• Journal of Powder Materials
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• v.15 no.4
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• pp.308-313
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• 2008

Al-Ni alloy nano powders have been produced by the electrical explosion of Ni-plated Al wire. The porous nano particles were prepared by leaching for Al-Ni alloy nano powders in 20wt% NaOH aqueous solution. The structural properties of leached porous nano powder were investigated by nitrogen physisorption, X-ray diffraction (XRD) and transmission Microscope (TEM). The surface areas of the leached powders were increased with amounts of AI in alloys. The pore size distributions of these powders were exhibited maxima at range of pore diameters 3.0 to 3.5 nm from the desorption isotherm. The maximum values of those were decreased with amounts of Al in alloys.

• Resources Recycling
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• v.22 no.2
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• pp.3-10
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• 2013

Indium is one of the rare metals, and it has been used mainly for preparation of indium tin oxide (ITO). This review investigated the process parameters and the merits and demerits of several methods to recover indium from the leaching solution of secondary resources, such as solvent extraction, ion exchange, and precipitation. D2EHPA has been used mostly as a cationic extractant for indium extraction in moderate acid solutions, while amine extractants are used in strong hydrochloric acid solution. Since the loading capacity of resins for indium is generally small, ion exchange has some advantage over solvent extraction only when the concentration of indium is low.

• Resources Recycling
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• v.21 no.3
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• pp.74-83
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• 2012

Rare earth metals have been made from rare earth compounds which were prepared from rare earth ore concentrates through successive processes such as leaching(i.e. extraction of rare earth elements to liquid media), separation, purification, precipitation. Here, process for treating monazite and bastnasite ore concentrates were briefly reviewed, and metallothermic reduction and fused salt electrolysis methods were introduced as the extraction technologies for rare earth metals.

• Journal of environmental and Sanitary engineering
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• v.12 no.3
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• pp.73-79
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• 1997

This research was intended as an investigation of applying Reduced Pressure Evaporation as efficient treatment method for landfill leachate. According to the variance of time, temperature, pressure and pH in experiments, the properties of leachate treatment are follows. The removal efficiencies of COD, NH$_{3}$-N, TOC, Conductivity and SS on the basis of reaction time was 96.4%-97.5%, -1.4%-53.7%, 81.7%-89.0%, 92.0%-95.3% and 99.86%-99.97%, respectively. When the pH of Influent was 7.5, the pH of effluent was increased to 10-11 with time elapse. It is concluded that the orgin of pH increase may be ammonia. When the properties of concentrate were investigated at the concentration ratio 90%(V/V), concentration difficiency represented in the ratio of experimental value/calculated value had following orders ; COD>TOC>NH$_{3}$-N>Conductivity>SS. Concentrate had good precipitation because of additive thermal treatment in the process. When evaporation experiments with pH adjustment of 4.0, 6.0, 7.5, 9.0 and 10.0 were performed ; Acidic evaporation experiments(pH 4.0, 6.0) showed low removal efficiency(81.6, 87.6%) of COD and high removal efficiency (97.5%. 84.6%) of NH$_{3}$-N at initial evaporation. Basic evaporation(pH 9.0, 10.0) showed high removal efficiency (97.2%, 98.9%) of COD and very low removal efficiency (-7.4%, -27.2%) of NH$_{3}$-N at initial evaporation.

• Journal of Environmental Impact Assessment
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• v.11 no.1
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• pp.13-23
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• 2002

본 연구에서는 침출수를 비롯한 매립지의 각종 오염물질 배출로 수자원이 오염되어 피폭체의 피해가 빈발하는 문제를 해결하기 위해서, 매립지의 상대적 유해성을 평가하여 한정된 환경관리 예산의 합리적 배분을 위한 우선순위를 결정할 수 있는 의사결정 지원도구로서 LHR(Landfill Site Hazard Ranking)모형을 개발했다. LHR모형은 다요소의사결정(多要素意思決) 기법에 정성적 위해성(危害性) 평가기법을 접맥시켜 주관적 가중치를 모형에 반영한 가치내재화(價値內在化) 모형이다. LHR모형은 피폭체의 주요 피폭경로를 지하수 이동경로와 지표수 이동경로로 보았으며, 각 이동경로별로 누출 가능성, 폐기물 특성 및 피폭체 특성으로 요소범주를 3종류로 구분하여 폐기물의 독성이나 매립량같은 특성이 매립지의 수리지질학적 요소 및 자연지리적 요소에 의해 결정되는 오염물질의 누출 가능성을 통해 매립지 주변의 지역주민과 취약한 수생태계 같은 피폭체에 끼치는 매립지의 유해성을 상대적으로 평가했다. 그리고 LHR모형에서는 매립지 유해성을 공기 이동경로 및 사회경제적 측면에서도 평가하기 위해 매립지 이격거리별 토지이용 형태의 유해성을 평가했다. 그리고 각 평가요소별 가중치는 위계분석과정(位階分析過程)의 쌍대비교법(雙對比較法)에 의하여 할당했으며, 민감도 분석으로 LHR모형을 검증했다.

