• Title/Summary/Keyword: 충.방전특성

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The Impeditive Properties and Charge/Discharge of Positive Active Material $LiMnO_2$ (정극 활물질 LiMnO2 충.방전과 임피던스 특성)

  • Wi, Seong-Dong;Kim, Jong-Ok;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05c
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    • pp.299-305
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    • 2003
  • The battery industries have been developed to the implementation of lithium ion secondary cell from the cell of Ni/Cd and Ni/MH in the past to be asked of an age of high technology from low technology. Also in resent the polymeric cell to get a good high function with an age of new advanced information system is changed from the 21 century to the secondary batteries society. The properties of lithium secondary batteries have the high energy density, the long cycle time, the low self discharge area and the high active voltage. The wanted properties of secondary batteries for the motion of an apparatuses of industries of an high skill age have a small type trend of the energy density and it is become with a strong asking of the industrial society market about the storable medium of the convenience and new power energy. The electrochemical properties is researched for the cell to be synthesised and crystallized the positive active material LiMnO2 of the secondary cell at 9250C to get a new improved data of the electric discharge for that the capacitance of the LiMnO2 thin film that is improving and researching with the properties and a merit and demerit in the this kind of asking.

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Charge-discharge Characteristics of $TiO_2$-Activated Carbon Composite Electrode using Electrospinning (전기방사법으로부터 제조된 $TiO_2$ 섬유 복합전극의 충방전 특성)

  • An, Mi-Sun;Kim, Han-Joo;Son, Won-Keun;Takahashi, Hideaki;Park, Soo-Gil
    • Proceedings of the KIEE Conference
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    • 2005.07c
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    • pp.2022-2024
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    • 2005
  • Electrical double-layer capacitor (EDLC) is an electrochemical energy storage device in which electric charges only accumulated by a pure electrostatic attraction force are stored on the electrolyte-electrode interface in a form of double layer and separated by the electrolyte. The composite was prepared by mixing nanosize $TiO_2$ and activated carbon through a means of ultrasonic vibration in ethanol solution for 30 min in various mass ratios of $AC:TiO_2$ to form activated carbone-semiconducting oxide composites. Either 1.0 M $LiClO_4/EC-DEC$ or $Et_4NBF_4$/EC-DEC was used as the electrolyte. It was found that with modification of $TiO_2$, the specific capacitance of activated carbon measured at $1mA/cm^2$ was increased from 40 to 50 F/g. This method is unique in comparison the conventional method because it uses semiconducting TiO2 other than electrochemically active materials such as $RuO_2$. The increase in specific capacitance could be attributed to the decrease in electric polarization, caused by the introduction of $RuO_2$.

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The AC impedance of $LiM_{y}Mn_{2-y}O_{4}$cathode material by charge and discharge temperature (충방전 온도에 따른 $LiM_{y}Mn_{2-y}O_{4}$정극 활물질의 임피던스 특성 분석)

  • 정인성;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.351-354
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    • 2000
  • AC impedance of LiM $n_2$ $O_4$ and LiM $g_{0.1}$M $n_{1.9}$ $O_4$ samples have been studied at various temperature with charge-discharge test. AC impedance of LiM $n_2$ $O_4$ measured at -2$0^{\circ}C$, room temperature and 5$0^{\circ}C$ revealed that initial impedance before charge-discharge test was gradually decreased and become small by becoming law temperature. It indicates that the Li ion diffusion and the transfer resistance of the cathode are related to the temperature of cycling. Impedance at high temperature was suddenly increased because Mn dissolution and decomposition of electrolyte had been increased during cycling, compared to impedance at low temperature. Therefore, charge-discharge capacity was suddenly decreased at high but was slowly at low. In LiM $g_{0.1}$M $n_{1.9}$ $O_4$, impedance and capacity were stability at room temperature than there at 5$0^{\circ}C$, too. Initial impedance at 5$0^{\circ}C$ before charge-discharge test was small and impedance was suddenly increased during cycling than that at room temperature.ure.ure.

