• Clean Technology
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• v.28 no.3
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• pp.218-226
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• 2022

As a result of the recent social transformation towards a hydrogen economy and carbon-neutrality, the demands for hydrogen energy have been increasing rapidly worldwide. As such, eco-friendly hydrogen production technologies that do not produce carbon dioxide (CO₂) emissions are being focused on. Among them, ammonia (NH₃) is an economical hydrogen carrier that can easily produce hydrogen (H₂). In this study, Ru/Al₂O₃ catalyst coated onmetallic monolith for hydrogen production from ammonia was prepared by a dip-coating method using a catalyst slurry mixture composed of Ru/Al₂O₃ catalyst, inorganic binder (alumina sol) and organic binder (methyl cellulose). At the optimized 1:1:0.1 weight ratio of catalyst/inorganic binder/organic binder, the amount of catalyst coated on the metallic monolith after one cycle coating was about 61.6 g L^-1. The uniform thickness (about 42 ㎛) and crystal structure of the catalyst coated on the metallic monolith surface were confirmed through scanning electron microscopy (SEM) and X-ray diffraction (XRD) analysis. Also, a numerical optimization regression equation for NH3 conversion according to the independent variables of reaction temperature (400-600 ℃) and gas hourly space velocity (1,000-5,000 h^-1) was calculated by response surface methodology (RSM). This model indicated a determination coefficient (R²) of 0.991 and had statistically significant predictors. This regression model could contribute to the commercial process design of hydrogen production by ammonia decomposition.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2010.10a
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• pp.53-54
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• 2010

국내에서 소규모 어항의 재개발에 관광객 유치를 위한 친환경적인 기술의 적용이 본격화되고 있다. 항내수질 개선이라는 목적 하에서 외곽시설인 방파제의 선택은 항내 정온과 제체 안정성의 확보가 전제되어야 한다. 따라서 본 연구에서는 친환경방파제인 슬릿방파제의 수리특성을 파악하기 위한 수리모형실험을 수행하고 그 결과를 이용하여 파랑변형 및 유동 실험을 수행하였다. 현장 적용성 확인을 위하여 선정된 구조라항은 우리나라 남해의 소규모 어항으로, SSE, S, SSW파향에 영향을 받는 지역으로, 슬릿방파제를 적용한 결과 제체안정성과 항내 정온도가 확보되는 것으로 나타났다. 이는 슬릿방파제의 특징으로 장주기파의 통과율이 뛰어나다는 점과 소파효과라는 1차적인 목적과 항만 및 연안수역에서 해수교환의 향상이라는 2차적인 목적을 동시에 만족하는 것으로 나타났다.

• Journal of the Korean Geosynthetics Society
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• v.20 no.2
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• pp.1-11
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• 2021

In this study, a study related to laboratory and pilot test were performed to use an environmental soil stabilizer developed to induce a hardening reaction similar to that of Ordinary Portland Cement (OPC) by using industrial by-products of blast furnace slag and the combustion ash of a circulating fluidized bed boiler as the main material. For this, specimens were prepared using liquid A of sodium silicate and silica sol, and liquid B of an environmental soil stabilizer (or OPC), and laboratory tests were performed to analyze the strength and environmental characteristics. And pilot test was performed on the aging reservoir, field permeability test and electrical resistivity survey were performed in the field to analyze the applicability. As a result of the laboratory test, the homo-gel compressive strength of the chemical injection material using the environmental soil stabilizer as liquid B was about 2.88 to 3.23 times greater than that of OPC. In addition, the elution amount of most heavy metals was lower than that of OPC, and the survival rate in the fish, acute toxicity test was 100%. Therefore, when judged based on the results of the laboratory test, it was analyzed to be superior to OPC in terms of strength and environment. In the results of the pilot test in the aging reservoir, when the environmental soil stabilizer was reinforced with liquid B of the chemical injection material, the coefficient of permeability in the aging reservoir decreased to 1/50 level. In addition, as a result of the electrical resistivity survey, it was analyzed that the electrical resistivity inside the aging reservoir increased as time passed, the saturation zone disappeared, and the overall reinforcement.

