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Structures of (4-Nitro-benzylidene)-(3-nitro-phenyl)-amine and trans-Dichlorobis (3-nitroaniline) palladium(II)  

Lee Hee K. (Department of Chemistry(BK21), Sungkyunkwan University)
Lee Soon W. (Department of Chemistry(BK21), Sungkyunkwan University)
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Korean Journal of Crystallography / v.16, no.1, 2005 , pp. 6-10 More about this Journal
Abstract
A novel potential linking ligand (4-nitro-benzylidene)-(3-nitro-phenyl)-amine (1) was prepared from 4-nitrobenzaldehyde and 3-nitroaniline by the Schiff-base condensation. From the reaction between 1 and dichlorobis(benzonitrile)palladium (II) $(PdCl_2(NCPh)_2)$, an unexpected product $trans-PdCl_2(NO_2-C_6H_4-NH_2)_2$ (2) was isolated. Compounds 1 and 2 were structurally characterized by X-ray diffraction. In compound 2, the $NH_2$ hydrogen atoms in the 3-nitroaniline ligand participate in intermolecular N-H${\cdot}\;{\cdot}\;{\cdot}\;$Cl hydrogen bonds.
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