• Title/Summary/Keyword: 촉매연소

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A study on the combustion performance with Hydrogen Peroxide / Kerosene (과산화수소/ 케로신을 추진제로 한 200N급 엔진의 연소 성능에 관한 연구)

  • Kim, Young-Mun;Hwang, Oh-Sik;Lee, Yang-Suk;Ko, Young-Sung;Kim, Yoo;Kim, Sun-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.05a
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    • pp.61-64
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    • 2009
  • A study on the variation of combustion performance by oxidizer/fuel ratio was conducted. Shower head type injector was used. Injector propelled by liquid kerosene and liquid hydrogen peroxide. The designed operation condition for thrust and combustion pressure were 200N and 10bar. It is found that optimum oxidizer/fuel ratio.

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Study for Bio HC - SCR over $Ag/Al_{2}O_{3}$ catalyst (Ag/$Al_{2}O_{3}$ 촉매를 이용한 Bio HC - SCR 연구)

  • Lee, Min-Joo;Lee, Hye-Min;Lee, Ju-Hun;Kim, Jin-Gul
    • Proceedings of the KAIS Fall Conference
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    • 2007.05a
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    • pp.39-41
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    • 2007
  • 자동차의 연소과정 후 발생되는 NOx를 제거하기 위하여 재생유(Bia-diesel)를 환원제로 사용하였으며, $Ag/Al_{2}O_{3}$ 를 배출가스 후처리 촉매로 사용하였다. 그에 따른 물리적 특성을 조사하고 bio-diesel 환원제의 질소산화물 제거 성능 실험을 수행하였다. 그 결과 $Ag/Al_{2}O_{3}$ 촉매계에서 최적의 Ag 담지량은 2wt% 인 것으로 나타나고, 산처리된 $Ag/Al_{2}O_{3}$ 촉매가 반응 온도$300^{\circ}C$ 에서 가장 높은 NOx 제거 전화율을 나타낸다.

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Performance Analysis of Off-Gas/Syngas Combustor for Thermal Management of High Temperature Fuel Cell System (고온형 연료전지 열관리를 위한 배기가스 연소기 성능시험)

  • Lee, Sang-Min;Lee, Youn-Hwa;Ahn, Kook-Young;Yu, Sang-Seok
    • Journal of Hydrogen and New Energy
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    • v.21 no.3
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    • pp.193-200
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    • 2010
  • Anode off-gas of high temperature fuel cell still contains combustible components such as hydrogen, carbon monoxide and hydrocarbon. In this study, a catalytic combustor has been applied to the high temperature fuel cell so that the combustion of anode-off gas can be boosted up. Since the performance of catalytic combustor directly depends on the combustion catalyst, this study is designed to perform the experimental investigation on the combustion characteristics of the three commercial catalysts with a different composition. Screening tests with three catalysts are preceded before the performance examination since it is necessary to determine the most suitable catalyst for design configuration of the catalytic combustor. The performance analysis shows that methane conversion rate strongly depends on gas hourly space velocity (GHSV) as well as inlet gas temperature. Additionally, the GSHV optimization results show that the optimum GHSV will be in the range between 18,000 $hr^{-1}$ and 36,000 $hr^{-1}$. It is also shown that the minimum inlet temperature of catalytic reaction of methane is from $100^{\circ}C$ to $150^{\circ}C$.

Catalytic Combustion of Ozone Precursor Using Metal -Phthalocyanine Catalyst (금속-프탈로시아닌을 이용한 오존전구물질의 촉매연소)

  • 서성규;윤형선;김상채
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 1999.10a
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    • pp.449-450
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    • 1999
  • VOCs(volatile organic compounds)는 대기중에서 질소산화물과 함께 광화학반응에 참여하여 인체 및 동식물에 유해한 오존 등 2차 오염물질인 광화학산화물을 형성하는 전구물질로 작용한다. 1998년 8월 미국 EPA에서는 휘발성유기화합물과 지표 부근의 오존 또는 스모그의 발생량을 감소시키기 위해 페인트, 세제 및 살충제의 제조공법에 관한 새로운 규칙을 발표하여 휘발성 용제 사용 규제를 강호하고 있다(과학기술부, 1998).(중략)

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Decomposition of Toluene using a 2 Stage Reactor Composed of Dielectric Barrier Discharge and Adsorption Process (DBD와 흡착공정을 조합한 2단형 반응기에서 톨루엔 분해에 관한 연구)

