• Title/Summary/Keyword: 최적환경조건

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Preparation and Properties of Moisture-absorbing Film Impregnated with Polyacrylic Acid Partial Sodium Salt Material (폴리아크릴산 나트륨 염이 함침된 흡수성 고분자 복합 필름의 제조 및 특성 연구)

  • Lee, Youn Suk;Choi, Hong Yeol;Park, Insik
    • Korean Chemical Engineering Research
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    • v.52 no.4
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    • pp.530-537
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    • 2014
  • Moisture is a major factor causing the deteriorative physical change, microbial growth, and chemical reaction of the products. In this study, the moisture absorbing composite films have been prepared with moisture absorbing material of polyacrylic acid partial sodium salt (PAPSS) impregnated on LLDPE polymer for the functional packaging applications. The results showed that PAPSS impregnated film illustrated uniformly dispersed PAPSS particles in the LLDPE polymer matrix. The transparency of the PAPSS impregnated film decreased slightly at higher PAPSS concentrations. An increase in the PAPSS content for moisture-absorbing films showed a similar decrease in tensile strength, percent elongation at break, and tear strength. Their values of films impregnated with PAPSS of 0.5, 1, and 2% showed no significant difference. Meanwhile, 4% PAPSS films significantly decreased the values of mechanical properties compared to the films impregnated with different PAPSS levels. Values of the oxygen permeability and water vapor permeability for PAPSS impregnated films decreased significantly with greater PAPSS. The results indicate that 4% PAPSS impregnated in LLDPE films had high affinity of moisture absorbencies compared to the other films. The mathematical equation that best described the moisture sorption isotherm of each film sample was the GAB equation at $25^{\circ}C$. The crystallization and melting temperatures of PAPSS films were influenced by the addition of PAPSS material, but showed good thermal stability.

The Study on Urea-Lignin Copolymer Adhesive from Kraft Black Liquor for Plywood Manufacturing (Kraft Pulp 폐액(廢液)을 이용(利用)한 합판용(合板用) 요소(尿素) Ligning 접착제(接着劑) 연구(硏究))

  • Ryu, Jae-Yun;Lee, Hwa-Hyong
    • Journal of the Korean Wood Science and Technology
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    • v.16 no.2
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    • pp.50-61
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    • 1988
  • 접착제(接着劑) 제조(製造)를 위하여 펄프폐액(廢液)중의 리그닌을 이용(利用)하는 연구(硏究)가 1930년경(年傾)부터 진행(進行)되여 아황산펄프폐액(廢液)중의 Lignosulfonate의 경우는 페놀수지(樹脂)나 요소수지(要素樹脂)에 증량(增量)시키거난 반응(反應)시키는 연구(硏究)인데 비하여 kraft 리그닌을 이용(利用)하는 경우는 페놀수지(樹脂)의 보문(報文)이 주류(主流)를 이루고 있으나 요소계(要素系) 공축합수지(共縮合樹脂)는 아직 발표(發表)된 바 없으며 또한 아직까지 리그닌을 이용(利用)한 상업적(商業的)인 접착제(接着劑)가 제조(製造)되어 활용(活用)되지 못하고 있는 실정(實情)이다. 따라서 본(本) 연구(硏究)는 합판제조(合板製造)의 원가절감(原價節減), 폐액이용(廢液利用)의 환경보존관점(環境保存觀點)에서 Krfat Pulp 폐액(廢液)중의 리그닌접착제(接着劑)의 제조(製造)하고져 실시(實施)하였으며, Urea-Lignin 접착제(接着劑)의 도포량(塗布量)은 일반적(一般的)으로 합판(合板)에 도포(塗布)되는 요소수지(要素樹脂)의 량(量)(320g/$m^2$)과 동일(同一)하고 압축응력(壓縮應力)은 균일(均一)하게 12kg/$cm^2$으로 하여 열압조건(熱壓條件)(온도(溫度), 시간(時間))의 영향(影響))을 아울러 규명(糾明)하였다. Urea-Formaldehyde와 Kraft lignin의 혼합비(混合比)는 중량비(重量比)(N.V.C)로 7:3으로 합성수지(合成樹脂)를 만들어 합판제조(合板製造)를 통(通)하여 구명(究明)를 결과(結果) 다음과 같은 결론(結論)을 얻었다. 1. 본(本) 실험(實驗)의 결과(結果) 요소수지(要素樹脂)의 약(約) 30%가 krfat lignin으로 대체(代替)할 수 있음을 보여준 바, Pulping 공정(工程)의 부산물(副産物)로 얻어진 폐액(廢液)은 합판제조시(合板製造時) 접착제(接着劑)의 대체원(代替源)으로 유효(有效)하다. 2. 경제적관점(經濟的觀點)에서 합판제조(合板製造)를 위한 최적열압조건(最適熱壓條件)은 $160^{\circ}C$에서 3분(分)으로 압착(壓搾)하는 것이 적절(適切)하였다.(상태(常態)): 16.49kg/$cm^2$, 내수(耐水) : 18.56kg/$cm^2$, 내온수(內溫水) : 12.53kg/$cm^2$). 3. 요소-리그닌 접착제(接着劑)로 제조(製造)된 합판(合板)의 전단인장강도(剪斷引長强度)는 양호(良好)한 접착력(接着力)을 나타냈으며, 내수접착력(耐水接着力)($30^{\circ}C$에서 3시간(時間) 심적후(沈積後) 시험(試驗)은 상태접착력(狀態接着力)과 별차이가 없거나 더 높은 인장강도력(引長强度力)을 보여준 바, 내수합판용(耐水合板用) 접착제(接着劑)로 상당한 전망(展望)을 나타냈다.

