• Journal of the Korean Crystal Growth and Crystal Technology
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• v.32 no.2
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• pp.61-67
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• 2022

A metal salt solution was prepared from valuable metals (Ni, Co, Mn) recovered from a scrap of waste lithium secondary batteries, and an NCM811 precursor was synthesized from the solution. The effect on precursor formation according to reaction time was confirmed by SEM, PSA, and ICP analysis. Based on the analysis results, the electrochemical properties of the synthesized NCM811 precursor and the commercial NCM811 precursor were investigated. The Galvano charge-discharge cycle, rate performance, and Cycle performance were compared, and as a result, there was no significant difference from commercial precursors.

• Proceedings of the Korea Water Resources Association Conference
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• 2023.05a
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• pp.78-78
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• 2023

기후변화 위기는 유사 이래 인류가 직면한 가장 큰 도전으로 범정부적 글로벌 문제로서 이를 해결하기 위한 다양한 정책들이 범국가 차원 혹은 세계적 기업들에 의해 발표 혹은 시행되고 있다. 이러한 기후변화위기와 탄소배출 저감을 위한 대표적인 대응 방안 중 하나가 바로 재생에너지의 확대·보급 노력이다. 그러나 재생에너지는 날씨와 계절 등 자연환경의 영향을 받는 에너지원으로써 간헐성, 변동성을 가지므로, 시간대별 발전량 예측과 전력공급 안정성에 어려움이 있다. 이러한 문제를 해결하기 위하여 재생에너지 발전은 석탄화력 발전과 달리 전력의 수요와 공급의 균형을 위한 에너지저장장치(Energy Storage System, 이하 ESS)가 있어야 한다. ESS는 전력공급 안정성 향상과 전력 수급의 유연성을 제공하는 장점이 있지만, 초기 설치비용이 높은 단점이 있다. 특히, 배터리 기반 ESS의 경우 높은 구축 비용과 한정적인 충. 방전수명으로 인하여 대용량 ESS로써의 역할 수행에는 분명한 한계가 있다. 하지만 재생에너지와 연계한 ESS로 양수발전댐을 활용할 경우 장주기, 장수명, 대용량 에너지 저장에 매우 합리적인 수단으로 판단되었다. 다만, 양수발전 댐 구축에는 토목공사로 인한 환경 훼손이라는 문제점도 존재한다. 본 고에서는 지역 분산형 소규모 양수발전(Pumped Storage Hydropower, 이하 PSH)댐 구축 및 운영기술 개발을 통해 지역 전력공급과 전력 수급을 조절하면서 변동성 재생에너지를 안정적으로 사용할 수 있는 방안을 소개하고자 한다. 특히, 해당 기술은 지역별 특성에 맞춰 유연하게 설치할 수 있으며, 대규모 토목공사로 의한 환경적 부작용을 최소화할 수 있다. 또한 소규모 PSH는 지역의 저수지 및 수자원을 이용하여 에너지를 저장함으로써 변동성 큰 재생에너지의 유연화 대응과 동시에 안정적인 에너지 공급이 가능하다. 본 고에서는 재생에너지의 확대·보급에 따른 문제점과 대표적 ESS 기술들을 분석·소개한다. 지역분산형 소규모 PSH 기술개발 연구기획 내용 소개를 통하여 전력 생산 및 공급의 탈중앙화를 달성하고, 지역별 변동성 재생에너지의 안정적 활용과 지역 전력공급 특성 및 전력 수급에 대응할 수 있는 방안을 제안하고자 한다.

• Korean Chemical Engineering Research
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• v.61 no.3
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• pp.348-355
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• 2023

Magnesium secondary batteries are attracting much attention due to their potential to replace conventionally used lithium ion batteries. Magnesium secondary battery cathode material Mo₆S₈ were synthesized by molten salt synthesis method and PVC as a carbon materials were added to improve electrochemical properties. Crystal structure, size and surface of the synthesized anode materials were measured through XRD and SEM. Charge-discharge profiles and rate capabilities were measured by battery test system. 2.81 wt% PVC coated sample showed the best rate capabilities of 85.8 mAh/g at 0.125 C-rate, 69.2 mAh/g at 0.5 C-rate, and 60.5 mAh/g at 1 C-rate.

• Journal of IKEEE
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• v.27 no.4
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• pp.477-485
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• 2023

In this paper, the effect of AC ripple on the lifetime of lithium-ion batteries is experimentally analyzed. Bidirectional power conversion system(PCS) is used to increase the efficiency of energy storage systems (ESS). When connected to the grid, a current ripple with a frequency twice the grid frequency is applied to the battery due to its structure. Therefore, to analyze the effect of AC ripple on Li-ion battery aging, cycle life test are performed by applying charge/discharge profiles of DC current and DC+AC current ripple specifications. Based on the experimental results, direct current internal resistance (DCIR), incremental capacitance (IC), and surface temperature were analyzed. As a result, it is confirmed that AC ripple does not directly affect degradation and that battery degradation slows down after a certain cycle. These results can serve as a guideline for optimizing filters to reduce ripple on the battery side in applications where AC ripple occurs.

• Composites Research
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• v.36 no.6
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• pp.422-428
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• 2023

The electrical contact resistance between the bipolar plate (BP) and the carbon felt electrode (CFE), which are in contact by the stack clamping pressure, has a great impact on the stack efficiency because of the relatively low clamping pressure of the vanadium redox flow battery (VRFB) stack. In this study, a polyethylene (PE) composite-CFE hybrid bipolar plate structure is developed through a local heat welding process to reduce such contact resistance and improve cell performance. The PE matrix of the carbon fiber composite BP is locally melted to create a direct contact structure between the carbon fibers of CFE and the carbon fibers of BP, thereby reducing the electrical contact resistance. Area specific resistance (ASR) and gas permeability are measured to evaluate the performance of the PE composite-CFE hybrid bipolar plate. In addition, an acid aging test is performed to measure stack reliability. Finally, a VFRB unit cell charge/discharge test is performed to compare and analyze the performance of the developed PE composite-CFE hybrid BP and the conventional BP.