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Properties of charge/discharge in synthesis method or substituting transition element for Li-Mn Oxide (전이금속 치환 및 합성방법에 따른 Li-Mn 산화물의 충방전 특성)

  • Jee, Mi-Jung;Choi, Byung-Hyun;Lee, Dae-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.46-46
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    • 2007
  • There has been rapid progress in the portable electronics industry. which has led to a great increase for a demand of portable, lightweight power sources. Lithium 2'nd batteries have met these demand. and many studies on the cahtod materials for the lithium 2,nd batteries have been reported during the last decade. Possible candidates for the cathode materials for lithium 2,nd batteries are $LiCoO_2$, $LiNiO_2$, and $LiMn_2O_4$. Currently $LiCoO_2$ is widely used. but $LiMn_2O_4$ is an excellent alternative material in view of its several advantages such a low cost as well as the wasy availability of raw materials and environmental benignity. In this study, find the most suitable synthesis method that satisfied high capacitor and stability cycle character, etc in Li-Mn oxide for 2'nd batteries. And also made an experiment on doping the $LiMn_2O_4$ spinel with a small amount of metal ions has a remarkable effect on the electrochemical properties and characterics of powder, BET, PSA, Porosity, etc.

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The Design of DC-DC Converter for multi-output of PV system (태양광발전 시스템의 다중출력제어를 위한 DC-DC 컨버터 설계)

  • Lee, Woo-Hee;Lee, Mi-Young;Lee, Jun-Ha;Lee, Hoong-Joo
    • Proceedings of the KIEE Conference
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    • 2005.07b
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    • pp.1377-1379
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    • 2005
  • 독립형 태양광 발전시스템은 태양전지, 배터리, 충 방전 제어기, 컨버터, 부하로 나눌 수 있다. 태양광 발전은 비선형 전압전류 특성을 가지고 있기 때문에 발전효율을 최대한 높이기 위해 최대전력추종제어(MPPT)를 하게된다. 또한 부하가 여러 개일 경우에는 다양한 출력이 요구되는데, 이를 위해 강압 및 승압이 가능한 컨버터가 필요하게 된다. 그러나 다중부하에는 다수의 컨버터와 각각의 컨버터를 제어하기 위한 제어기가 필요하게 되므로 cost가 증가요인이 된다. 따라서 본 논문에서는 승 강압에 의한 다중출력을 갖는 병렬구조의 DC-DC컨버터를 제안하고자 한다. 제안된 컨버터는 입력전압을 승 강압하여 두 개의 출력전압을 갖는다. 강압동작은 일반적인 buck형 컨버터에 커패시터를 추가하여 구성하였고, 승압을 위해서는 리플율이 적은 Coupling inductor를 이용하고 커패시터를 추가하여 두 개의 컨버터를 병렬로 구성하였다. 컨버터의 병렬제어를 위해 제어기를 설계하고 이를 시뮬레이션 하였다.

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Charge/Discharge Characteristics of $SnO_2$ thin film as an anode of thin film secondary battery for microelectromechanical system device (Microelectromechnical system 소자를 위한 박막형 2차전지용 $SnO_2$ 음극박막의 충방전 특성 평가)

  • 남상철;조원일;전은정;신영화;윤영수
    • Journal of the Korean Vacuum Society
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    • v.9 no.1
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    • pp.36-41
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    • 2000
  • $SnO-2$ thin films for thin film secondary battery anode were deposited n glass substrate with stain-less steel collector and charge/discharge experiments were conducted to investigate feasibility of $SnO-2$ thin film as a new anode material. The as-deposited films were pure $SnO-2$ phase which is not related to deposition condition. The grain size on the surface of as-deposited films increased with increase of oxygen partial pressure. However, the grain size did not show any change above oxygen partial pressure of 80:20. The surface roughness of the as-deposited films increased after decreasing because of resputtering effect of oxygen negative ion in plasma. All films showed typical $SnO-2$ anode characteristics which has a side effect at the first cycle, which is not related to the deposition condition. The charge/discharge experiments of 200cycles indicated that capacity of $SnO-2$ films depended on oxygen contents and surface roughness. The cycle characteristics was determined by initial charge/discharge reaction. The $SnO-2$ film with low initial capacity showed more stable cycle characteristics than film with high initial capacity.

