• Journal of the Korean Chemical Society
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• v.46 no.1
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• pp.7-13
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• 2002

Although it has been known that the magnetized water shows different physicochemical properties, the exact nature of the magnetized water is not clearly elucidated yet. We have explored the effect of magnetized water in the precipitation of salts, i.e., $BaSO_4,\;BaCO_3,\;CaCO_3$, and in the hydration hardening of gypsum plaster. The amount of salt precipitation was measured by salt filter assay in water bath, $25^{\circ}C$ and also the hydration hardening speed of gypsum plaster was measured by the Gillmore needle method at room temperature. When the salt ions were interacted with each other in 0.1 M concentration, the precipitation reactions of $BaSO_4,\;BaCO_3$, and $CaCO_3$ increased more in the magnetized water, about 3.6%, 3.8%, and 4.4%, respectively, than in the control water. And the hydration hardening speed of gypsum plaster increased more in the magnetized water than in the control water. These data suggest that the magnetized water, which is supposed to be organized by forming numerous nano/micro clusters, induces the increase of salt precipitation and also accelerates the hydration hardening speed of gypsum plaster.

• Journal of the Korea Organic Resources Recycling Association
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• v.26 no.1
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• pp.47-53
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• 2018

Recovery of lactic acid from fermentation broth using chemical precipitation was investigated with various chemicals. Effects of chemical types, mixing speeds, settling duration, and solvent addition were evaluated to improve the recovery rates of lactic acid. Overall, recovery efficiencies increased as the dosage of chemicals increased. Recovery rate of lactic acid by CaO was higher than those of $Ca(OH)_2$ and $CaCO_3$. Recovery of lactic acid increased by 48% under the optimized reaction conditions which included a mixing speed at 180 rpm, a settling duration of 24 h, and addition of ethanol at 25%(v/v). Practical application needs to consider types and concentrations of other organic acids as well as lactic acid. Based upon the results of fluorescence excitation emission matrix (FEEM), size exclusion chromatography (SEC), characteristics of recovered lactic acid were same as that in the fermentation broth.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.8 no.3
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• pp.454-462
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• 1998

Mechanisms and conditions for rounding of AUC particles were examined during AUC precipitation. Rounding of AUC particle was possible only by external circulation using pump, not by internal circulation using agitator. The rate of AUC rounding $(dn_p/dt)$ was proporational to operation conditions such as magma density $(M_t:g-U/{\iota}l)$, turn over ratio $(T_o)$ and impeller tip velocity of pump (U); $ dn_p/dt{\propto}M_t{\cdot}T_o{\cdot}U^2$. The validity of this relationship was qualitatively confirmed by comparing the expermental results. Two rounding mechanisms were suggested. One is crack formation mechanism and the other etch-pit formation mechanism on the surface of AUC particle. It was found that the crack formation is more dominant at the initial stage and the etch-pit formation at the final stage of the AUC precipitation.

• Journal of Korean Society of Water and Wastewater
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• v.20 no.3
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• pp.451-460
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• 2006

While sludge settles down in a batch column, sludge concentration becomes high. Sludge concentration change is one of the most critical causes of the sludge settling velocity variation. Therefore, sludge concentration change causes sludge index to change. SVI is more sensitive than other sludge indexes to the change of sludge concentration. And if sludge-water interface has reached final height within 30minutes, SVI is not suitable for prediction of sludge settling characteristic, Therefore, SVIs of each sludge are, in some cases, different although each sludge has the same settling velocity. But SVI has been widely used to interpret sludge settling characteristic by a simple testing method. This work has two purposes. The first purpose is to predict sludge settling velocity by using sludge-water interface settling velocity. And the second purpose is to develop new sludge settling characteristic index to exactly interpret sludge settling characteristic by overcoming the limit of SVI.

• 한국도로학회:학술대회논문집
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• 2009.11a
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• pp.669-672
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• 2009

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.8 no.2
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• pp.115-122
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• 2010

In this study, the removal of Cs and Tc from a simulated fission products (FP) solution which were co-dissolved with U during the oxidative-dissolution of spent fuel in a mixed carbonate solution of $(Na_2CO_3-NaHCO_3)-H_2O_2$ was investigated by using a selective precipitation method. As Cs and Tc might cause an unstable behavior due to the high decay heat emission of Cs as well as the fast migration of Tc when disposed of underground, it is one of the important issues to removal them in views of the increase of disposal safety. The precipitation of Cs and Re (as a surrogate for Tc) was examined by introducing sodium tetraphenylborate (NaTPB) and tetraphenylphosponium chloride (TPPCl), respectively. Precipitation of Cs by NaTPB and that of Re by TPPCl were completed within 5 minutes. Their precipitation rates were not influenced so much by the temperature and stirring speed even if they were increased by up to $50^{\circ}C$ and 1,000 rpm. However, the pH of the solution was found to have a great influence on the precipitation with NaTPB and TPPCl. Since Mo tends to co-precipitate with Re at a lower pH, especially, it was effective that a selective precipitation of Re by TPPCl was carried out at pH of above 9 without co-precipitation of Mo and Re. Over 99% of Cs was precipitated when the ratio of [NaTPB]/[Cs]>1 and more than 99% of Re, likewise, was precipitated when the ratio of [TPPCl]/[Re]>1.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.5
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• pp.3336-3344
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• 2014

