• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.3
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• pp.343-350
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• 2012

A planar solid oxide fuel cell (PSOFC) is studied in its application in a high-temperature stationary power plant. Even though PSOFCs with external reformers are designed for application from the distributed power source to the central power plant, such PSOFCs may sacrifice more system efficiency than internally reformed SOFCs. In this study, modeling of the PSOFC with an external reformer was developed to analyze the feasibility of thermal energy utilization for the external reformer. The PSOFC system model includes the stack, reformer, burner, heat exchanger, blower, pump, PID controller, 3-way valve, reactor, mixer, and steam separator. The model was developed under the Matlab/Simulink environment with Thermolib$^{(R)}$ modules. The model was used to study the system performance according to its configuration. Three configurations of the SOFC system were selected for the comparison of the system performance. The system configuration considered the cathode recirculation, thermal sources for the external reformer, heat-up of operating gases, and condensate anode off-gas for the enhancement of the fuel concentration. The simulation results show that the magnitude of the electric efficiency of the PSOFC system for Case 2 is 12.13% higher than that for Case 1 (reference case), and the thermal efficiency of the PSOFC system for Case 3 is 76.12%, which is the highest of all the cases investigated.

• 한국연소학회:학술대회논문집
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• 2004.11a
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• pp.181-186
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• 2004

Catalytic combustion is one of the suitable methods which is applicable to micro heat source due to high energy density and no flame quenching. And hydrogen can be oxidized at room temperature with platinum catalyst. So hydrogen-fueled micro catalytic combustor with platinum catalyst can be good and easy-handling heat source for another micro devices. In this work we focused on general catalytic combustion characteristics of hydrogen-air premixed gas in 10mm scale catalytic combustor for the further application to micro scale. Platinum was coated on dense ceramic monolith which can be installed in simple-structured catalytic combustor. We investigated the effect of flow rate, heat loss and platinum percentage in catalyst-coated monolith on catalytic combustion performance by temperature distribution in the combustor. By those results we confirmed catalytic reactivity and estimated reaction area. And we simulated micro scale catalytic reaction by sliced monolith. The results of this work will be important design factors for micro scale catalytic combustor.

• 한국연소학회:학술대회논문집
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• 2003.12a
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• pp.287-298
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• 2003

A numerical investigation of a catalytically stabilized thermal (CST) combustor was conducted for a multi-channel catalyst bed, and both the catalyst bed and thermal combustor were simultaneously modeled. The numerical model handled the coupling of the surface and gas reaction in the catalyst bed as well as the gas reaction in the thermal combustor. The behavior of the catalyst bed was investigated at a variety of operating conditions, and location of the flame in the CST combustor was investigated via an analysis of the distribution of CO concentration. Through parametric analyses of the flame position, it was possible to derive a criterion to determine whether the flame is present in the catalyst bed or the thermal combustor for a given inlet condition. The results showed that the maximum inlet temperature at which the flame is located in the thermal combustor increased with increasing inlet velocity.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1999.11a
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• pp.31-34
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• 1999

기-고체간의 접촉효율이 높고, 층 내 전체에 걸쳐서 균일한 기-고의 접촉을 갖는 등 많은 장점이 있어 석탄연소로, 촉매반응기와 같은 여러 기-고 반응기에 적용이 확대되고 있는 순환유동층은 높은 유속에서 조업되므로 상승관내 고체입자들은 즉시 비산하게 된다. 따라서, 원활한 반응에 필요한 상승관내 적절한 고체체류량 유지를 위해 고체입자들 대부분은 싸이클론에서 포집 되어 고체재순환부에 의하여 상승관내로 재주입 된다.(중략)

• Journal of the Korean Society of Propulsion Engineers
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• v.13 no.5
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• pp.48-56
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• 2009

The auto-ignition tests of hybrid rockets with the concentrated hydrogen peroxide as an oxidizer were presented. Auto-ignition was successfully demonstrated by injecting decomposed gases from $H_2O_2$ into paraffin or polyethylene fuels. In addition, restart and instant ignition were realized with this rocket. For stable combustion, a higher $L^*$ value was required for the paraffin combustion compared with PE. On the other hand, much faster response time was demonstrated in case of a paraffin, which was 13 and 30 ms at ignition delay and rise time respectively.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2009.11a
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• pp.499-502
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• 2009

The auto-ignition tests of hybrid rockets with the concentrated hydrogen peroxide as an oxidizer were presented. Auto-ignition, restartability, and instant ignition were successfully demonstrated by injecting decomposed gases from $H_2O_2$ into paraffin or polyethylene fuels. In addition, much faster response time was demonstrated in case of a paraffin, which was 13 and 30 ms at ignition delay and rise time respectively.

