• The Journal of Korean Academy of Prosthodontics
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• v.52 no.4
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• pp.312-316
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• 2014

Purpose: The aim of this study was to compare the fracture toughness of currently available resin cements for zirconia restorations and evaluate the effect of water storage on fracture toughness of those resin cements. Materials and methods: Single-edge notched specimens ($3mm{\times}6mm{\times}25mm$) were prepared from three currently available dual cure resin cements for zirconia restorations (Panavia F 2.0, Clearfil SA luting and Zirconite). Each resin cement was divided into four groups: immersed in distilled water at $37^{\circ}C$ for 1 (Control group), 30, 90, or 180 days (n=5). Specimens were loaded in three point bending at a cross-head speed of 0.1 mm/s. The maximum load at specimen failure was recorded and the fracture toughness ($K_{IC}$) was calculated. Data were analyzed using one-way ANOVA and multiple comparison $Scheff{\acute{e}}$ test (${\alpha}$=.05). Results: In control group, the mean $K_{IC}$ was $3.41{\pm}0.64MN{\cdot}m^{-1.5}$ for Panavia F, 2.0, $3.07{\pm}0.41MN{\cdot}m^{-1.5}$ for Zirconite, $2.58{\pm}0.30MN{\cdot}m^{-1.5}$ for Clearfil SA luting respectively, but statistical analysis revealed no significant difference between them. Although a gradual decrease of $K_{IC}$ in Panavia F 2.0 and gradual increases of KIC in Clearfil SA luting and Zirconite were observed with storage time, there were no significant differences between immersion time for each cement. Conclusion: The resin cements for zirconia restorations exhibit much higher $K_{IC}$ values than conventional resin cements. The fracture toughness of resin cement for zirconia restoration would not be affected by water storage.

• The Journal of Korean Academy of Prosthodontics
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• v.51 no.2
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• pp.73-81
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• 2013

Purpose: The purpose of this study was to evaluate the effect of surface treatment on the shear bond strength of zirconia ceramic to 3 resin cements. Materials and methods: A total of 143 disk-shaped Zirconia blocks (HASS Co., Gangneung, Korea) were randomly divided into three treatment groups: (1) only 50 ${\mu}m$ $Al_2O_3$ sandblasting, (2) 50 ${\mu}m$ $Al_2O_3$ sandblast and zircona liner, (3) 50 ${\mu}m$ $Al_2O_3$ sandblasting and Rocatec (3M ESPE, Seefeld, Germany). Bistite II (Tokuyama Dental Co., Japan), Panavia F (Kuraray Medical, Japan), and Superbond C&B (Sun Medical, Japan) were used to cement onto the zirconia. After 24h of storage in distilled water, shear bond strength was evaluated. High value group was re-tested after thermocycling at 5,000 cycles(5-$55^{\circ}C$). Shear bond strength data were analyzed with one-way ANOVA, two-way ANOVA test and Post Hoc Test (${\alpha}$=.05). Shear bond strength data before and after thermocycling were analyzed with Independent sample T test (${\alpha}$=.05). Results: Super-bond C&B treated with Rocatec showed the most high shear bond strength. Super-bond C&B groups resulted in significantly higher than other cement groups (P<.05). Rocatec groups resulted in significantly higher than other surface treatment groups (P<.05). Shear bond strength has increased in Panavia F treated with Zirconia liner (P<.05). After thermocycling, shear bond strength was increased in Super-bond C&B treated with Rocatec but decreased in other groups (P<.05). Conclusion: Super-bond C&B cement resulted the highest shear bond strength and Rocatec system enhanced the shear bond strength. After thermocycling, shear bond strength has decreased in most resin cements except Super-bond C&B treated with Rocatec.

• Journal of Korean Academy of Oral and Maxillofacial Radiology
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• v.24 no.1
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• pp.59-66
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• 1994

The radiopacity of six composite resins, three resin luting cements and ten filling materials were studied. The purpose was to obtain an indication of radiopacity value of different brands within each of these groups of materials and to show differences in radiopacities of filling materials and natural tooth structures. On radiographs, the optimal densities of standardized samples were determined by computer imaging system and radiopacity values of the materials were expressed in millimeter equivalent aluminum. Within the groups of materials studied, there was considerable variation in radiopacity. The composite resins of P-50, Z100 and Prisma AP.H displayed much higher radiopacities than aluminum. Panavia resin cement was shown to be similarly radiopaque to aluminum. Generally, the radiopacity of base and filling materials appeared to be higher than that of the enamel and dentin. If materials with substantial difference in radiopacity are used in combined applications for restorative treatment of teeth, lower radiopacity can interfere with the diagnosis and detection of gaps near the restoration.