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Engineering Performance and Applicability of Environmental Friendly Porous Concrete for a Marine Ranch Using Steel Industry By-products (철강산업 부산물을 활용한 해양목장 조성용 친환경 다공질 콘크리트의 공학적 성능 및 적용성)

  • Lee, Byung-Jae;Jang, Young-Il;Kim, Yun-Yong
    • Journal of the Korea Concrete Institute
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    • v.25 no.1
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    • pp.115-123
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    • 2013
  • The steel industry, a representative industry that significantly consumes raw materials and energy, produces steel as well as a large amount of by-product steel slag through the production process. The vast habitat foundation of marine life has been destroyed due to recent reckless marine development and environment pollution, resulting in intensification of the decline of marine resources, and a solution to this issue is imperative. In order to propose a method to recycle large amounts of by-product slag into a material that can serve as an alternative to natural aggregate, the engineering properties and applicability for each mixing factor of environment friendly porous concrete as a material for the composition of marine ranches were evaluated in this study. The test results for percentage of voids per mixing ratio revealed that the margin of error for all conditions was within 2.5%. The compressive strength test results showed that the most outstanding environmental friendly porous concrete can be manufactured when mixing 30% slag aggregate and 10% specially treated granular fertilizer for the optimum volume fraction. As concrete for marine applications, the best seawater resistance was obtained with mixing conditions for high compression strength. An assessment of the ability to provide a marine life habitat foundation of environmentally friendly porous concrete showed that a greater percentage of voids facilitated implantation and inhabitation of marine life, and the mixing of specially treated granular fertilizer led to active initial implantation and activation of inhabitation. The evaluation of harmfulness to marine life depending on the mixture of slag aggregate and specially treated granular fertilizer revealed that the stability of fish is secured.

Cultivation technique using plastic container and selection the superior strain of nameko mushroom (Pholiota nameko) (맛버섯(Pholiota nameko) 우량균주 선발 및 병 재배법)

  • Jung, Kyung-Ju;Choi, Duck-Soo;Choi, Hyeong-Gug;Kim, Joung-Keon;Chung, Ki-Chul
    • Journal of Mushroom
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    • v.5 no.2
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    • pp.51-58
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    • 2007
  • These experiment was conducted to find the superior strain selection, cultivation technique and optimum environmental condition of nameko mushroom culture using plastic container. The results was following as Mycelium of Pholiota nameko grown well at MCM and Hamada media, and its media acidity was pH 6~7. The optimum temperature condition for growing mycelium was $25^{\circ}C$. Under $15^{\circ}C$ and above $30^{\circ}C$ of temperature condition, mycelium growing speed was delayed remarkably. Among the 29 strains of nameko mushroom, the most productive strains was JNM19007, JNM19026, JNM19027 and JNM19028. The optimum media composition rate for produce fruitbody was pine sawdust 80% + wheat bran 20%. In this condition, the average fruitbody amount was 188g per 1,100cc container. The optimum post-culturing period was 50 days and mushroom sprout appeared 7 days after old mycelia removed. The suitable temperature was $12^{\circ}C$ for induce sprout, growing period was $16^{\circ}C$ and the optimum relative humidity was 95% in all culturing periods.

