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Influence of Tri-Sodium Citrate on ZnS buffer layer prepared by Chemical bath deposition

  • Song, Chan-Mun;Lee, Sang-Hyeop;Eom, Tae-U;Im, Dong-Geon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.405-405
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    • 2016
  • CIGS 박막 태양전지에서 완충층으로 사용되는 ZnS는 단파장 영역에서 높은 투과도와 CIGS 계면과의 좋은 접착을 가지고 친환경적이며 3.74eV의 에너지 밴드갭을 가지고 있기 때문에 CdS를 사용했을 때 보다 더 넓은 에너지 영역의 광자를 p-n 접합 경계 영역으로 통과 시킬 수 있고 Cd-free 물질이라는 점에서 기존의 CdS 완충층의 대체 물질로 각광 받고 있다. 본 연구에서는 CIGS 박막에 화학습식공정 방법을 이용하여 최적화된 ZnS 박막의 증착 조건을 찾기 위해 실험 변수인 시약의 농도, 실험온도, 열처리 조건 등의 다양한 변화를 통해 실험을 진행하였고, 박막의 갈라짐과 pin-hole 현상을 개선하고 균일한 막을 제조하기 위해 구연산 나트륨 농도에 따른 ZnS 박막의 특성을 연구하였다. 본 실험 결과로서 실험변수인 황산아연의 농도 0.15M, 암모니아는 0.3M, 티오요소 1M, 공정 온도 $80^{\circ}C$의 최적화 된 조건에서 가장 좋은 품질의 ZnS 박막을 제조하였지만, ZnS 박막의 열처리 후 산소의 양이 줄어감에 따라 박막의 표면이 갈라지고 pin-hole 현상이 발생하는 것을 확인할 수 있었다. 박막의 품질을 개선하기 위해 구연산 나트륨을 첨가하여 실험한 결과 구연산 나트륨의 0.05M의 농도에서는 박막 표면에 90nm의 갈라짐의 크기와 pin-hole 현상이 남아있는 것을 확인하였고, 농도가 높아질수록 점차 크기가 줄어들면서 0.4M에서는 갈라짐이 거의 없는 표면과 pin-hole 현상도 없어지는 것을 확인하였고, 약 144nm의 박막 두께와 3.8eV의 에너지 밴드갭을 가지고, 약 81%의 높은 광투과율을 갖는 고품질의 ZnS 박막을 제작할 수 있었다.

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Replacement of Saline Water through Injecting Fresh Water into a Confined Saline Aquifer at the Nakdong River Delta Area (염수로 충진된 낙동강 델타지역 피압대수층에서 담수주입에 의한 염수치환 연구)

  • Won, Kyung-Sik;Chung, Sang Yong;Lee, Chang-Sup;Jeong, Jae-Hoon
    • The Journal of Engineering Geology
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    • v.25 no.2
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    • pp.215-225
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    • 2015
  • We performed injection tests in a deep-seated confined aquifer to assess the potential of artificial recharge as a means of preventing saltwater contamination, thereby securing groundwater resources for the Nakdong Delta area of Busan City, Korea. The study area comprises a confined aquifer, in which a 10-21-m-thick clay layer overlies 31.5-36.5 m of sand and a 2.8-11-m-thick layer of gravel. EC logging of five monitoring wells yielded a value of 7-44 mS/cm, with the transition between saline and fresh water occurring at a depth of 15-38 m. Above 5 m depth, water temperature is 10-15.5℃, whereas between 5 and 50 m depth the temperature is 15.5-17℃. Approximately 950 m3 of fresh water was injected into the OW-5 injection well at a rate of 370 m3/day for 62 hours, after which the fresh water zone was detected by a CTD Diver installed at a depth of 40 m. The persistence of the fresh water zone was determined via EC and temperature logging at 24 hours after injection, and again 21 days after injection. We observed a second fresh water zone in the OW-2 well, where the first injection test was performed more than 20 days before the second injection test. The contact between fresh and saline water in the injection well is represented by a sharp boundary rather than a transitional boundary. We conclude that the injected fresh water occupied a specific space and served to maintain the original water quality throughout the observation period. Moreover, we suggest that artificial recharge via long-term injection could help secure a new alternative water resource in this saline coastal aquifer.