The purpose of this study is small scale coagulation module is developed and demonstrated through a lab-scale test. Recent as a sewage treatment rate increases, have heightened the interest in the necessity on the nonpoint source and developing a small processing unit has been increased. Coagulation sedimentation module in this study is additional growth of floc through swirling in the outside zone, reduction of microstructure floc number and the internal settling zone through vertical/level flow complex sedimentation method after the coagulation process precipitation method as an effective high separation efficiency can be divided was also assessed. Coagulation sedimentation module can increase the load factor was 4.4 times compared to conventional clarifier base on the same volume and surface area through vertical/level flow. In this study, this process was selected formation and maintenance of swirling and uniform flow distribution in the internal settling zone as an important design factor, to derive its FLUENT was used to characteristics of the flow model. Through the simulation of swirling, influent velocity, dimensions of external basin, hopper depth of bottom cone was determined and through analysis of velocity distribution, flow distribution detailed specifications are derived like as diameter and number of effluent hole. Lab-scale($120{\ell}/hr$) test results, influent of 300~800 NTU to less than 10 NTU without polymer feeding was able to operate in the 20minutes retention time(surface loading rate $37.3m^3/m^2$-day), and through analysis FLUENT the possibility of using design parameters were derived.

• Clean Technology
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• v.10 no.1
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• pp.1-7
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• 2004

In this study, the performance of Aluminium foil etching waste(PWF100) as a cohesive agent was estimated and the methods to commercialize it were investigated through comparison of physical properties between Aluminium foil etching waste(PWF100) and commercial cohesive agent(PAC17). The height of sediment bed was measured according ot the change of the concentration of BKN-100, BKR-110, and BKR-120 prepared by using PWF100. When the concentrations of BKN-100, BKR-110, and BKR-120 were increased, the heights of sediment bed were constant after decreased. Also, the density of sediment bed was investigated according to the change of the concentration of BKN-100. When the concentrations of BKN-100 were increased, the densities of sediment bed were decreased. In addition, based on the concentration of BKN-100, BKR-110, and BKR-120, the sediment rate was experimented. When the concentrations of BKN-100, BKR-110, and BKR-120 were increased, sediment rates were rapid and then slow. Moreover, the volumes of sediment bed were measured according to the change of the concentration of BKN-100. According to increasing the concentrations of BKN-100, the required time for getting to the minimum volume of sedment bed were reduced and then increased. Lastly, the required time for sedimentation based on the concentration of BKN-100, BKR-110, and BKR-120 was investigated. When the concentrations of BKN-100, BKR-110, and BKR-120 were increased, the required times for sedimentation were increased after decreased. From these results, it can be concluded that the PWF100 acts as a cohesive agent.

• Journal of the Korean Society of Food Science and Nutrition
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• v.33 no.8
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• pp.1359-1366
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• 2004

Ultra high temperature treated (UHT) skim milk and colloidal calcium phosphate-free skim milk were treated with microbial transglutaminase (TGase), ultracentrifuged at various rates, lyophilized, and observed for morphological properties with a scanning electron microscope (SEM). UHT skim milk showed small holes of associated micelles at lower centrifugal rates, and became thick and irregular, and fine particles were associated regularly at higher centrifugal rates. When UHT skim milk with TGase was incubated for 1 hour, casein micelles aggregated and broadened as centrifugation rate increased. When UHT skim milk with TGase was incubated for 8 hours, casein micelles were associated irregularly to large aggregates and widened. Colloidal calcium phosphate-free skim milk with TGase incubated for 1 hour and separated by two-step centrifugation showed aggregated lump, while the milk incubated for 8 hours with TGase was associated with broadened, compact, and regular layers as the centrifugation rate increased. Such phenomena were caused by heat treatment, protein crosslinking reaction catalyzed by TGase and conformational changes of casein molecules, and could be dependent on reaction time, temperature and ultracentrifugation rate.

• Clean Technology
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• v.29 no.4
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• pp.327-332
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• 2023

This study investigated synthesis gas production via steam reforming of biogas. Ni-Al₂O₃ and Ni-CeO₂ catalysts were synthesized using the co-precipitation method, with controlled precipitation agent injection rates. Catalytic performances were tested at various temperatures, with a gas composition ratio of CH₄:CO₂:H₂O = 1:0.67:3 and a gas hourly space velocity (GHSV) of 647,000 mL h^-1 gcat^-1. The rate of precipitation agent injection influenced the characteristics of the catalysts depending on the type of support used. As the temperature increased, both the CO₂ reforming of methane and the reverse water gas shift reactions occurred. The Ni-Al₂O₃ catalyst, synthesized with a single injection of the precipitation agent, exhibited the best catalytic activity under conditions with sufficient steam supply among the prepared catalysts, due to its high Ni dispersion.