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Study of Supercritical Carbon Dioxide/n-Butyl Acetate Co-solvent System with High Selectivity in Photoresist Removal Process (포토레지스트 공정에서 높은 선택성을 가지는 초임계 이산화탄소/n-butyl acetate 공용매 시스템 연구)

  • Kim, Dong Woo;Heo, Hoon;Lim, Kwon Teak
    • Clean Technology
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    • v.23 no.4
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    • pp.357-363
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    • 2017
  • In this study, the supercritical carbon dioxide ($scCO_2$)/ n-butyl acetate (n-BA) co-solvent system was employed to remove an unexposed negative photoresist (PR) from the surface of a silicon wafer. In addition, the selectivity of the $scCO_2$/n-BA co-solvent system was confirmed for the unexposed and exposed negative PR. Optimum conditions for removal of the unexposed PR were obtained from various conditions such as pressure, temperature and n-BA ratio. The n-BA was highly soluble in $scCO_2$ without cloud point and phase separation in mostly experimental conditions. However, the $scCO_2$/n-BA co-solvent was phase separated at 100 bar, above $80^{\circ}C$. The unexposed and exposed PR was swelled in $scCO_2$ solvent at all experimental conditions. The complete removal of unexposed PR was achieved from the reaction condition of 160 bar, 10 min, $40^{\circ}C$ and 75 wt% n-BA in $scCO_2$, as measured by ellipsometry. The exposed photoresist showed high stability in the $scCO_2$/n-BA co-solvent system, which indicated that the $scCO_2$/n-BA co-solvent system has high selectivity for the PR removal in photo lithograph process. The $scCO_2$/n-BA co-solvent system not only prevent swelling of exposed PR, but also provide efficient and powful performance to removal unexposed PR.

Fractionation of KOCC by Froth-Flotation(IV)- (부상부유처리에 의한 국산 골판지 고지의 분급(IV))

