• Resources Recycling
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• v.16 no.3 s.77
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• pp.34-43
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• 2007

A comparative study of the extraction behavior of vanadium and titanium in sulphate solutions using Cyanex272, PC88A and Alamine336 has been carried out. effect of pH in sulphate solutions, concentration of extractant and extraction isotherms has been studied. Solvent extraction separation studies of vanadium and titanium from the mixed solutions were also carried out in order to obtain a criterion for choosing the more effective extraction regent. From the experimental results, it was conformed that Alamine336 was good extractant to extraction of vanadium and separation from titanium from the mixed solutions.

• Journal of the Korean GEO-environmental Society
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• v.7 no.1
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• pp.29-39
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• 2006

Recently, Korea brings to remarkable levels about industrialization, modernization, population and development of technology. Especially, the rapidly growing from this technology has increased the burden on existing industrial waste landfills. The purpose of this research is to existing knowledge base of landfill cover liner behavior during periods freeze/thaw. Although these tests have been invaluable in clarifying the problem of freeze/thaw, extending the results of such experimental studies to prototype landfills are questionable. For this investigation, the author utilized a large scale laboratory simulation allowing inclusion of the field depth of the cover systems, layered soil profiles, rainfall simulation, a cold climate and boundary conditions similar to those encountered in the landfill. And the soil materials used stabilized soils (mixed clays, cements, and minerals) instead of clays. The bottom liners are made up of drainage layer (30cm), stabilized layer (75cm), and leach collection layer (60cm). The stabilized layers are made up of supporting layer (45cm) and impermeable layer (30cm) - consisted of $P_A$ and $P_B$ layer.

• Journal of the Korean Geotechnical Society
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• v.18 no.4
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• pp.137-146
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• 2002

Geomembrane, compacted clay liner, and geosynthetic clay liner (GCL) are widely used to prevent leachate from leaking to adjacent geo-environment at a municipal solid waste (MSW) landfill. Interface shear strength between GCL and geomembrane installed at a landfill side slope is important properties for the safe design of side liner or final cover systems. The interface shear strength between two geosynthetics was estimated by a large direct shear test in this study. The shear strength was evaluated by the Mohr-Coulomb failure criterion. The effects of normal stress, hydration or dry condition, and a hydration method were investigated. The test results show that the interface shear strength and shear behavior varied depending up on the level of normal stress, the type of geosynthetic combinations, and a hydration method. When GCLs were sheared after being hydrated under 6kPa loading, the results were consistent with those published by other researchers. Summaries of friction angles, normal stress and hydration condition is presented. These friction angles could be used as a reference value at a site where similar geosynthetics are installed.

• Journal of the Korean Geotechnical Society
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• v.21 no.6
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• pp.117-126
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• 2005

The chemical property analysis on the deposited clay using scanning electron microscope and energy dispersive x-ray spectrometer were performed. Also, the triaxial compression tests and consolidation tests using NaCl aqueous solution and leachate as substitute pore (or saturated) water in samples were carried out to find out the behaviour characteristics of strength and deformation of contaminated deposited clay. from the chemical composition analysis results of clay samples, the magnitudes of composition ratio were revealed in the order of O, C, Si, Al, and Fe. Of these, why the ratio of carbon appeared to be large is estimated as due to the increase of the phyto-planktons after the construction of tide embankment. In the triaxial compression test and consolidation test results, the shear strength and compression properties have increased with the increase in concentration of contaminant (NaCl). This phenomenon is considered as to be caused by the changes of soil structure to flocculent structure owing to the decrease in the thickness of diffuse double layer in proportion to increase in the concentration of electrolyte.

• Journal of Powder Materials
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• v.21 no.3
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• pp.202-206
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• 2014

Leaching of MOCVD dust in the LED industry is an essential stage for hydro-metallurgical recovery of pure Ga and In. To recover Ga and In, the leaching behavior of MOCVD scrap of an LED, which contains significant amounts of Ga, In, Al and Fe in various phases, has been investigated. The leaching process must be performed effectively to maximize recovery of Ga and In metals using the most efficient lixiviant. Crystalline structure and metallic composition of the raw MOCVD dust were analyzed prior to digestion. Subsequently, various mineral acids were tested to comprehensively study and optimize the leaching parameters such as acidity, pulp density, temperature and time. The most effective leaching of Ga and In was observed for a boiling 4 M HCl solution vigorously stirred at 400 rpm. Phase transformation of GaN into gallium oxide by heat treatment also improved the leaching efficiency of Ga. Subsequently high purity Ga and In can be recovered by series of hydro processes.