Seismic interval velocity analysis on prestack depth domain for detecting the bottom simulating reflector of gas-hydrate (가스 하이드레이트 부존층의 하부 경계면을 규명하기 위한 심도영역 탄성파 구간속도 분석)

  • Ko Seung-Won;Chung Bu-Heung
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.638-642
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    • 2005
  • For gas hydrate exploration, long offset multichannel seismic data acquired using by the 4km streamer length in Ulleung basin of the East Sea. The dataset was processed to define the BSRs (Bottom Simulating Reflectors) and to estimate the amount of gas hydrates. Confirmation of the presence of Bottom Simulating reflectors (BSR) and investigation of its physical properties from seismic section are important for gas hydrate detection. Specially, faster interval velocity overlying slower interval velocity indicates the likely presences of gas hydrate above BSR and free gas underneath BSR. In consequence, estimation of correct interval velocities and analysis of their spatial variations are critical processes for gas hydrate detection using seismic reflection data. Using Dix's equation, Root Mean Square (RMS) velocities can be converted into interval velocities. However, it is not a proper way to investigate interval velocities above and below BSR considering the fact that RMS velocities have poor resolution and correctness and the assumption that interval velocities increase along the depth. Therefore, we incorporated Migration Velocity Analysis (MVA) software produced by Landmark CO. to estimate correct interval velocities in detail. MVA is a process to yield velocities of sediments between layers using Common Mid Point (CMP) gathered seismic data. The CMP gathered data for MVA should be produced after basic processing steps to enhance the signal to noise ratio of the first reflections. Prestack depth migrated section is produced using interval velocities and interval velocities are key parameters governing qualities of prestack depth migration section. Correctness of interval velocities can be examined by the presence of Residual Move Out (RMO) on CMP gathered data. If there is no RMO, peaks of primary reflection events are flat in horizontal direction for all offsets of Common Reflection Point (CRP) gathers and it proves that prestack depth migration is done with correct velocity field. Used method in this study, Tomographic inversion needs two initial input data. One is the dataset obtained from the results of preprocessing by removing multiples and noise and stacked partially. The other is the depth domain velocity model build by smoothing and editing the interval velocity converted from RMS velocity. After the three times iteration of tomography inversion, Optimum interval velocity field can be fixed. The conclusion of this study as follow, the final Interval velocity around the BSR decreased to 1400 m/s from 2500 m/s abruptly. BSR is showed about 200m depth under the seabottom

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A Study Identifying Improved Building Height Regulations for Managing Natural Landscape in Collective Facility Districts in and around National Parks (국립공원 집단시설지구 자연경관관리를 위한 층고규제 합리화 방안)

  • Lee, Gwan-Gyu
    • Journal of the Korean Institute of Landscape Architecture
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    • v.39 no.5
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    • pp.48-56
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    • 2011
  • The objective of this study is to develop quantitative criteria for setting reasonable standards and regulations for building heights in collective facility districts inside national parks or those connected to their borders. Heights of all building sin collective facility districts were simulated in order to determine heights of ridge lines of sight passing the upper parts of buildings from a main view point. Where a facility's zone is located at the inside or boundary of inland mountainous national parks, and there are coastal type national parks with mountains in the background, the study recommended assigning the maximum allowable height of a building as 8.82m if national park authorities intend to preserve the ridges at three-tenths the height of a mountain. It amounts to 3 or 3.5 stories when it is converted into the number of floors. It is desirable to apply this standard to accommodations like a hotel except lodge or cottage as the maximum allowable height of a building. Nevertheless, when there aren't back mountainous areas among coastal-type national parks, there is a need for applying a separate standard. If an equal and uniform standard is applied to all collective facility districts, it becomes difficult to address local differences when managing landscape. There must be flexibility when applying a standard, depending on variables such as location of view points, differences in the methods of selection of view points, and differences in view angles, etc. Thus, there is a need for different landscape management strategies that address the unique natural environment of different zones.