  • 여성국;윤혜정;류정용;김용환;신종호;송봉근;서영범
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2000.11a
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    • pp.40-40
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    • 2000
  • 우리나라의 제지산업은 천연펄프 자급능력이 20% 내외로서 낮은 실정이며 주원료의 7 70% 이상을 수입펄프와 고지에 의존하는 원료수급의 불균형이 심화된 상태이다 .. 1999년도 제지통계에 의하면 골판지 원지로 사용되는 라이너지와 골심지의 연간 생산량이 각각 169만 톤과 88만톤을 점유하여 국내 전체 지류생산량 887만톤의 약 29%를 점하고 있다. 이처럼 국내 제지산업에서 큰 비중을 차지하는 골판지 원지는 주로 국내에서 발생되는 고지를 원료 로 하여 생산되고 있어 환경친화적인 지류라 할 수 있다. 그러나, 국산 골판지 고지( Korean O Old Corrugated Container)의 경우 골판지 고지 이외에 각종 인쇄고지와 기타 산업용지가 혼합된 최하급지로서, 고지 재생 시 여러 가지 많은 제한요소를 지니고 있다. 국산 골판지 고지는 거듭된 재생처리로 인하여 미세분의 함량이 전체 지료의 절반에 달할 만큼 많으며, 아울러 섬유가 각질화됨에 따라 재생처리가 거듭될수록 그러한 미세분의 형성이 더욱 조장 되고 있다. 일반적으로 크기 75µm 이하의 무기질 및 단섬유를 일걷는 미세분은 골판지 원지 의 초지시 습지필의 탈수를 저해하여 생산성을 저하시키는 요인이 되어 왔다. 이러한 문제 를 해결하기 위해 선진국에서는 골판지 고지를 스크린 또는 클리너 둥으로 정선 처리하여 장단섬유를 분급한 다음, 장섬유분을 선택적으로 고해하여 종이의 강도를 향상시키는 기술 이 개발되어 적용돼 왔으나, 이러한 기술은 우리 나라와 같이 장섬유 보다 미세분 함량이 많은 저급의 골판지 고지를 주원료로 삼는 골판지 원지의 강도 개선에 큰 효과를 거둘 수 없는 기술이라고 판단된다. 이는 기존의 섬유 분급 처리는 고급 고지의 경우에는 효과적이 나 저급의 혼합고지를 100% 재활용하여 구성되는 국산 골판지의 생산 시에 적용하기에는 5 50-60%에 이르는 미세분이 포함되어 분리의 대상이 섬유장이 다른 펼프 섬유라기 보다는 미세섬유를 펄프섬유로부터 분리하는 것이 필요하기 때문이다. 이러한 문제점을 극복하기 위해서는 기포의 수력학적 포집작용을 이용하여 고농도의 미세분을 선택적으로 분급시키는 부상부 유 분급처리방법을 적용하였다. 이 방법은 미세분의 농축을 위한 부가적인 처리가 필요치 않으며, 분급에 천공을 이용하지 않기 때문에 분급처리 시 천공의 plugging 문제가 발생되 지 않는다는 장점도 가지고 있다. 미세분 분급을 위한 최적의 부상부유 조건은 장섬유의 응 집을 촉진하면서 미세분은 그러한 응집체에 포함되지 않은 상태로 자유로이 부상하여 걷혀 지는 경우이다. 응집거동을 조절하기 위한 시도로서 부상부유 처리시 유량을 달리한 실험결 과에 의하면 유량이 낮을수록 장섬유 손실이 줄고 미세분이 선택적으로 포집되나 전체 부상 부유 리젝트의 양이 줄어드는 문제점이 있었다. 이에 본 실험에서는 장섬유의 응집에 영향 하는 또 다른 인자로서 지료의 농도를 증가시키면서, 미세분의 부상부유를 촉진시키도록 유 량을 증가시키는 조건으로 부상부유 처리에 의한 미세분 분급효율을 증가시키고자 하였다.

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Sulfate Modulation for Hydrogen Production by Chlamydomonas reinhardtii in Continuous Culture (Chlamydomonas reinhardtii 연속 배양에서 수소생산을 위안 황 조절)

  • Kim, Jun-Pyo;Park, Tai-Hyun;Kim, Mi-Sun;Sim, Sang-Jun
    • KSBB Journal
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    • v.20 no.6
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    • pp.453-457
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    • 2005
  • We investigated the effect of sulfate re-addition on hydrogen production under sulfur-deprived condition. When the final concentration of sulfate to cell suspensions($0{\sim}120{\mu}M$) was increased, chlorophyll concentration, culture density, and total amount of $H_2$ produced, increased up to an optimal concentration of $30{\mu}M\;MgSO_4$. Maximum hydrogen volume was 236 mL $H_2/L$ culture at $30{\mu}M\;MgSO_4$. However, the addition of excess sulfate(above $MgSO_4\;60{\mu}M$) delayed the start of hydrogen production and the induction of hydrogenase. Accordingly, the final yield of hydrogen production was reduced. Using these results, we attempted the continuous and sustained hydrogen production by sulfate re-addition($30{\mu}M\;MgSO_4$) using a single C. reinhardtii culture for up to 4 cycles. In total, hydrogen production volume was 625 mL $H_2/L$ culture.

The Development of a GIS-based Sewer-network Analysis System (GIS를 이용한 하수관망해석시스템 개발)

  • Lee, Jung-Hun;Kim, Kye-Hyun
    • Journal of Korean Society for Geospatial Information Science
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    • v.6 no.2 s.12
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    • pp.69-79
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    • 1998
  • It is one of the most crutial thing to secure efficient infrastructure of social infrastructure Including rna drinking water, sewer, gas, and electricity, etc. in modern society. Among them, the sourer system need to be properly maintained so as to sustain water quality over the large watershed thereby to provide reasonable level of living environment A few municipalities and private firms have so in been using sewer management system for assessing existing sewer network and auxiliary facilities. Such existing system can only provide functions to manage the sewer pipe itself and they can not fully estimate the amount of sewage water over the pipe through 4he network analysis due to the deficiency of the system Such a limited sewer network analysis function can only analyze the whole network under the assumption of uniformity. The results from such a process can not be fully implemented in the field. Therefore, this study emphasized the development of a sewer management system which can provide practical values from network analysts considering areal peculiarities using a zoning map utilizing a GIS. The system can support analyzing scenarios due to the changes of sewer amounts from the changes of population densities and rainfall amounts not to mention of calculating sewer amount for individual sewer pipes. furthermore, the system can support the decision making for better designing sewer facilities from the expansion of metropolitan areas and constructing satellite cities. Eventually, it will contribute to enhance the effectiveness of sewer-related works and services for residents as well as supporting a decision making for minor and major trouble-shootings.