• Journal of the Korean GEO-environmental Society
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• v.17 no.8
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• pp.29-37
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• 2016

In order to prevent leakage of contaminants in offshore landfill, vertical barrier should be installed. Vertical barrier should be installed at designed depth of seabed to prevent the horizontal transport of contaminant in the subsurface. In this study, the seepage and contaminant transport in the subsurface according to embedded depth of vertical barrier were analyzed by using 2-D finite element analysis program SEEP/W and 3-D finite difference analysis program Visual Modflow. Numerical modelling results show that seepage flux and contaminant transport in seabed was greatly reduced when vertical barrier was installed at certain depth of low permeable layer. Therefore, the determination of minimum embedded depth for preventing contaminant leakage is helpful to design the economical vertical barrier.

• Journal of the Korean GEO-environmental Society
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• v.11 no.11
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• pp.47-54
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• 2010

Nowadays, geosynthetics for reinforcement and protection are widely applied to the waste landfill site. Current research indicates the potential for progressive failure in geosynthetic-soil system depends on the interface shear strength governed by several intrinsic factors such as moisture, normal stress, chemical, etc. In particular, the effect of the acidity and basicity from the leachate is intensively reviewed to assess the chemical reaction mechanism of interface shear strength under the cyclic loading condition. New multi-purpose interface apparatus(M-PIA) has been manufactured and the cyclic direct shear tests using submerged geosynthetics and soils under the different chemical conditions have been performed, consequently, the thickness of interface and shear stress degradation are verified. The basic schematic of the Disturbed State Concept(DSC) is employed to estimate the shear stress degradation in the interface, then, normalized disturbed function is obtained and analyzed to describe the shear stress degradation of geosynthetic-soil interface with chemical influence factors under dynamic condition.

• Resources Recycling
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• v.31 no.3
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• pp.73-80
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• 2022

Reduction smelting of spent lithium-ion batteries at high temperature produces metallic alloys. Following solvent extraction of the leaching solutions of these metallic alloys with either sulfuric or hydrochloric acid, the raffinate is found to contain Ni(II), Co(II), Mn(II), and Si(IV). In this study, two cationic exchange resins (Diphonix and P204) were employed to investigate the loading behavior of these ions from synthetic sulfate and chloride solutions. Experimental results showed that Ni(II), Co(II), and Mn(II) could be selectively loaded onto the Diphonix resin from a sulfate solution of pH 3.0. With a chloride solution of pH 6.0, Mn(II) was selectively loaded onto the P204 resin, leaving Ni(II) and Si(IV) in the effluent. Elution experiments with H₂SO₄ and/or HCl resulted in the complete recovery of metal ions from the loaded resin.

• Journal of Soil and Groundwater Environment
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• v.28 no.6
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• pp.24-32
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• 2023

Continuous increase of domestic meat consumption has inevitably increased generation of livestock manure and caused severe environmental impacts on ecosystem and human beings. This work produced biochar from cattle manure samples with different composting aging stages and investigated the properties of the produced biochar. The result of thermogravimetric analysis showed that thermal decomposition of the manure initiated at <600℃. The biochar yield was higher for the manure with a longer pre-composting period due to the elimination of microbially metabolized carbons during composting process. The result of FT-IR analysis showed that the number of surface functional groups were reduced during pyrolysis while enhancing the graphitic structures of the carbon framework. Manure samples tended to leach out N and P in leaching tests, with its amount higher for aged one than fresh one. However, their leaching was substantially suppressed when the manure was produced into biochar. In XPS spectra, it was found that N and P in the manure incorporated into biochar surface to form N-doped graphitic carbon and P-N-moieties, respectively. The findings of this work suggest that the thermochemical process can be of a viable option to valorize into biochar for potential environmental applications as well as to alleviate undesired nutrients loading to the environment.

• Resources Recycling
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• v.26 no.4
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• pp.88-94
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• 2017

The recovery of gold in cyclone type electrolytic cell was conducted from solution for stripping gold of PCB by cyanide. The electrolytic recovery behaviors of gold was investigated by reaction time and addition of electrolytic sodium hypochlorite (NaOCl) and gold plating additive (KG-120). Because the electrolysis generated NaOCl reacted with the cyanide in the leachate by alkaline chlorination, more than 99% of the cyanide was removed at a $NaOCl(g)/CN^-(g)$ ratio of 1.0. When NaOCl was added during the recovery of the gold from cyanide leachate in the cyclone electrolytic cell, the recovery of gold was 98% at the ratio of $NaOCl(g)/CN^-(g)$ from 0.5 to 2.5 in 480 minutes and decreased rapidly over the ratio of 3.0. Gold was recovered more than 99% by adding 1.5 and 4.5%(v/v) of KG-120 with NaOCl in 480 minutes. In particular, when the concentration of KG-120 was 3.5 and 4.5%(v/v), more than 96% of gold was recovered within 240 minutes and the initial recovery rate was relatively faster. The optimum concentration of KG-120 is 3.5%(v/v) considering the economic feasibility and efficiency.