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Metal Complexes of Ambidentate Ligand (VIII). Ni (II) and Pd (II) Complexes of Isonitrosomethylacetoacetate Imines (Ambidentate 리간드의 금속착물 (제 8 보). Isonitrosomethylacetoacetate Imine 리간드의 니켈(II) 및 팔라듐(II) 착물)

  • Bon-Chang Goo;Gang-Yeol Choi;Man-Ho Lee;In-Whan Kim
    • Journal of the Korean Chemical Society
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    • v.37 no.7
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    • pp.662-671
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    • 1993
  • New Ni(II) and Pd(II) complexes of isonitrosomethylacetoacetate imine derivatives, Ni(IMAA-NH)(IMAA-NH'), Ni(IMAA-NH)(IMAA-NR), $Pd(IMAA-NH)_2\;and Pd(IMAA-NR)_2(R=CH_3,\;C_2H_5,\;n-C_3H_7,\;n-C_4H_9,\;or\;CH_2C_6H_5)$, where H-IMAA-NH and H-IMAA-NR represent isonitrosomethylacetoacetate imine and N-alkylisonitrosomethylacetoacetate imine derivative, respectively, have been prepared and the structures of the complexes have been studied by elemental analyses, electronic, infrared, and $^1H-\;and\;^{13}C-NMR$ spectroscopies.

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Genome sequence of carotenoid producing Sphingobacteriaceae bacterium SH-48 isolated from freshwater in Korea (카로티노이드 생산 Sphingobacteriaceae SH-48 균주의 유전체 염기서열 분석)

  • Choi, Ahyoung;Chung, Eu Jin;Nam, Young Ho;Choi, Gang-Guk
    • Korean Journal of Microbiology
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    • v.53 no.4
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    • pp.347-350
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    • 2017
  • We sequenced the genome of the Sphingobacteriaceae bacterium SH-48 isolated from the Sohan stream in Republic of Korea by using a dilution-to-extinction culturing method. The sequences were assembled into a draft genome containing 5,650,162 bp with a G + C content of 35.4% and 4,856 protein-coding genes in 2 contigs. This strain contains the carotenoid biosynthesis genes crtY, crtZ, crtD, crtI, crtB, and crtH as gene clusters. This genomic information provides new insights into the carotenoid biosynthesis pathway.

The Diversity of Heterotrophic Bacteria Isolated from Intestine of Starfish(Asterias amurensis) by Analysis of 16S rDNA Sequence (16S rDNA염기서열에 의한 불가사리(Asterias amurensis) 장내에서 분리된 종속영양세균 군집의 다양성)

  • Choi, Gang-Guk;Lee, Oh-Hyung;Lee, Geon-Hyoung
    • The Korean Journal of Ecology
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    • v.26 no.6
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    • pp.307-312
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    • 2003
  • To study the diversity of heterotrophic bacteria isolated from intestine of starfish, Asterias amurensis, we collected starfishes from the coastal area near Jangheung-Gun, Jeollanam-Do, Korea during July, 2000. Population density and bacterial diversity in the intestine of starfish were measured. The results were as follows; The population densities of heterotrophic bacteria in the intestine of starfish were 8.65${\pm}$0.65${\times}10^3\;dfu\;g^{-1}$. Gram positive bacteria occupied 59% among 29 isolates. The community structure of dominant heterotrophic bacteria in the intestine of starfish consisted of Bacillaceae in the low G+C gram positive bacteria subphylum, Microbacteriaceae in the high G+C gram positive bacteria subphylum, and Alteromonadaceae in ${\gamma}$-Proteobacteria subphylum. Among eight strains of Bacillus spp., three strains showed more than 97% identity, but five strains showed about 90% identity with type strain on the basis of partial 16S rDNA sequence.

Genotype Analysis of the Major Histocompatibility Complex Region in Korean Native Chicken (한국 재래닭의 MHC 영역 유전자형 분석)

  • Jung, Kie-Chul;Hoque, Md. Rashedul;Seo, Dong-Won;Park, Byung-Kwon;Choi, Kang-Duk;Lee, Jun-Heon
    • Korean Journal of Poultry Science
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    • v.36 no.4
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    • pp.317-322
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    • 2009
  • The chicken major histocompatibility complex (MHC) is known to be associated with disease resistance and susceptibility to several pathogens. The microsatellite marker LEI0258 is physically located between the BG and BF of MHC region and variations near this marker have been well documented. In this report, the LEI0258 marker was used to find specific alleles for the Korean native chicken. The MHC haplotype was analyzed by PCR screening and sequencing of LEI0258 region in four different breeds including black Korean native chicken, brown Korean native chicken, Cornish and Rhode island red. The serologically same MHC haplotypes showed the differences in repeat numbers, a few indels or single nucleotide polymorphisms by sequencing analysis. Even though we could not identify specific alleles for Korean native chickens, the genotypes analyzed in these breeds can give valuable information for the relationships with disease resistance and establishment of breeding strategies for the Korean native chicken.

