• pp.39-47
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• 1997

Geochemical study was carried out to find out the distribution of metals and cyanide in soil in the vicinity of the abandoned Daduck mine and the reason for acid mine drainage occurrence in the tailings impoundment. Chemical analysis showed that content of As in soil around tailings exceeded 15mg/kg, Korean standard of soil contamination in the farm land. That means the contamination of soil by As is due to input of tailings. According to total decomposition of tailings, As, Cd, Cu, Pb, Zn and S were highly concentrated in tailings. However the water in tailings impoundment was changed to acidic and contaminated by metals and sulfate because the tailings in the top of the tailings impoundment had been oxidized. Acid mine drainage contaminated the water course in the vicinity of the paddy soils. The proper measures are required to prevent contamination of the soil and water in the vicinity of the Daduck mine.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.7 no.4
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• pp.41-50
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• 1987

The present study was conducted to measure and predict the leachate generation and to establish the methods of leachate control and handling by both field and lab-lysimeter studies. The change of biodegradable matter, field capacity, dry density, quantity and quality of leachate as a function of time of landilling were measured. The model based on the theory of unsaturated flow and contaminant transport in porous media was developed and simulation model was used for the prediction of movement of landfill moisture and for the strength in leachate in terms of organic and inorganic contaminant. The model constructed from the present study in terms of unsaturated decomposition and transport combined with the evapotranspiration and surface runoff showed good agreement with the results obtained by lysimeter studies.

• Journal of the Korean GEO-environmental Society
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• v.6 no.1
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• pp.5-13
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• 2005

The conventional settlement prediction method is not appropriate to model landfill settlement because it is very complex phenomenon. Biodegradation needs to be considered for long-term settlement since landfills are comprised of various organic materials and soils. As organic materials are decomposed, they directly influences on settlement producing LFG(Landfill Gas). Therefore, mathematical settlement prediction model is proposed based on the generated gas volume. As one of stabilization methods, leachate recycling system is adopted to model tests. Two model tests; one is leachate recycled, the other is non-recycled, are componented with proposed model and analysed regarding gas generation and settlement. The proposed mathematical model requires correction coefficients of 1.4 and 1.7 for non-recycled model and recycled, respectively. The recycled model showed 22% increase of long-term settlement more than the non-recycled model.

• Journal of the Korean Geophysical Society
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• v.5 no.1
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• pp.19-27
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• 2002

Geophysical surveys(self-potential, electromagnetic, electrical resistivity, and seismic refraction methods) were performed to delineate the flow channel of leachate from a AMD (acid mine drainage) by correlating the anomalies to geochemical characteristics at an abandoned mine (Jangpoong mine). The geophysical responses attempted to be correlated with water sample analysis data(pH, EC, heavy metals, ${SO_4}^{-2}$). Electrical dipole-dipole resistivity sections represent the low-resistivity zone trending northwest, which indicates the leachate flow by AMD along the contact of the mine waste rock dump and the bedrock. From the overall points of geophysical and geochemical anomalies, it is summarized that the flow channel of leachate by AMD can be successfully imaged with composite interpretations on the geophysical and geochemical studies.

• Magazine of the Korean Society of Agricultural Engineers
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• v.43 no.4
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• pp.37-49
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• 2001

This study was performed in order to produce the basic data for developing prediction techniques of desalinization to be applicable to reclaimed tidal lands at the beginning stage. the desalinization experiments were carried out by two water management practices, namely, the leaching method by subsurface drainage and the rinsing method by surface drainage. The 5 soil samples used in this study were collected in 4 tidal land reclamation projects. Regression equations were obtained in order to investigate the changes of electrical conductivity during the desalinization of reclaimed tidal lands and to estimate water requirements for desalinization. The results obtained from this study were summarized as follows: 1. According to USDA Salinity Laboratory classification system of salt affected soils the reclaimed tidal land soils used in this study were saline-sodic soils with the high electrical conductivity and the high exchangeable sodium percentage. 2. With the increase of the water requirements for desalinization the electrical conductivity was decreased with high degree of correlationships and the desalinization effects were remakable in both the leaching method and the rinsing method. 3. In case of the leaching method the electrical conductivity had been reduced below the classification value of salt affected soils when the depth o water leached per unit depth of soil (Dwl/Ds) was 0.3 and the desalinization effects showed a tendency to be much the same in each treatment.

