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Study on the Stability of NaBH4 Solution during Storage Process (NaBH4수용액 저장과정 중 안정성에 관한 연구)

  • Sim, Woojong;Jo, Jaeyoung;Choi, Daeki;Nam, Sukwoo;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.48 no.3
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    • pp.322-326
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    • 2010
  • Stability of sodium borohydride solution during storage was studied. In order to enhance the $NaBH_4$ stability, NaOH and KOH were added to the $NaBH_4$ solution. The effect of concentration of the borohydride and alkaline solution, temperature and materials of storage vessels on the rate of borohydride hydrolysis was investigated. The rate of hydrogen evolution decreased as the concentration of alkaline increased due to increase of $NaBH_4$ stability in the solution. The stability of $NaBH_4$ solution decreased when the borohydride concentration raised from 10 to 15 wt% and then increased when the $NaBH_4$ concentration increased above 15 wt% due to increase in the pH of the concentrated solution. The activity coefficient of hydrolysis of $NaBH_4$ solution(NaOH 3.0 wt%, $NaBH_4$ 25 wt%) was 115.1 kJ/mol and this value was 1.5~4.0 times higher than that of hydrolysis of $NaBH_4$ solution with catalyst. The borohydride solutions in glass and stainless-steel vessel were more stable than the solution in plastic(PE) vessel.

Study on crystallization behavior of an ethylene-polypropylene copolymer based encapsulant for photovoltaic application (태양전지 봉지재용 에틸렌-프로펠렌 공중합체의 결정화 거동에 관한 연구)

  • Son, Younggon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.12
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    • pp.737-742
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    • 2016
  • We prepared five different ethylene-propylene copolymers (EPCs) for use as the encapsulant of a photovoltaic module. All of the polymers were of commercial grade from ExxonMobile company and had different ethylene/propylene compositions. The crystallization behaviors and crystal structures of the polymers were analyzed by differential scanning calorimetry and wide angle X-ray scattering diffractometry, respectively. We observed the general trend that the degree of crystallization, density and glass transition temperature of the EPCs decreased with increasing ethylene content. However, an unexpected result was also observed: the EPC with the highest ethylene content (22.2 mol. %) showed the highest melting temperature. As a result, the EPC with 22.2 mol. % of ethylene shows the highest light transmittance, due to its having the lowest degree of crystallization and highest thermal creep resistance. This abnormal result is attributed to the blocky structure prepared by ExxonMobile's special catalyst technology. It was also observed that new additional melting peaks appeared as the crystallization time increased. Using wide angle X-ray scattering diffractometry, it was confirmed that these additional peaks originated from the formation of a new crystal structure caused by annealing.

Anti-Reflection Coating Technology Based High Refractive Index Lens with Ultra-Violet Rays Blocking Function (반사방지 코팅기술 기반 자외선 차단 기능의 고굴절률 안경렌즈)

  • Kim, Ki-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.12
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    • pp.482-487
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    • 2016
  • Ultra-violet rays are very harmful to eye health care. The blocking of ultra-violet rays and a reduction of optical reflection in the visible light range, which is to increase the share of transmitted light, and avoid the formation of ghost images in imaging, are important for the applications of polymer eyeglasses lenses. In this study, the high-refractive index polymer lenses, n=1.67, were fabricated by injection-molded method with the xylene diisocyanate monomer, 2,3-bis-1-propanethiol monomer, and benzotriazol UV absorber (SEESORB 709) mixture. To reduce the reflection of the polymer lens surfaces, multi-layer anti-reflection (AR) coatings were coated for both sides of the polymer lens using an E-beam evaporation system. The optical properties of the UV blocking polymer lens were characterized using a UV-visible spectrometer. The material properties of the thin films, which were composed AR coating layers, refractive index, and surface roughness, were analyzed by ellipsometry and atomic force microscopy. As a result, the fabricated polymer lens perfectly blocked ultra-violet rays below 395 nm with a blocking rate greater than 99%.

