• Journal of Adhesion and Interface
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• 제17권4호
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• pp.136-140
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• 2016

In this study, a series of dimer acid-based polyamides with different diamines were synthesized by condensation polymerization and the polyamides were characterized by Fourier transform infrared spectroscopy (FT-IR). Effects of diamine structures on mechanical and thermal properties of polyamides were investigated. The tensile strength and lap shear adhesion strength of aromatic-based polyamide (DAP) were higher than those of aliphatic-based polyamide (DAH). In DSC thermogram, DAP has a high $T_g$ and $T_m$ compared with DAH. DAP's and DAH's softening point were $112-115^{\circ}C$ and $98-121^{\circ}C$, respectively.

• Magazine of the Korea Concrete Institute
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• 제6권6호
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• pp.143-150
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• 1994

Most widened bridges have been constructed by the joining-construction method that makes new and existmg bridges structurally a single structure. Since the joining-constructiori method has several problems in design and construction viewpoint, this study is conducted in order to investigate the flexural fatigue behavior of RC slabs, which are widened and influenced by traffic-induced vibration of existmg bridge during placing and curing of new concrete, with the prototype fatigue test. It was found that stress concentration at the jclmts anti slips between steel bar and concrete are occured. Hut, the general tx:havinrs are similar to the original state and joining-construction method using expansive concrete nut~gated the influence of the trafflc-induced vibration.

• Journal of the Korean Chemical Society
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• 제46권1호
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• pp.52-56
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• 2002

Synthesis of unsymmetrical trisannelated benzenes such as 2,3,4,5,6,7,8,9,10,11-decahydro-1H-cyclopenta[l]phenanthrene (1c) and 1,2,3,4,5,6,7,8,9,10-decahydrobenz[e]-as-indacene (1d) is described. The synthetic approach involves efficient condensation of pre-formed enones such as bicyclohexyliden-2-one (3), bicyclohexyl-1-en-2-one (4) and bicyclopentyliden-2-one (5) in the presence of cyclopentanone and cyclohexanone using anhydrous $CuCl_2$ as a catalyst.

• Journal of Life Science
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• 제14권3호
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• pp.406-410
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• 2004

Glyoxal or methylglyoxal was incubated with catalase in 0.24 M sodium phosphate buffer (pH 7.4) at 37$^{\circ}C$. Dicarbonyls modify and inactivate catalase. Plasmid DNA that is directly incubated with glycation propagators, glyoxal and methylglyoxal, showed different DNA mobility shift compared to nomal plasmid DNA. When plasmid DNA is added in Fenton reaction with glycated catalase, plasmid DNA was significantly strand broken and 8-hydroxydeoxyguanosine production was time dependently increased. These results suggest that glycation of antioxidant is synergistic effect to oxidative stress.

• Journal of the Korean Chemical Society
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• 제45권4호
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• pp.312-317
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• 2001

7'-Aldehyde-nucleosides analogue (2a, 2c) were synthesized from 6-N-benzoyl-2',3'-O-isopropylideneadenosine and uridine. The condensation of 2 with ethoxycarbonylmethylene Wittig reagent produced the adenosine and uridine analogues containing extended conjugated diene and ethoxycarbonyl group, ethyl-1',5',6',7',8'-pentadeoxy-1'-(adenin-9-yl)-$\beta$-D-ribo-nona-5'(E),7'(E)-dienofuranuronate (4b) and ethyl-1'. 5',6',7',8'-pentadeoxy-1'-(uracil-1-yl)-$\beta$-D-ribo-nona-5'(E),7'-(E)-dienofuranuronate (4c). 9-[8',8'-dibromo-5',6',7',8' -tetradeoxy-$\beta$-D-ribo-octa-5'(E),7'(E)-diene]nucleosides (6b, 6c) were also prepared from 2 with similar method.

• Journal of the Korean Society of Food Science and Nutrition
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• 제22권4호
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• pp.418-422
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• 1993

For the purpose of utilizing tannins in the functional foods and crude drugs the xanthine oxidase inhibition of tannins isolated from Korean green tea was determined. Acetone extract from Korean green tea showed inhibitory effect against the xanthine oxidase. The galloyl tannins showed higher inhibitory activity against xanthine oxidase than the nongalloyl tannins. In terms of stereo isomers, (-)-epicatechins had higher inhibitory activity than the (+)-catechins. The synergistic activity was also observed. Tannins isolated from Korean green tea appeared to be incompetitive inhibitor against the xanthine oxidase.