Weighted-averaging Finite-element Method for Scalar Wave Equation in the Frequency Domain (가중평균 유한요소법을 이용한 주파수영역에서의 인공 음향파 합성)

  • Hyun Hye-Ja;Suh Jung-Hee;Min Dong-Joo
    • Geophysics and Geophysical Exploration
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    • v.5 no.3
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    • pp.169-177
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    • 2002
  • We develop the weighted-averaging finite-element method which uses four kinds of element sets. By constructing global stiffness and mass matrices for four kinds of element sets and then averaging them with weighting coefficients, we obtain a new global stiffness and mass matrix. With the optimal weighting coefficients minimizing grid dispersion and grid anisotropy, we can reduce the number of grid points required per wavelength to 4 for a $1\%$ upper limit of error. We confirm the accuracy of our weighted-averaging finite-element method through accuracy analyses for a homogeneous and a horizontal-layer model. By synthetic data example, we reconfirm that our method is more efficient for simulating a geological model than previous finite-element methods.

Analysis of the Electromagnetic Scattering by Conducting Strip Gratings with 2 Dielectric Layers On a Grounded Plane (접지평면위에 2개의 유전체층을 가지는 저항띠 격자구조에서의 전자파산란 해석)

  • 윤의중
    • The Journal of Information Technology
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    • v.4 no.3
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    • pp.77-86
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    • 2001
  • In this paper, Electromagnetic scattering problem by a resistive strip grating with 2 dielectric layers on a ground plane according as resistivity of resistive strip, relative permittivity and thickness of dielectric layers, and incident angles of a electric wave is analyzed by applying the PMM (Point Matching Method) known as a numerical procedure. The scattered electromagnetic fields are expanded in a series of floquet mode functions. The boundary conditions are applied to obtain the unknown field coefficients and the resistive boundary condition is used for the relationship between the tangential electric field and the electric current density on the strip. According as the relative permittivity and the thickness of layers are increased, the values of the geometrically normalized reflected power have a high value and the values of strip width are moved toward a high value going from left to right. When the resistivity of this paper has a value of zero, the numerical results of the geometrically normalized reflected power show in good agreement with those by the PMM of existing paper. Then, the most energys of the sharp variation point in minimum values of the geometrically normalized reflected power are scattered in direction of the other angles except incident angle.

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Geomorphic Processes of Masung Basin (마성분지(麻城盆地)의 지형생성작용(地形生成作用))

  • Son, Myoung-Won
    • Journal of the Korean association of regional geographers
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    • v.2 no.1
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    • pp.39-49
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    • 1996
  • There is a limestone basin surrounded by the mountains consisted of Paleozoic sedimentary and metamorphic rocks in the Masung, Munkyung city, Kyungsangpook do. The purpose of this paper is to elucidate the geomorphic processes of the gentle hillslopes in the marginal piedmont of Masung basin. To do so, I analyzed deposits over hillslopes and the relation ship between the distance from the divide and the height(above sea level) at the longitudinal profile of the hillslope, and considered interrelation between the distributions of the gentle hillslopes(less than 230m) and lithology. Geomorphic processes of Masung basin are as follow: (1) The depth of deposits over hillslope increases toward downstream of the hillslope. Most gravels within deposits, whose lithology is limestone, are those eroded at the boundary(overthrust fault zone) between the back-mountain and the hillslope. Deposits at the outward margin of hillslope is well sorted. and moderately imbricated. (2) Hillslope at the margin of the basin(160-230m asl) is formed by the action of 'the flow with channel'. At the boundary between the soft rock(limestone; basin floor) and hard rock(sedimentary and metamorphic rock; back-mountain), the relatively weak limestone is eroded to fresh bedrock by the subsequent action of the overland flow, and therefore discontinuity in slope appeared. (3) After hills lopes were formed, sediments(boulders and fine material) produced during dissection in back-mountain buried deposits over hillslope. In conclusion, geomorphic processes of Masung basin is 'differential erosion due to differentiation of lithological hardness' having suggested as geomorphic processes of granitic basin. However it is not 'removal of weathering material due to sheetflow' but 'erosion due to the overland flow with channel'.