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The Small Photovoltaic power supply using Hybrid Supercapacitor (하이브리드 커패시터를 적용한 소형 태양광 전원장치)

  • Kim, Tae-Yeop
    • Journal of IKEEE
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    • v.23 no.3
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    • pp.826-831
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    • 2019
  • The stand-alone photovoltaic power systems are widely used for lighting equipment and CCTV. In order for these devices to be competitive, the life of power storage devices such as batteries is very important. The characteristic Hybrid supercapacitor is the high power density and long life. We have proposed a stand-alone photovoltaic power system that uses hybrid supercapacitor. The charge and discharge characteristics and the internal resistance of the hybrid capacitor were measured to configure the power converter. A stable maximum output point tracking control algorithm is proposed even with the change in solar radiation. In order to verify the validity of the proposed system, a prototype was fabricated and tested using a 18W hybrid capacitor and a 10W solar cell.

A Study on Heating Characteristics of Li-ion Battery Applicated Single-phase Immersion Cooling Technology (단상계 침지냉각 기술이 적용된 Li-ion계 배터리 발열특성에 관한 연구)

  • Kim, Woonhak;Kang, Seokwon;Shin, Giseok
    • Journal of the Society of Disaster Information
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    • v.18 no.1
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    • pp.163-172
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    • 2022
  • Purpose: To secure efficient thermal management technology for Li-ion batteries, the applicability of the system applied with single-phase immersion technology was checked through an experiment. Method: Using JH3 pouch cells produced by LG-Chem, Korea, A 14S2P module was manufactured and immersed in a vegetable-based cooling fluid produced by Cargill, USA, and then charged and discharged at a rate of 0.3C to 1C to check the heat distribution. Result: It was possible to manage and there was no change in the molecular structure of the immersion solution. Conclusion: It was confirmed that the immersion cooling method can be applied to the thermal management of Li-ion batteries.

Analysis of Charge and Discharge Characteristics of Heavy Duty Electric Commercial Vehicle Batteries (중대형 전기 상용차 배터리의 주행중 충방전 특성 분석)

  • Song, Jingeun;Cha, Junepyo
    • Journal of Institute of Convergence Technology
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    • v.11 no.1
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    • pp.19-23
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    • 2021
  • These days, sales of battery electric vehicles have been rapidly increasing due to the strict CO2 regulations. However, since it take too long to measure the energy economy of electric vehicles, it has been required to improve the procedure of energy economy measurement. In order to improve this problem, the present study analyzed the battery charge/discharge pattern according to the changes in battery SOC (state of charge). In general, the energy economy test is started with a battery SOC charged to 100 %. However, it was identified that when the battery is fully charged, it can actually be charged over the 100 % (e.g., 100.5 %). This can induce errors in the energy economy measurement. Therefore, the present study recommend to start the test at SOC 99.9 %. The regenerative braking was partly restricted for the SOC over 90 %. This made it difficult to estimate the overall energy economy of the electric vehicle. However, it was identified that there was no change in the battery charge/discharge characteristics under the SOC 90 %. Therefore, the energy economy test can be shortened by predicting the overall energy economy through a short mileage test.

The Study on Structural Change and Improvement of Electrochemical Properties by Co-precipitation Condition of Li[Ni0.8Co0.15Al0.05]O2 Electrode (Li[Ni0.8Co0.15Al0.05]O2 전극의 공침 조건을 통한 구조적 변화와 전기적 특성의 향상 고찰)

  • Im, Jung-Bin;Son, Jong-Tae
    • Journal of the Korean Electrochemical Society
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    • v.14 no.2
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    • pp.98-103
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    • 2011
  • [ $Li[Ni_{0.8}Co_{0.15}Al_{0.05}]O_2$ ]cathode material for lithium secondary battery is obtained using co-precipitation method. To determine the optimal metal solution concentration value, the CSTR coprecipitation was carried out at various concentration values(1-2 mol/L). The surface morphology of coated samples was characterization by SEM(scanning electron microscope) and XRD (X-Ray Diffraction)analyses. Impedance analysis and cyclic voltammogram presented that internal resistance of the cell was dependent upon the concentration of metal solution. such data is very helpful in determining the optimal content of metal solution concentration to enhancing electrochemical property by adjusting powder size distribution and crystal structure.