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Effects of Local Climatic Conditions on the Early Growth in Progeny Test Stands of Korean White Pine (지역별 잣나무 차대검정림의 초기생장에 미치는 미기후의 영향)

  • 신만용;김영채
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.4 no.1
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    • pp.1-11
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    • 2002
  • This study was conducted to reveal the effects of local climatic conditions on the early growth of Korean white pine progeny test stands. For this, stand variables such as mean DBH, mean height, basal area per hectare, and volume per hectare by stand age and locality were first measured and summarized for each stand. Based on these statistics, annual increments for 10 years from stand age 10 to 20 were calculated for each of stand variables. The effects of local climatic conditions as one of environmental factors on the growth were then analyzed by both a topoclimatological method and a spatial statistical technique. From yearly climatic estimates,30 climatic indices which affect the tree growth were computed for each of the progeny test stand. The annual increments were then correlated with and regressed on the climatic indices to examine effects of local climatic conditions on the growth. Gapyung area provided the best conditions for the early growth of Korean white pine and Kwangju area ranked second. On the other hand, the growth pattern in Youngdong ranked last overall as expected. It is also found that the local growth patterns of Korean white pine in juvenile stage were affected by typical weather conditions. The conditions such as low temperature and high relative humidity provide favor environment for the early growth of Korean white pine. Especially, it was concluded that the low temperature is a main factor influencing the early growth of Korean white pine based on the results of correlation analysis and regression equations developed far the prediction of annual increments of stand variables.

Effects of Temperature, Food Concentration, and Shell Size on Filtering Rate and Pseudofeces Production of Unio douglasiae on Microcystis aeruginosa (수온, 먹이농도, 패각 크기가 Microcystis aeruginosa에 대한 말조개의 여과율 및 배설물 생산에 미치는 영향)

  • Lee, Yeon-Ju;Kim, Baik-Ho;Kim, Nan-Young;Um, Han-Yong;Hwang, Soon-Jin
    • Korean Journal of Ecology and Environment
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    • v.41 no.spc
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    • pp.61-67
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    • 2008
  • This study was conducted to evaluate filtering rate (FR) and pseudofeces production (PFP) of a freshwater filter-feeding bivalve, Unio douglasiae, on a toxic cyanobacterium (Microcystis aeruginosa). The experiments were conducted under the various conditions of water temperature $(5{\sim}35^{\circ}C)$, mussel size $(5.6{\sim}13.3cm)$ and food con centrations $(49{\sim}491{\mu}g\;Chl-{\alpha}L^{-1})$. Among the applied temperature, the maximum FR $(0.41L\;gAFDW^{-1}hr^{-1})$ and PFP (0.47mg $gAFDW^{-1}hr^{-1}$) were observed at 15 and $25^{\circ}C$, respectively. Both weight-based FR and PFP were not correlated with the mussel size, and the values lied in a limited range with some degree of variation. Likewise, no significant relations between FR and PFP was observed in the mussel size. The FR values were negatively correlated with food concentration, while PFP showed positive correlation. Among the applied food concentrations, the maximum FR (0.34L $gAFDW^{-1}hr^{-1}$) and PFP (0.06mg $gAFDW^{-1}hr^{-1}$) appeared in $113{\mu}g\;Chl-{\alpha}L^{-1}$ and $491{\mu}g\;Chl-{\alpha}L^{-1}$, respectively. These results indicate that the grazing of Unio douglasiae are affected by various parameters, and it may be applied as an effective biofilter to inhibit Microcystis bloom under appropriate application. However, further studies on the fate of excreted pseudofeces are needed to understand their possibility of stimulating nuisant algal growth.