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Study on the Dispersion Stability of Precipitated Calcium Carbonate Suspensions (침강성 탄산칼슘 현탁액의 분산 안정성에 관한 연구)

  • Park, Myung-Jae;Ahn, Ji-Whan;Kim, Hwan
    • Journal of the Korean Ceramic Society
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    • v.38 no.4
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    • pp.343-350
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    • 2001
  • 본 연구에서는 탄산화법으로 침강성 CaCO$_3$분말을 제조하고 제조된 CaCO$_3$현탁액의 분산안정성을 연구하였다. CaCO$_3$현탁액의 pH 변화와 고분자전해질 PMAA와 PAA의 첨가에 따른 입자크기, 유동학적 특성(점도), zeta potential 및 현탁액의 침강속도 등을 측정하였다. 탄산화법에 의해 약 0.1$\mu\textrm{m}$ 크기와 비표면적이 23.57$m^2$/g인 단분단 calcite형 CaCO$_3$분말을 제조하였다. pH가 11인 CaCO$_3$현탁액에 0.01 wt% PMAA가 첨가된 경우에 우수한 분산안정성을 나타내었는데 이는 CaCO$_3$입자표면에 PMAA의 흡착에 의한 electrosteric 안정화기구와 CaCO$_3$입자들 사이의 정전기적 반발력에 의한 것으로 판단된다. PMAA와 PAA 첨가량 변화에 따른 pH 6, 9, 11의 CaCO$_3$현탁액의 침전높이를 측정한 결과 PMAA와 PAA의 농도가 0.15 wt% 부근에서 분산안정성을 보였는데 이는 CaCO$_3$입자들 사이간의 분산제에 의한 뚜렷한 경계를 갖는 흡착층이 형성되었기 때문으로 생각되며 따라서 CaCO$_3$현탁액의 최적 분산안정성을 위해서는 적절한 pH 조절과 PMAA 및 PAA의 첨가가 필요함을 알 수 있다.

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Research about the cooling of a small size rocket nozzle (소형로켓 노즐의 냉각에 관한 연구)

  • Go, Tae-Sig;Shim, Jin-Ho
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2007.04a
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    • pp.365-369
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    • 2007
  • The solid rocket interacts circumscriptively in terms of is many more than liquid rocket. It is uncontrollable than liquid rocket because all part of combustion is decided such as Mixture ratio of propellant, burning time and area. However, production cost is cheap and because authoritativeness security can be easy and enlarge the early speed that follow thrust-to-weight ratio, it is used comprehensively by small size rocket. Considered about nozzle cooling to control phenomenon that burn by thermal conduction in interior wall of nozzle that follow in thrust increase of solid rocket and erosion phenomenon by combustion gas of high speed.

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Numerical Study on Three - Dimensional Viscous Flows in Turbine Blade Passages (터빈 블레이드 통로에서의 3차원 점성유동에 대한 수치해석)

  • 윤준원;유정열
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.3
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    • pp.527-539
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    • 1992
  • 본 연구에서는 터빈익렬의 입구유동면에 주어지는 끝벽 경계층유동에 의하여 익렬 내의 유동에서 발생하는 여러 와류들에 의한 2차 유동과 이와 연관된 여러가지 3차원 점성유동 현상 그리고 이에 따른 유동손실을 보다 정확히 예측하기 위한 수치해 석적 연구를 수행하였으며, 이에 필요한 수치해석적 연구를 수행하였으며, 이에 필요 한 수치해석코드를 작성하였다.유동특성에 대하여 상세한 연구결과가 보고되어 있 는 UTRC(United Technologies Research Center) 평면 터빈익렬을 연구대상으로 채택하 여 익렬 내의 3차원 유동특성을 연구하고 계산한 결과를 기존의 결과와 비교 검토하였 다. 강한 2차유동이 존재하는 경우에 발생하는 수치확산을 감소시키기 위하여 대류 항에 대하여 2차 정확도(second-order accuracy)의 선형상류도식(linear upwind sche- me)을 사용하여 일반적으로 널리 사용되는 하이브리드도식(hybrid scheme)에 의한 해 석결과와 비교하였다. 터빈익렬 내의 난류 유동은 익렬의 회전과 유선의 만곡 등에 의한 영향으로 복잡한 유동현상을 나타내지만, 터빈익렬 내의 난류유동 특성에 대한 실험결과가 아직까지는 부족하고 또한 본 연구에서는 평균유동값의 정확한 해석에 중 점을 두었으므로 표준 k-.epsilon. 모델을 사용하였다.