• Applied Biological Chemistry
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• 제37권6호
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• pp.498-502
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• 1994

For glucosyltransferase(GTase) inhibitors, two flavan-3-ols were isolated from Theobroma cacao beam husk. They showed positive reaction with $anisaldehyde-H_2SO_4$ solution, $FeCl_3$ to be confirmed as dimeric flavan-3-ols on TLC and were identified as procyanidin B-1 [(-)-epicatechin-$(4{\beta}{\rightarrow}8)$-catechin] and procyanidin B-3 [(+)-catechin-$(4{\beta}{\rightarrow}8)$-catechin by spectroscopic analysis. Their inhibitory effect on glucosyltranaferase activity was also investigated and procyanidin B-1 showed 50% inhibition at 0.3 mM. They inhibited on the glucosyltransferasa noncompetitively and dimeric flavan-3-ol containing (-)-epicatechin had higer inhibitory activity.

• Korean Journal of Crystallography
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• 제16권1호
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• pp.6-10
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• 2005

A novel potential linking ligand (4-nitro-benzylidene)-(3-nitro-phenyl)-amine (1) was prepared from 4-nitrobenzaldehyde and 3-nitroaniline by the Schiff-base condensation. From the reaction between 1 and dichlorobis(benzonitrile)palladium (II) $(PdCl_2(NCPh)_2)$, an unexpected product $trans-PdCl_2(NO_2-C_6H_4-NH_2)_2$ (2) was isolated. Compounds 1 and 2 were structurally characterized by X-ray diffraction. In compound 2, the $NH_2$ hydrogen atoms in the 3-nitroaniline ligand participate in intermolecular N-H${\cdot}\;{\cdot}\;{\cdot}\;$Cl hydrogen bonds.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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• pp.120-124
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• 2004

본 연구는 Diluted Ceria 입자를 사용한 $SiO_2$(Oxide) CMP 현상에 대한 내용이다. Ceria Slurry의 경우 Silica Slurry와 비교하였을 때 Oxide Wafer 표면과 축합 화학반응을 일으키며 Chemistry Dominant한 CMP Mechanism을 따르고, Wafer Center Removal Rate(RR) Fast 의 특성을 가진다. Ceria Slurry의 문제점인 연마 불균일도를 해결하기 위해 Tribological System을 이용하였다. CMP Tribology는 Pad-Slurry 유막-Wafer의 System을 가지며 윤활막에 작용하는 마찰계수(COF)가 주요 인자이다. Tribology에 적용되는 Stribeck Curve를 통해 Slurry 윤활막의 두께(h) 정도를 예상할 수 있으며, 이 윤활막의 두께를 조절함으로써 Uniformity 향상이 가능하다. 이 Ceria Slurry CMP의 연마 불균일도를 향상시킬 수 있는 방법으로 pH 조절 및 점도 증가가 있다. Ceria 입자 CMP는 분산액의 pH 변화에 강한 작용을 받게 되며 PH5 근방에서 최적화된 Uniformity가 가능하다. 점도를 증가시키는 경우 유막 h가 증가하게 되어 Ceria Slurry의 유동이 균일 분포 상태에 가까워지며 Wafer Uniformity 향상이 가능하다.

• Journal of the Korean Chemical Society
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• 제31권5호
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• pp.457-463
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• 1987

The total synthesis of insulin A chain (1-21) with properly protected sulfhdryl groups of three cysteins for the correct intra and inter disulfide bond formation has been accomplished on 2-bromopropionylated 2% DVB-styreneresin support employing manually operated rotary vessel. The sulfhydryl groups of cysteins were protected with acetamidomethyl, benzyl, and benzhydryl respectively. Glutamine and asparagine were attached to the peptide chain by active ester coupling, all other amino acids were coupled with DCC/HOBT. The synthesized peptide was purified by DEAE Sephadex A-25 and gel filtration Sephadex LH-20. The final product was found to be homogeneous by HPLC, electrophoresis, and amino acid analysis. The overall yield of the pure isolated peptide was 6%.