• Journal of the Korea institute for structural maintenance and inspection
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• v.16 no.5
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• pp.59-67
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• 2012

During the manufacturing of Portland cement, CO2 gas is also necessarily produced through both decarbonation of calcium carbonate and kiln burning. By partially replacing the Portland cement with limestone powder, which is an inert filler in a concrete mixture, CO2 consumption can be reduced in a construction field. This study is to investigate the fundamental durability characteristics of limestone powder added concrete. Experimental variable was the replacement ratio of limestone powder from 0% to 25% with 5% increment. Durability characteristics were investigated by resistance to freeze-thaw, alkali-silica reaction and de-icing chemical in addition to the properties of fresh concrete. From test results, it was observed that the addition of limestone powder did not significantly affect the resistance to freeze-thaw reaction and de-icing chemical. The addition of limestone powder reduced the occurrence potential of alkali-silica reaction by reducing an alkali content in Portland cement.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2009.11a
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• pp.165-170
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• 2009

Since artificial building materials and environmental contamination are getting worse recently, people has been interested in eco-friendly construction. In addition, the problems like Sick Building Syndrome are issued these days. In order to solve these problems, the reuse of building materials and the development of environment-friendly materials are urgently in demand. In this sense, Hwangtoh is in the limelight as the environment-friendly material, and broad studies on it have been in progress. However the reactivity of Hwangtoh is low, and without activation process it is very hard to use it as a building material. This study examined the usability of Hwangtoh as an environmental building material by experimenting the reactivity of inactivated Hwangtoh with Reaction Induction Material.

• Applied Chemistry for Engineering
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• v.26 no.3
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• pp.347-350
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• 2015

In this study, ionic liquids have been employed as a green catalyst in the alkylation of isobutane with 2-butene. One of acid ionic liquids, 1-octyl-3-methylimidazolium-bromide-aluminum chloride, was used in the reaction. Effects of the liquid hourly space velocity (LHSV), reaction temperature and composition of ionic liquids on the reaction performance were investigated in order to optimize reaction conditions. Under identical reaction conditions, the optimum reaction temperature was $80^{\circ}C$ and the ionic liquid with the anion composition of 0.56 showed an excellent reaction activity. Moreover, a correlation model was developed with a statistical approach to predict the product yields.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2010.05a
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• pp.602-603
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• 2010

• Journal of the Korean Applied Science and Technology
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• v.36 no.2
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• pp.676-684
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• 2019

The Pictet-Spengler reactions have widely known for the organic synthesis or biosynthesis of biologically active compounds, tetrahydro-${\beta}$-carbolines. We have developed the simple and efficient synthetic method for the synthesis of ${\beta}$-carbolines in water. Their chemical structures were characterized by nmr and UPLC/MS/QTOF. Calculated masses of compound 1 ($C_{17}H_{17}N_2$ 249.1392), 2 ($C_{17}H_{23}N_2$ 255.1861), 3 ($C_{19}H_{21}N_2O_3$ 325.1552) and 4 ($C_{19}H_{19}N_2O$ 279.1497) were almost identical with the detected masses of compound 1 (249.1315), 2 (255.1789), 3 (325.1460) and 4 (279.1364) respectively. Those synthesized four compounds showed strong antibiotic activity against the common E. coli.

• Korean Journal of Organic Agriculture
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• v.21 no.1
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• pp.19-31
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• 2013

As a result of analysis on situations of environment-friendly school meals, it was obtained that student's parents were interested in food safety and the importance of sanitary supervision. Many parents responded that environment-friendly school meals increased the health and eating habits of their children. The higher and higher educated parents responded that environment-friendly school meals effected on the children's health positively. Also, the higher educated parents responded that environment-friendly school meals effected on the children's eating habits positively. After the environment-friendly school meals, the item increase to purchase was vegetables by 25% of the consumers who purchase environment-friendly agri-products. The second and third increasing items were respectively fruits and rice. When environment-friendly agri-products were consumpted and influenced positively through school meals, the consumption of environment-friendly agricultural products will be increased. The expansion of environment-friendly school lunch program cannot bring the consumption expansion of environment-friendly agri-products immediately. However, when the persistent promotion and student's parents confidence on environment-friendly agri-products were accumulated and experienced positive effects through school meals, it will give a positive effect on the consumption of environment-friendly agr-products.

• Korean Chemical Engineering Research
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• v.60 no.3
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• pp.452-458
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• 2022

Three types of gas-liquid hybrid horizontal, vertical and needle-to-cylinder plasma reactors were fabricated. Through these reactors, a high-efficiency, eco-friendly cleaning concept that generates reactive active species generated in atmospheric plasma discharge and gas-liquid activation reaction of cleaning components through the potential difference within the electrode was presented. As a result of comparing the efficiency for cleaning performance, the needle-to-cylinder type reactor had the best characteristics. Through this study, it was confirmed that the gas-liquid hybrid atmospheric pressure plasma reactor has the potential to be applied to ultra-precision cleaning processes such as semiconductor processes.