Optimization of Extraction Conditions of Polyphenolic Compounds from Amaranth Leaf using Statistically-based Optimization (통계학적 최적화를 이용한 아마란스 잎으로부터 폴리페놀 열수추출조건 최적화)

  • Jo, Jaemin;Choi, Kanghoon;Shin, Seulgi;Lee, Jihyun;Kim, JinWoo
    • Korean Chemical Engineering Research
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    • v.54 no.3
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    • pp.315-319
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    • 2016
  • This study examined the optimization of hot-water extraction conditions for maximizing the total polyphenol compounds (TPC) extracted from amaranth leaf. The effects of three independent variables, including extraction temperature, extraction time and ethanol concentration on TPC were investigated using central composite design (CCD). The concentration of TPC increased with increased levels of extraction temperature and time. The extraction temperature and the ethanol concentration showed the significant effect on TPC production (p<0.05). The predicted values at the optimized condition were acceptable when compared to the experimental values ($R^2=0.9566$). The optimum extraction conditions were as follows: temperature of $90.1^{\circ}C$, time of 50 min and ethanol concentration of 61.6% (v/v) for the maximum TPC of 12.6 mg GAE/g DM.

Categorical time series clustering: Case study of Korean pro-baseball data (범주형 시계열 자료의 군집화: 프로야구 자료의 사례 연구)

  • Pak, Ro Jin
    • Journal of the Korean Data and Information Science Society
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    • v.27 no.3
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    • pp.621-627
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    • 2016
  • A certain professional baseball team tends to be very weak against another particular team. For example, S team, the strongest team in Korea, is relatively weak to H team. In this paper, we carried out clustering the Korean baseball teams based on the records against the team S to investigate whether the pattern of the record of the team H is different from those of the other teams. The technique we have employed is 'time series clustering', or more specifically 'categorical time series clustering'. Three methods have been considered in this paper: (i) distance based method, (ii) genetic sequencing method and (iii) periodogram method. Each method has its own advantages and disadvantages to handle categorical time series, so that it is recommended to draw conclusion by considering the results from the above three methods altogether in a comprehensive manner.

Metal Complexes of Ambidentate Ligand (Ⅶ). Palladium (Ⅱ) Complexes of Isonitrosobenzoylacetone Diimine Derivatives (Ambidentate 리간드의 금속착물 (제 7 보). Isonitrosobenzoylacetone 디이민유도체를 리간드로 하는 팔라듐 (Ⅱ) 착물)

  • Choi, Gang-Yeol;Jun, Young-Sook;Baek, Jae-Bum;Lee, Man-Ho
    • Journal of the Korean Chemical Society
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    • v.35 no.6
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    • pp.667-672
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    • 1991
  • Two palladium(Ⅱ) complexes, N-(2-aminoethylisonitrosobenzoylacetone imino) chloropalladium(Ⅱ), PdCl(IBA)-en, and N-(3-aminopropylisonitrosobenzoylacetone imino) chloropalladium(Ⅱ), PdCl (IBA)-tn, have been prepared from the condensation of isonitrosobenzoylacetone (IBA) and diamine (ethylenediamine(en) or trimethylenediamine(tn)) in the presence of palladium(Ⅱ) ion. It is suggested that the Schiff base formed by condensation of an isonitrosobenzoylacetone and a diamine coordinates to the metal through three nitrogens of isonitroso (=N-O), C=N, and $NH_2$groups as a tridentate ligand. And also a chloride ion coordinates to the metal in addition to the Schiff base ligand to form a square-planar geometry.

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A Study of Engineering Properties of Rock Mass Weathered by Sea water (해수에 의한 암반 풍화의 공학적 특성 연구)

  • Choi Kang-Il;Kang Coo-Won;Go Chin-Surk
    • Explosives and Blasting
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    • v.23 no.1
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    • pp.9-17
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    • 2005
  • This study is to clarify the comparative relationship and mechanical anisotropy of granite distributed in the Nam-weon on the subject of weathered rock mass sea water surroundings. Artificial weathering test is defined as a test, which controls the weathering rate and agents by controlling the weathering rate and agents by artificial environmental of salt water. Increased weathering degree is large indicated by weathering salt water, such as apparent specific gravity, absorption, porosity, uniaxial compression strength, P-wave velocity, slake durability, shore hardness, indirect tensile strength(brazilian test) and cohesion were measured. As the Weathering salt water proceeds, cracks develope increasingly. A number the cracks affect the rock deformation. Therefore, stress-strain curve of weathered salt water rock in one confined state are quite differ from weathered fresh water rock those. A reason of their deformation type is the formation of micro-cracks and potential porosity caused by artificial weathering test.