• Restorative Dentistry and Endodontics
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• v.10 no.1
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• pp.71-83
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• 1984

The purpose of this study was to evaluate the transmission spectrum of the set calcium hydroxide dental cement (Dycal, L.D. Caulk Co. Milford, Del.) Cement was prepared for A T R spectra at a low powder-to-liquid ratio of 3.0gm/ml in order to retard the reaction and facilitate the manipulation of loading the cement into the cell. Spectra were recorded on an I R Spectrophotometer (MX-1, FT) at an agle of incidence of 55. The A T R cell was a RIIc Model TR5 with a hemisperical KRS-5 (Thallium-Bromide-Iodide). A spectrum was recorded within 3 minutes. Further spectra were recorded after 5,10,30 minutes and 1,5,24, 72 hours. The results were as follows; 1. The setting reaction between acid paste and base past would take place fastly within 10 minutes after mix, and that would be slow until 72 hours after mix. 2. In the set cements, some methyl salicylate and calcium hydroxide remained unreacted until 72 hours after mix. 3. The setting reaction and the reaction rate occuring at the surface and in the bulk cements were similar. 4. The chelates were bound together between calcium hydroxide and methyl salicylate.

• Restorative Dentistry and Endodontics
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• v.34 no.2
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• pp.113-119
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• 2009

The purpose of this study was to compare the tensile bond strength of several self-adhesive resin cements bonded to dentin surfaces with different wet conditions. Three self-adhesive resin cements: Rely-X Unicem (3M ESPE, St. Paul, MN. USA). Embrace Wetbond (Pulpdent. Oakland. MA. USA). Maxcem (Kerr. Orange. CA. USA) were used. Extracted sixty human molars were used. Each self-adhesive resin cement was adhered to the dentin specimens (two rectangular sticks from each molar) in different wet conditions. Tensile bond strength were measured using universal testing machine (EZ Test. Shimadzu corporation. Kyoto. Japan) at a crosshead speed of 1.0mm/min. After the testing. bonding failures of specimens were observed by Operative microscope (OPMI pro, Carl Zeiss. Oberkochen, Germany). T-test was used to evaluate the effect of dentin surface wetness. One-way ANOVA test was used to evaluate the tensile bond strength of self-adhesive resin cements in the same condition. Scheffe's test was used for statistical analyzing at the 95% level of confidence. The result showed that wetness of dentin surface didn't affect tensile bond strength of self-adhesive resin cements and Maxcem showed the lowest tensile bond strength.

• Korean Journal of Dental Materials
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• v.44 no.1
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• pp.69-77
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• 2017

The aim of this study was to investigate the effects of chitosan powder addition on the strengthening of conventional glass ionomer cement. Two types of chitosan powders with different molecular weight were mixed with conventional glass ionomer cement (GIC): low-molecular weight chitosan (CL; 50~190 kDa), high-molecular weight chitosan (CH; 310~375 kDa). The chitosan powders (CL and CH) were separately added into the GIC liquid (0.25-0.5 wt%) under magnetic stirring, or mixed with the GIC powder by ball-milling for 24 h using zirconia balls. The mixing ratio of prepared cement was 2:1 for powder to liquid. Net setting time of cements was measured by ISO 9917-1. The specimens for the compressive strength (CS; $4{\times}6mm$), diametral tensile strength (DTS; $6{\times}4mm$), three-point flexure (FS; $2{\times}2{\times}25mm$) with flexure modulus (FM) were obtained from cements at 1, 7, and 14 days after storing in distilled water at $(37{\pm}1)^{\circ}C$. All mechanical strength tests were conducted with a cross-head speed of 1 mm/min. Data were statistically analyzed by one-way ANOVA and Tukey HSD post-hoc test. The mechanical properties of conventional glass ionomer cement was significantly enhanced by addition of 0.5 wt% CL to cement liquid (CS, DTS), or by addition of 10 wt% CH (FS) to cement powder. The CL particles incorporated into the set cement were firmly bonded to the GIC matrix (SEM). Within the limitation of this study, the results indicated that chitosan powders can be successfully added to enhance the mechanical properties of conventional GIC.

