• Title/Summary/Keyword: 촉매 연소

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Physicochemical Characteristics of CDPF according to Ash a Cleaning agent (Ash 세정제에 따른 CDPF의 물리화학적 특성)

  • Seo, Choong-Kil
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.4
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    • pp.641-647
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    • 2017
  • In order to meet the stricter emission regulations, the proportion of after-treatments for vehicles and vessels has been increasing gradually. The objective of this study is to investigate the physicochemical properties according to ash cleaning agents of CDPF for Diesel Engines. Penetrating agents with strong penetration into ash and a surfactant component to mix water and oil were prepared properly. The cleaning characteristics of S1 sample were good. Washcoat loss rate of S1 sample was lower by about 2.2% because of less KOH component and lower Na2SiO3 content. Washcoat loss rate of S4 sample with an added KOH and Na2SiO3 components by penetration agents was increased by about 13%. In terms of less than about 13% of CDPF's washcoat loss rate, it was able to reduce the harmful gas components.

Catalytic Combustion of Methane over $AMnAl_{11}O_{19}$(A=La, Sr, Ba) and $CeO_2/LaAMnAl_{11}O_{19}$ ($AMnAl_{11}O_{19}$(A=La, Sr, Ba) 및 $CeO_2/LaAMnAl_{11}O_{19}$를 이용한 메탄의 촉매 연소)

  • Kim, Seongmin;Lee, Joon Yeob;Cho, In-Ho;Lee, Dae-Won;Lee, Kwan-Young
    • Korean Chemical Engineering Research
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    • v.49 no.5
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    • pp.633-638
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    • 2011
  • Mn substituted La, Sr or Ba-hexaaluminate were prepared by $(NH_4)_2CO_3$ co-precipitate method and calcined at $1,200^{\circ}C$ for 5 h. Catalysts were characterized by X-ray diffraction and $N_2$ physisorption and scanning electron microscope (SEM). Compared to $SrMnAl_{11}O_{19}$ and $BaMnAl_{11}O_{19}$, $LaMnAl_{11}O_{19}$ in which La located at mirror plane showed better crystallinity and high surface area, 13 $m^2/g$. $LaMnAl_{11}O_{19}$ revealed well developed plate-like structure which is characteristic structure of hexaaluminate. The catalytic activity of methane combustion increased in the following order: $LaMnAl_{11}O_{19}$ > $SrMnAl_{11}O_{19}$ > $BaMnAl_{11}O_{19}$ and was dependent on surface area of catalysts. 60 wt% $CeO_2/LaMnAl_{11}O_{19}$ calcined at $700^{\circ}C$ showed enhanced methane activity and methane was oxidized completely at low temperature ($700^{\circ}C$). It was confirmed that addition of ceria seems to be effective for the low and middle temperature combustion of methane. But, after calcination at high temperature of $1,200^{\circ}C$, it lost the promoting effect of ceria due to increase of ceria particle size and it had a limit to applying to the high temperature catalytic combustion.

Simultaneous Application of Platinum-Supported Alumina Catalyst and Ozone Oxidant for Low-temperature Oxidation of Soot (백금담지 알루미나 촉매와 오존 산화제 동시 적용에 의한 탄소 입자상 물질의 저온 산화반응)

  • Lee, Jin Soo;Lee, Dae-Won
    • Korean Chemical Engineering Research
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    • v.56 no.5
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    • pp.752-760
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    • 2018
  • The lowering of temperature for combustion of diesel particulate matters (or diesel soot) is one of the important tasks in automotive industry that is searching for a way to meet up "high-fuel efficiency, low-emission" standard. In this study, it was discussed how the use of ozone over platinum-based catalyst promotes a low-temperature soot oxidation occurred at $150^{\circ}C$. The use of platinum catalyst did not increase oxidation rate largely but was very effective in improving the selectivity of carbon dioxide. The pre-oxidation of NO into $NO_2$ using ozone was rather crucial in improving the oxidation rate of soot at $150^{\circ}C$.

Status and perspectives of the advanced catalytic combustion (촉매연소의 신기술 동향)

  • Kang, Sung-Kyu
    • 한국연소학회:학술대회논문집
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    • 2003.12a
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    • pp.299-308
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    • 2003
  • This paper provides a review of the status and of the perspectives of advanced catalytic combustion for ultra clean combustion of gas turbines and for industrial combustors. The development of catalytic materials and their combustion techniques for gas turbines are briefly reported. The fuel-rich approaches to catalytic combustion are mentioned for a new technology of thermal- and fuel-NOx control. The fuel-rich catalytic combustion are also applicable to the combustor of ceramic gas turbine, and to the combustion of biomess and municipal waste sludge. Some extended technologies of combustion synthesis are introduced for the synthesis of carbon nanotube and of Perovskite combustion catalysts

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자동차용 엔진의 연구동향

  • 이성렬
    • Journal of the KSME
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    • v.28 no.5
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    • pp.469-475
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    • 1988
  • 연료소비율의 향상은 점차 감소되어 가는 경향에 있다. 그 원인은 3원촉매변환기 채용에 의한 이론공기연료비의 사용, 기관의 연소개선이 발전하여 고압축비화에 의한 연료소비율 향상이 더 이상 어렵게 되었다는 점을 들 수 있다. 한편, 고압축비화의 역효과로는 연소실내 최고압력이 증가하여 각부의 강도나 기관 소음의 문제가 대두된다. 이들 역효과를 타파하여 충분한 연료 소비 향상을 얻을 수 있는 수단이 단기적인 과제가 될 것이다. 전자제어, 희박연소, 마찰저감 등 통상의 엔진의 개량에 대한 노력이 계속될 것이다.

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Study on the Enhancement of Burning Rate of HTPB/AP Solid Propellants (HTPB/AP계 고체 추진제의 연소속도 증진 방안 연구)

  • Lee, Sunyoung;Ryu, Taeha;Hong, Myungpyo;Lee, Hyoungjin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.21 no.4
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    • pp.21-27
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    • 2017
  • In this paper, in order to control the burning rate and pressure exponent of HTPB/AP/Al based propellant for the improvement of performance, the effect of the size ratio of AP particles and various contents of Butacene as burning catalyst on combustion properties was investigated. In the propellant formulation with both $28{\mu}m$ Al of 23% and Butacene of 3%, the burning rate and pressure exponent were increased with increasing the contents of $9{\mu}m$ AP particles. And the burning rate was increased with increasing the contents of Butacene with showing the relatively low pressure exponent in the propellant containing Butacene. However, the significant variations of pressure exponent by contents of Butacene were not observed.

Investigation on the Change of Ammonia Dissociation for Satellite Thruster According to the Catalyst Loss (위성추력기에서 촉매유실에 따른 암모니아 해리도 변화에 대한 연구)

  • Hwang, Chang-Hwan;Lee, Sung-Nam;Baek, Seung-Wook;Kim, Su-Kyum;Yu, Myoung-Jong
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.11a
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    • pp.218-222
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    • 2011
  • During the development of the iridium catalyst for domestic production, the catalyst failure, loss, sintering phenomena are observed by high pressure and temperature. By these abnormal failure of catalyst bed, the performance of thruster is degraded. To figure out the detail phenomena on the damaged catalyst bed, a numerical analysis code is developed by assuming the catalyst bed as an one dimensional porous media. The numerical analysis code is validated with experiment data. Thereby, resulting physical phenomena are examined by considering the variation of catalyst bed characteristics incurred by catalyst granule failure. Through these numerical analyses we figure out the effect of the catalyst loss on the decomposition of hydrazine and ammonia.

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