• Resources Recycling
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• v.2 no.2
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• pp.22-26
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• 1993

The flowsheet for the recovery of gallium and indium from zinc residues has been established based on the sulfuric acid treatment. In comparison with the alkali treatment, the method proposed in this work allowed the recovery of indium together with gallium. The majority of iron contained in leach liquor could be removed through the two-stage neutrallization under oxidative or reductive atmosphere. Crude gallium and indium could be obtained through the alkali and/or acid leaching of the products generated from the above treatment. In addition, cementation of indium with zinc powders could also be used for the concentration of it from weak acid solutions.

• Journal of Soil and Groundwater Environment
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• v.12 no.2
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• pp.55-64
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• 2007

An analytical method using ion-exchange chromatography was developed for simultaneous quantification of low-molecularweight organic acids ($C_1-C_6$ aliphatic carboxylic acids) and inorganic anions, and then applied to the assessment of ground water contaminated by leachates from a municipal solid waste landfill. Peak interferences of halide ions to organic acids were removed by pretreatment of water samples with Ag-containing cartridges. This method allowed accurate detection of low-molecular weight organic acids (i.e., formate, acetate, propionate, pyruvate, succinate, and oxalateas) low as 0.5 mg/L with a linear dynamic range up to 20 mg/L within 11 min run time along with typical inorganic anions. High level of pyruvate and low level of formate and acetate were detected in groundwater and landfill leachates using the analytical method. Pyruvate concentration in groundwater showed a significant correlation with concentrations of $Cl^-$ and $HCO_3^-$, and pyruvate levels decreased along the downgradient from the landfill, indicating the sources of pyruvate are landfill leachate.

• Resources Recycling
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• v.23 no.6
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• pp.22-29
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• 2014

Recycling process of iron should be developed for efficient recovery of neodymium (Nd), rare metal, from acid-leaching solution of Nd magnet. In this study, $FeCl_3$ solution as iron source was used for preparation of iron nano particles with the condition of various factors, such as, reductant, and surfactant. $Na_4P_2O_7$ and Polyvinylpyrrolidone (PVP) as surfactants, $NaBH_4$ as reductant, and palladium chloride ($PdCl_2$) as a nucleation seed were used. Iron powder was analyzed by using XRD, SEM for measuring shape and size. Iron nano particles were prepared at the ratio of 1:5 (Fe (III) : $NaBH_4$). Size and shape of iron particles were round-form and 50 ~ 100 nm size. Zeta-potential of iron at the 100 mg/L of $Na_4P_2O_7$ was negative value, which was good for dispersion of metal particle. When $Na_4P_2O_7$ (100 mg/L), PVP($FeCl_3:PVP$ = 1 : 4, w/w) and Pd($FeCl_3:PdCl_2$ = 1 : 0.001, w/w) were used, iron nano particles which were round-shape, well-dispersed and near 100 nm-sized range. In this condition, $FeCl_3$ solution changed with spent Nd leachate solution, and then it is possible to be made round-formed iron nano particles at pH 9 and at the reaction bath over 20 L which is not include any surfactant.

• Resources Recycling
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• v.13 no.5
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• pp.28-36
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• 2004

The extraction of platinum group metals such as Pt, Pd and Rh from spent automobile catalyst has been investigated by leaching in HCl solutions using $HNO_3$ or NaOCl as a oxidant. The effect of type and amount of oxidant, reaction time and pulp density on the extraction of platinum group metals was examined. Platinum group metals were recovered by the cementation method using aluminum as a reducing agent. The extraction ratio was higher when NaOCl was used as a oxidant. The optimum leaching conditions were obtained to be: HCl 8 M, the amount of NaOCl 1.4 mole, leaching temperature $90^{\circ}C$, leaching time 180 minutes, pulp density 400g/L. Under the optimum conditions, the extraction of Pt, Pd and Rh were 96.1%, 93.6% and 77.3%, respectively. With the addition of 2.0g of aluminum which corresponds to 28 equivalent the reduction were 98% for Pt. 98.8% for Pd and 65.3% for Rh, respectively.