• Applied Chemistry for Engineering
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• v.19 no.5
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• pp.574-581
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• 2008

The optimum regeneration conditions for the regeneration of three way spent catalysts (TWCs), which were taken from automobiles with different driving conditions, were investigated to evaluate the suitability as alternative catalysts for removing VOCs. The spent catalysts were washed with five different acids ($HNO_3$, $H_2SO_4$, $C_2H_2O_4$, $C_6H_8O_7$, and $H_3PO_4$) to remove contaminants and examine the optimum conditions for recovering the catalytic activity. The physicochemical properties of spent and its regenerated TWCs were evaluated by using nitrogen adsorption-desorption isotherms, XRD, and ICP. The relative atomic ratios of contaminants and platinum group metals (PGMs) of the spent TWCs were greatly dependent on the placed positions. The main contaminants formed were lubricant oil additives and metallic components. Also, the regeneration treatment increased the PGMs ratio, BET surface area, and average pore diameter of TWCs. The catalytic activity results indicated that the spent TWCs have the possibility for removing VOCs. Moreover, the employed acid treatments greatly enhanced the catalytic activity of the spent TWCs. Especially, nitric and oxalic acids provided the most improvement in the catalytic behavior. The catalytic activities of the regenerated TWCs were significantly influenced by the containing platinum ratios rather than the removal ratios of contaminants and the changes in the structural properties offered by the acid treatments.

• Journal of the Korean Society of Propulsion Engineers
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• v.15 no.6
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• pp.56-62
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• 2011

An experimental study on design of a catalytic ignitor was performed to use an ignition source for a small bi-propellant liquid rocket engine which use hydrogen peroxide and kerosene as propellants. In the catalytic ignitor, hot gas of hydrogen peroxide which was decomposed by a catalyst induced autoignition of kerosene. Mass flow rate and O/F ratio for the ignitor were calculated by CEA code. A combustion chamber which had a quartz window and thermocouples was manufactured to determine whether the ignition is successful. Ignition performance was investigated according to exit area of fixed rings and mixture ratio. Results showed that reliable ignition performance was achieved at non-choking exit area of fixed ring and O/F ratio of 6~8.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.132.1-132.1
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• 2010

Anode off-gas of high temperature fuel cells such as MCFC still contain combustible components such as hydrogen, carbon monoxide and hydrocarbon. Thus, it's very important to fully burn anode off-gas and use the generated heat in order to increase system efficiency. In the present study, catalytic combustors have been applied to high temperature MCFC system so that the combustion of anode-off gas can be boosted up. Since the performance of catalytic combustor directly depends on the combustion catalyst, this study has been focused on the experimental investigation on the combustion characteristics of multiple commercial catalysts having different structures and compositions. In order to determine the design conditions of the catalytic combustor, parameters such as inlet temperature, space velocity and excess air ratio have been varied and optimized for combustor design. Results show that $H_2$ in off-gas assists $CH_4$ combustion in a way that it decreases minimum inlet temperature limit and increases maximum space velocity while keeping high fuel conversion efficiency.

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.92.1-92.1
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• 2011

Anode off-gas of high temperature fuel cells such as MCFC contains a significant amount of combustible components like hydrogen, carbon monoxide and methane according to fuel utilization ratio of the fuel cell stack. Thus, it is important to fully burn anode off-gas and utilize the generated heat in order to increase system efficiency and reduce emissions as well. In the present study, 25 kW catalytic combustor has been developed for the application to a load-following 300kW MCFC system. Mixing and combustion characteristics have been experimentally investigated with the catalytic combustor. Since the performance of catalytic combustor directly depends on the combustion catalyst, this study has been focused on the experimental investigation on the combustion characteristics of multiple catalysts having different structures and compositions. Results show that the exhaust emissions are highly dependent on the catalyst loading and the ratio of catalytic components. Test results at load-following conditions are also shown in the present study.