• Korean Journal of Dental Materials
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• v.43 no.1
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• pp.43-50
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• 2016

The aim of this study was to investigate the effect of multiwall carbon nanotube functionalized with carboxyl group (MWCNT-COOH) on the mechanical properties of dental glassionomer cement (GIC). MWCNT-COOH was prepared by the acid oxidative method. The MWCNT-COOH was incorporated into a commercial GIC powder or liquid at 0.5 wt% or 1.0 wt%. The net setting time of the cements was measured in accordance with ISO 9917 (Dental water-based cement). Specimens for compressive strength ($4mm{\varphi}{\times}6mm$), diametral tensile strength ($6mm{\varphi}{\times}4mm$) and flexure strength with modulus ($2mm{\times}2mm{\times}25mm$) were prepared by mixing with the cement liquid and kept in water bath of $(37{\pm}1)^{\circ}C$. Mechanical tests were conducted in 1 d, 7 d, and 14 days at a cross-head speed of 1 mm/min. Compressive strength of GIC mixed with 0.5 wt% MWCNT-COOH increased significantly at 7 d. However, overall mechanical properties of GIC modified with MWCNT were not significantly increased with a delayed setting time, in comparison with control cement. Overall results indicated that the MWCNT/GIC composite cements showed a limited strengthening effect for dental glassionomer cement.

• The korean journal of orthodontics
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• v.36 no.5
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• pp.360-368
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• 2006

Objective: Surface characteristics of dental materials play an important role in bacterial adhesion. The purpose of this study was to investigate surface characteristics of 5 different light-cured orthodontic adhesives (1 fluoride-releasing composite, 3 non-fluoride-releasing composites, and f resin-modified glass ionomer). Methods: Surface roughness was measured using a confocal laser scanning microscope. Contact angle and surface free energy components were analyzed using the sessile drop method. Results: Surface roughness was significantly different between adhesives despite a relatively small variation (less than $0.05\;{\mu}m$). Lightbond and Monolok2 were rougher than Enlight and Transbond XT. There were also significant differences in contact angles and surface free energy components between adhesives. In particular, considerable differences in contact angles and surface free energy components were found between resin modified glass ionomer and the composites. Resin modified glass ionomer showed significantly smaller contact angles in 3 different probe liquids and had higher total surface free energy and stronger polarity, with notably stronger basic property than the composites. Conclusion: Resin modified glass ionomer may provide a more favourable environment for bacterial adhesion than composite adhesives.

• Restorative Dentistry and Endodontics
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• v.35 no.6
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• pp.479-485
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• 2010

Objectives: The aim of this study was to compare the push-out bond strengths of resin cement/fiber post systems to post space dentin using different application methods of resin cement. Materials and Methods: Thirty extracted human premolars were selected and randomly divided into 3 groups according to the technique used to place the cement into root canal: using lentulo-spiral instrument (group Lentulo), applying the cement onto the post surface (group Direct), and injecting the material using a specific elongation tip (group Elongation tip). After shaping and filling of the root canal, post space was drilled using Rely-X post drill. Rely-X fiber post was seated using Rely-X Unicem and resin cement was light polymerized. The root specimens were embedded in an acrylic resin and the specimens were sectioned perpendicularly to the long axis using a low-speed saw. Three slices per each root containing cross-sections of coronal, middle and apical part of the bonded fiber posts were obtained by sectioning. The push-out bond strength was measured using Universal Testing Machine. Specimens after bond failure were examined using operating microscope to evaluate the failure modes. Results: Push-out bond strengths were statistically influenced by the root regions. Group using the elongation tip showed significantly higher bond strength than other ways. Most failures occurred at the cement/dentin interface or in a mixed mode. Conclusions: The use of an elongation tip seems to reduce the number of imperfections within the selfadhesive cement interface compared to the techniques such as direct applying with the post and lentulospiral technique.

• The korean journal of orthodontics
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• v.30 no.1 s.78
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• pp.83-89
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• 2000

The purposes of this study were to evaluate clinical applicability of resin modified glass ionomer cements and to determine the effect of salivary contamination on the tensile bond strength. Fourty extracted human permanent premolars were prepared lot bonding and standard edgewise brackets were bonded with Ortho-One, Fuji Ortho LC, Vitremer and Advance. Fourty extracted human permanent premolars were contaminated with saliva, dried and bonded with same materials above. The tensile bond strength was tested by Instron testing device aster storage in normal saline at ,$37^{\circ}C$ for 24 hours from bonding. The results were as follows : 1. The tensile bond strength of Ortho-One group was $7.68\pm1.76$, Advance group was $7.87\pm2.80$, Fuji Ortho LC group was $4.99\pm2.53$, Vitremer group was $2.80\pm0.88$ MPa. The tensile bond strength in contaminated condition of Ortho-One group was $4.12\pm1.67$, Advance group was $5.37\pm0.68$, Fuji Ortho LC group was $4.41\pm1.61$, Vitremer group was $2.60\pm1.10$ Mpa. 2. Salivary contamination did not affect the tensile bond strength when compared with the uncontaminated enamel group in Fuji Ortho LC and Vitremer (p>0.05) and there was great significant difference in the tensile bond strength of Ortho-One and Advance. 3. Advance, Ortho-One and Fuji Ortho LC seemed to have clinically a proper bond strength.