• The Journal of the Korea institute of electronic communication sciences
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• v.18 no.6
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• pp.1151-1156
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• 2023

In this paper, we propose a deep learning model that utilizes charge/discharge data from initial lithium-ion batteries to predict the remaining useful life of lithium-ion batteries. We build the DMP using the PNP model. To demonstrate the performance of DMP, we organize DML using the LSTM model and compare the remaining useful life prediction performance of lithium-ion batteries between DMP and DML. We utilize the RMSE and RMSPE error measurement methods to evaluate the performance of DMP and DML models using test data. The results reveal that the RMSE difference between DMP and DML is 144.62 [Cycle], and the RMSPE difference is 3.37 [%]. These results indicate that the DMP model has a lower error rate than DML. Based on the results of our analysis, we have showcased the superior performance of DMP over DML. This demonstrates that in the field of lithium-ion batteries, the PNP model outperforms the LSTM model.

• Journal of the Korean Electrochemical Society
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• v.27 no.2
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• pp.55-72
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• 2024

Secondary batteries are used as an essential renewable energy source in our lives, such as electric vehicles and energy storage systems (ESS), as an alternative to fossil fuels due to global warming. However, cases of battery fires and explosions have been reported due to thermal runaway in secondary batteries due to various causes such as overdischarge, high-speed charging and discharging, and external short circuit, and great efforts are being made to find solutions suitable for each cause. In particular, as cases presumed to be caused by the overcharging process have been reported, this review will examine the chemical reactions of secondary batteries that can occur during the overcharging process and discuss risk investigation methods to check and prevent them.

• Journal of the Korean Electrochemical Society
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• v.17 no.2
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• pp.94-102
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• 2014

Cation exchange membrane (Nafion) was modified to reduce the vanadium ion permeation through the membrane and to increase the vanadium redox flow battery (VRB) system performance by coating the graphene oxide (GO) which has nano-plate like morphology. Modified membrane properties were studied by measuring the ion exchange capacity (I.E.C), water uptake and proton conductivity. The thickness of the coated layer on the surface of the Nafion membrane was observed as $0.93{\mu}m$ by SEM. Proton conductivity and vanadium ion permeability of the modified membrane were decreased to 27% and 25% compared to that of the commercial Nafion membrane respectively. VRB single cell performance test was performed to compare the system performance of the VRB applied with commercial Nafion membrane and modified membrane. VRB system applied with modified membrane showed higher coulombic efficiency and energy efficiency than the VRB system applied with the commercial Nafion membrane due to the reduction of the vanadium ion permeation. From these result, we could suggest that the membrane modification by coating the GO on the surface of the Nafion membrane could be one of the promising strategies to reduce the vanadium ion permeation and to increase the VRB system performance effectively.

• Journal of the Korean Electrochemical Society
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• v.17 no.1
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• pp.49-56
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• 2014

As an electrolyte additive, the effects of lithium bis(oxalate)borate (LiBOB) on the electrochemical properties of a carbon-coated silicon monoxide (C-coated SiO) negative electrode are investigated. The used electrolyte is 1.3M $LiPF_6$ that is dissolved in ethylene carbonate (EC), fluoroethylene carbonate (FEC), and diethyl carbonate (DEC) (5:25:70 v/v/v) with or without 0.5 wt. % LiBOB. In the LiBOB-free electrolyte, the film resistance is not so high in the initial period of cycling that lithiation is facilitated to generate the crystalline $Li_{15}Si_4$ phase. Due to repeated volume change that is caused by such a deep charge/discharge, cracks form in the active material to cause a resistance increase, which eventually leads to capacity fading. When LiBOB is added into the electrolyte, however, more resistive surface film is generated by decomposition of LiBOB in the initial period. The crystalline $Li_{15}Si_4$ phase does not form, such that the volume change and crack formation are greatly mitigated. Consequently, the C-coated SiO electrode exhibits a better cycle performance in the later cycles. At an elevated temperature ($45^{\circ}C$), wherein the effect of film resistance is less critical, the alloy ($Li_{15}Si_4$ phase) formation is comparable for the LiBOB-free and added cell to give a similar cycle performance.

• Korean Chemical Engineering Research
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• v.55 no.5
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• pp.593-599
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• 2017

In order to enhance ultra battery performances, the electrochemical characteristics of nano Pb/AC anode composite was investigated. Through nano Pb adsorption onto activated carbon, nano Pb/AC was synthesized and it was washed under vacuum process. The prepared anode materials was analysed by SEM, BET and EDS. The specific surface area and average pore size of nano Pb/AC composite were $1740m^2/g$ and 1.95 nm, respectively. The negative electrode of ultra battery was prepared by nano Pb/AC dip coating on lead plate. The electrochemical performances of ultra battery were studied using $PbO_2$ (the positive electrode) and prepared nano Pb/AC composite (the negative electrode) pair. Also the electrochemical behaviors of ultra battery were investigated by charge/discharge, cyclic voltammetry, impedance and rate capability tests in 5 M $H_2SO_4$ electrolyte. The initial capacity and cycling performance of the present nano Pb/AC ultra battery were improved with respect to the lead battery and the AC-coated lead battery. These experimental results indicate that the proper addition of nano Pb/AC into the negative electrode can improve the discharge capacity and the long term cycle stability and remarkably suppress the hydrogen evolution reaction on the negative electrode.