• Applied Chemistry for Engineering
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• v.19 no.2
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• pp.179-184
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• 2008

The separation and purification of succinate are necessary for the succinic acid production by a fermentation process. Among the purification processes, desalination of succinate is inevitable. In this work, electrodialysis was selected as a desalination method and its operating parameters affecting the degree of desalination and energy consumption were examined. Commercialized electrodialysis apparatus was used in this work and its optimum operating parameters were determined by using design of experiment (DOE) method. Voltage, concentration of succinate, and pH were selected as main parameters. Among them, voltage seemed to be the most important one. The final conversion of succinate to succinic acid was calculated when the operating parameters were optimized. Finally, the effect of impurities, such as corn steep oil, yeast extract, and dextrose on the electrodialysis efficiency was also studied.

• Resources Recycling
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• v.16 no.6
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• pp.10-19
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• 2007

The mechanical process followed by hydrometallurgical treatment has been developed in order to recover cobalt and lithium from spent lithium ion battery. In the previous study, a citrate precursor combustion process to prepare cathodic active materials from the leaching solution was elucidated. Resynthesis of electrode materials should be more valuable in spent battery recycling. Conventional slurry mixing of $LiCoO_2$ and carbon cannot make uniform distribution, and therefore the cathode cannot reach the theoretical charge-discharge capacity and is easily degraded during the charge-discharge cycling. In this study, ultra-fine $LiCoO_2$ powders has been prepared by modification of the combustion process and fabricated the enhanced cathode by modification of mixing method of $LiCoO_2$ and carbon added.

• Resources Recycling
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• v.30 no.6
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• pp.36-42
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• 2021

Spent lithium-ion batteries are treated by reduction-smelting at high temperatures to recover valuable metals. Solvent extraction and precipitation of the HCl leaching solution of reduction-smelted metallic alloys resulted in a filtrate containing Ni(II) and a small amount of Si(IV). Adsorption and precipitation experiments were conducted to recover pure Ni(II) compounds from the filtrate. Si(IV) was selectively loaded onto polyacrylamide, but this method did not efficiently filter the solution due to an increase in viscosity. The addition of Na₂CO₃ as a precipitant to the filtrate led to the simultaneous precipitation of Ni(II) and Si(IV). However, it was possible to recover nickel oxalate with a purity higher than 99.99% by selectively precipitating Ni(II) with the addition of Na₂C₂O₄ as a precipitant.

• Korean Journal of Soil Science and Fertilizer
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• v.27 no.4
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• pp.275-283
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• 1994

The effects of anthracite and bituminous fly ash application on rice yield were investigated and the available silicate in paddy soil with ash application was analyzed. The obtained results are as follow : The yield of rice gradually decreased as the amount of anthracite ash increased. On the contrary, the rice yield gradually increased as the amount of bituminous ash increased. At harvesting stage the chemical properties in soil such as pH, organic content, and inorganic content($P_2O_5$, K. Ca, Mg and available $SiO_2$) were higher in bituminous ash treated soil than in anthracite treated soil. The amount of inorganic components in rice plant such as T-N, $P_2O_5$, $K_2O$, CaO, and MgO gradually decreased with the growing stage of rice. However, the amount of available silicate increased with the growing stage of rice. The silicate content in soil was determined by two different methods ; 1N-NaOAc extracted method and submerging setting method. In bituminous ash treated soil, the correlation between the silicate content in plant and in soil was found when the silicate content in soil was determined by the soil submerging method. In anthracite ash treated soil, however no correlation was found between the silicate content in plant and in soil determined by either method.

• Korean Journal of Soil Science and Fertilizer
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• v.15 no.4
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• pp.226-232
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• 1982

The incubation study of the phosphate Fertilizer Index (P.F.I) fertilizer recommandation method combining two factors-retention capacity of phosphate and available soil phosphate was conducted to test the applicability on both upland and paddy soils. The relationship between added P and the square root of the $NH_4OAc-P$ (for upland) or Bray No.1-P (for paddy) was a straight line for most of soils but was not straight for some soils which are low in phosphate absorption coefficient (P.A.C) However, the relationship between the value of the slop (termed as P.F.I) and the phosphate absorption coefficient was not showed a good correlation. The P.F.I was highly correlated with extractable Al on upland soils. The effect of extractable Al on P.F.I is more pronounced on newly reclaimed soil than cultivated upland. In case of paddy soils the P.F.I showed a high correlation with active iron contents. Also, P.F.I method was compared to NPK field trial on paddy soils to eximaine the applicability of the method in determining phosphate fertilizer recommandation.