  • 김관태;이웅재;한소영;한의주;최연석;송영훈;김석준
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.11a
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    • pp.415-416
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    • 2000
  • 플라즈마 화학공정을 이용한 유해대기오염물질(HAP$_{s}$ 또는 VOC$_{s}$ ) 처리기술은 기존의 촉매연소, 소각 및 흡착기술등에 비하여 낮은 초기 투자비, 여러가스의 동시처리, 소형화 또는 이동 배출원에 대한 적용이 가능하며, 대상가스의 종류나 발생량등에 따라 여러 전원(AC, Pulse, DC)을 이용한 기술개발이 가능하여 많은 연구가 진행되고 있다.$^{(1-4)}$ (중략)

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A Circulating Fluidized Bed Scrubbing Technology for Dry Removal of the SOx and NOx of Coal Combustion Gases (석탄연소가스내의 SOx/NOx 동시처리를 위한 순환유동식 건식세정기술)

  • 이상권;조경민
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1999.05a
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    • pp.69-74
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    • 1999
  • 각종 산업체의 공정에서 혹은 석탄 혹은 석유를 사용하는 화력발전설비에서 다량 발생되는 질소산화물(NOx), 황산화물(SOx)의 배출규제가 점점 강화되어 감에 따라 배출량 절감이 절실히 요구된다. 기존의 배기가스 정화장치는 처리대상에 따라 다양한 방법들이 사용되는데 황산화물의 경우 습식, 반건식, 건식세정법에 의해, 질소산화물은 선택적 촉매환원법(Selective Catalytic Reduction)과 선택적 무촉매환원법(Selective Non Catalytic Reduction)이 널리 이용되고 있다.(중략)

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Research for Performance Improvement of De-NOx of Cu-SCR Catalysts (Cu-SCR 촉매의 De-NOx 성능 향상을 위한 연구)

  • Seo, Choong-Kil
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.3
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    • pp.112-118
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    • 2018
  • In order to meet the strict emission regulations for internal combustion engines based on fossil fuel, the proportion of after-treatments for vehicles and vessels is gradually increasing. Diesel engines have high power, good fuel economy, and lower $CO_2$ emissions, and their market shares are increasing in commercial vehicles and passenger cars. However, NOx is generated in the localized high-temperature combustion regions, and particulate matter is formed in the zones of diffusion combustion. LNT and urea-SCR catalysts have been developed for after-treatment of the exhaust gas to reduce NOx in diesel vehicles. This study aims to improve the NOx reduction performance of Cu SCR catalyst, which is widely used in light, medium, and heavy-duty diesel engines. The de-NOx performance of $5Cu-2ZrO_2$/93Zeolyst(Si/Al=13.7) SCR catalyst was about 5-50% higher than that of $5Cu-2ZrO_2$/93Zeolite(Si/Al=2.9) at catalyst temperatures of $300^{\circ}C$ or higher. The zeolite had lower metal dispersion than zeolyst, and the reaction rate of the catalyst decreased as the average particle size increased. The $10Cu-2ZrO_2$/88Zeolyst catalyst loaded with 10wt% Cu had the highest NOx conversion rate of 40% at $200^{\circ}C$ and about 65% at $350^{\circ}C$. The ion exchange rate of Cu ions increased with that of Al, the crystalline compound of zeolite, and the de-NOx performance was improved by 20-40% compared to other catalysts.

Study for combustion characteristic according to the O/F ratio of low thrust rocket engine using green propellant (친환경 추진제를 사용하는 저추력 엑체로켓엔진의 혼합비에 따른 연소 특성)

  • Jeon, Jun-Su;Kim, Young-Mun;Hwang, O-Sik;Ko, Young-Sung;Kim, Yoo;Kim, Sun-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.11a
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    • pp.134-137
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    • 2009
  • Combustion tests of a low thrust rocket engine was performed to get combustion characteristics, which used a high concentrated hydrogen peroxide and kerosene as the oxidizer and fuel. The engine consisted of multi injector(six coaxial swirl injectors), chamber, nozzle and catalyst ignition system. The test was carried out by changing O/F ratio from 3.8 to 11.0. The experimental results showed that combustion efficiency was highest at O/F ratio from 5 to 6 and pressure fluctuations of all the range were lower than 5%.

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