노동력수요의 중장기 전망-지식기반경제로의 이행-

  • 최강식;김정호
    • Journal of Labour Economics
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    • v.20 no.1
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    • pp.59-89
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    • 1997
  • 세계화 추세의 가속, 급속한 기술진보 및 정보화의 확산 등은 국제간의 분업구조 뿐만 아니라 국내의 산업구조 및 취업구조를 급격히 변화시키고 있다. 국내 취업구조의 변화는 산업간 직업간 취업비중을 모두 변화시키고 있어 고용의 양적 측면은 물론이고 질적 측면에서도 큰 변화가 예상된다. 그러므로 중장기적인 노동력수요 예측은 향후 인력양성의 방향과 체계를 결정하는 데 중요한 지표가 될 뿐만 아니라 노동시장 정책에 있어서도 반드시 필요한 자료가 되고 있다. 따라서 본 연구에서는 향후 노동력에 대한 중장기 수요를 일반균형적인 접근을 통하여 산업별 직업별로 예측하고 이 예측결과에 따른 향후 노동시장 및 인력정책의 방향을 제시하는 데 있다. 본 연구에서는 기존의 연구들이 사용한 방법의 이론적 약점을 보완하면서 실증 결과의 예측성을 높일 수 있는 개선된 방법을 사용하였다. 산업별 취업자를 전망하는데 있어 기존 연구결과들은 주로 노동시장의 단일방정식만을 추정함으로써 생산요소의 수요가 비탄력적이지 않음에도 불구하고 생산요소간의 대체가능성을 무시하고 있으며, 인력수요에 중요한 결정 요인인 기술변화를 고려하지 못하고 있거나, 취업계수의 변화를 통해 기술진보의 효과를 고려한다고 하여도 기술진보가 생산요소간에 비중립적(factor non-neutral technology changes)으로 일어날 경우 요소간 대체가능성을 간과하고있다. 이러한 단점을 보완하기 위해 본 연구에서는 산업별 취업자 전망에서 노동시장의 단일방정식 추정이 아닌 일반균형에 입각한 경제 모형을 사용하였다. 또한 직종별 취업자 전망을 위해서는 일반적으로 이용되는 필요 인력량에 대한 고정계수(fixed coefficient manpower requirement)를 추정할 때 이중비례행렬모형(二重比例行列模型)을 이용하여, 산업구조의 변화로 인한 직업별 인력수요 변화가 충분히 고려되도록 하였다. 전망의 결과에 따르면 향후 우리 경제는 지식기반경제(knowledge-based economy)로 이행하고 있다고 볼 수 있다. 우선 산업구조면에서 지식집약적산업으로의 구조조정이 일어나게 되고 이에 따라 산업별 취업구조에서도 고기술산업의 취업준비중이 급속히 증가하게 된다. 직업별 취업분포에 있어서도 전문기술직 행정관리직 등의 고숙련 사무직의 비중은 크게 증가하는 반면 생산관련직과 농림어업직의 비중은 감소하게 된다. 이처럼 경제가 지식집약화되어 감에 따라 고학력자에 대한 수요는 지속적으로 증가하지만 현재 적절한 인력양성과 공급이 이루어지지 않고 있어 향후 기술이나 기능에 따른 수급부일정(需給不一政)(skill mismatch)현상이 매우 심해질 것으로 보인다. 따라서 앞으로의 인력정책에서 가장 주안점을 두어야 할 부분은 첨단기술산업과 관련된 인력의 양성에 있다고 하겠다.

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Analysis of passive time-reversal communication performance in shallow water with underwater sound channel (음향채널이 존재하는 천해에서의 수동 시역전 통신 성능 분석)

  • Choi, Kang-Hoon;Kim, Sunhyo;Choi, Jee Woong;Kim, Hyeonsu;Kim, Byoung-Nam
    • The Journal of the Acoustical Society of Korea
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    • v.37 no.1
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    • pp.21-30
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    • 2018
  • A passive time-reversal technique can improve error performance of the underwater communication system by reducing influence of inter-symbol interferences, which is caused by a multipath channel response. The passive time-reversal communication system equipped with numerous receivers generally can obtain superior error performance since larger diversity gain can be obtained as the number of available received signal increased. In this paper, we analyze the optimal number and combination of receivers that can approximately achieve the best error performance when using the limited number of receivers. For this analysis, we use communication data collected during SAVEX15 (Shallow-water Acoustic Variability Experiment 2015) carried out in the south-western part of Jeju Island from May 14 to May 28, 2015. Analysis results show that there are depths of energy concentration due to the channel characteristics in which the underwater sound channel are present, and the passive time-reversal technique using the limited number of the receivers can derive near-optimal communication performance if the receivers for time-reversal processing are located at the depths where energy is concentrated.