Preparation and Photoluminescence Characteristics of Liquid Silicone Rubber Containing Cadmium Selenide Nanoparticles (Cadmium Selenide Nanoparticles을 함유하는 액상실리콘 고무의 제조와 형광특성)

  • Kang Doo-Whan;Lee Byoung-Chul;Kim Ji-Young
    • Polymer(Korea)
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    • v.30 no.3
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    • pp.266-270
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    • 2006
  • Poly [(dimethylmethylyinyl) siloxane] phosphineoxide (PMViSPO) was prepared by adding phosphorus oxychloride $(POCl_3)$ to poly (dimethylmethylyinyl) siloxane (PMViS) at $0^{\circ}C$ under nitrogen atmosphere. Cadmium selenide (CdSe) was prepared by reacting cadmium oxide (CdO), tetradecyl-phosphonic acid (TDPA), trioctylphosphine oxide (TOPO) at $300^{\circ}C$, and adding solution of dissolved Se to tributylphosphine (TBP) and trioctylphosphine (TOP) CdSe-poly [(dimethylmethylvinyl) siloxane] phosphine-oxide (CdSe-SPO) adduct was synthesised by adding PMViSPO to CdSe solution. Liquid silicone rubber composite (LSRC-1) was prepared by compounding $\alpha,\omega-vinyl$ poly (dimethylsiloxane) (VPMS), $\alpha,\omega-hydrogen$) poly(dimethylsiloxane) (HPMS), and CdSe under Pt catalyst, and also LSRC-2 was prepared from VPMS, HPMS, and CdSe-SPO using Pt catalyst. It was confirmed that CdSe nanoparticles with photoluminescence characteristics was dispersed uniformly in LSR matrix. The diameter of CdSe was $30\sim50nm$. By measuring the number of CdSe nanoparticles, 202 particles of CdSe in LSRC-2 and 165 particles of CdSe in LSRC-1 were dispersed in the same area of LSR matrix. Thermal stability for LSRC-2 compounded with CdSe-SPO was better than LSRC-1.

A Study on AI Business Ecosystem (인공지능 비즈니스 생태계 연구)

  • Yoo, Soonduck
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.20 no.2
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    • pp.21-27
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    • 2020
  • The purpose of this study is to investigate the ecosystem structure underlying the development of artificial intelligence technology and related industries. In addition, the research on the AI business ecosystem based on AI technology and the ways to activate them was discussed. Ecosystems play a role in organically connecting producers, consumers, and decomposers. In the AI ecosystem, we classified the AI service producers, producers of AI services using the produced services, and data and related infrastructure services that are the basis of AI services. Stakeholders in the AI business ecosystem are the government and various private organizations that have a direct or indirect influence on AI service production, consumption, and operation. In Korea, in particular, the government plays a role as the most influential stakeholders. For example, the company contributes to the increase of producers, which are related to human resource development, and plays a catalyst role in the increase of services produced by R & D funding. In this study, the policy for revitalizing the AI business ecosystem includes (1) securing the environment for increasing producers, (2) spreading AI awareness among consumers, (3) securing data exchange and supply infrastructure, and (4) supporting services and related laws. Secure the system. This study is meaningful in that it contributes to and contributes to the construction of domestic AI-based environment and related research.

Various Technologies for Simultaneous Removal of NOx and SO2 from Flue Gas (배출가스의 질소산화물과 이산화황 동시 저감 기술)

  • Park, Hyun-Woo;Uhm, Sunghyun
    • Applied Chemistry for Engineering
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    • v.28 no.6
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    • pp.607-618
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    • 2017
  • Harmful air pollutants are exhausted from the various industrial facilities including the coal-fired thermal power plants and these substances affects on the human health as well as the nature environment. In particular, nitrogen oxides ($NO_x$) and sulfur dioxide ($SO_2$) are known to be causative substances to form fine particles ($PM_{2.5}$), which are also deleterious to human health. The integrated system composed of selective catalytic reduction (SCR) and wet flue gas desulfurization (WFGD) have been widely applied in order to control $NO_x$ and $SO_2$ emissions, resulting in high investment and operational costs, maintenance problems, and technical limitations. Recently, new technologies for the simultaneous removal of $NO_x$ and $SO_2$ from the flue gas, such as absorption, advanced oxidation processes (AOPs), non-thermal plasma (NTP), and electron beam (EB), are investigated in order to replace current integrated systems. The proposed technologies are based on the oxidation of $NO_x$ and $SO_2$ to $HNO_3$ and $H_2SO_4$ by using strong aqueous oxidants or oxidative radicals, the absorption of $HNO_3$ and $H_2SO_4$ into water at the gas-liquid interface, and the neutralization with additive reagents. In this paper, we summarize the technical improvements of each simultaneous abatement processes and the future prospect of technologies for demonstrating large-scaled applications.

A Study on Fashion Design Using Geometric Pattern (기하학적 패턴을 활용한 패션디자인 연구)

  • 김신우;금기숙
    • Journal of the Korean Society of Costume
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    • v.52 no.1
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    • pp.53-67
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    • 2002
  • 자연을 분석함으로써, 얻어진 기하학적 패턴은 이미 자연의 질서를 포함하고 있는 논리적이고 합리적인 기본형이기 때문에 간결하며 시각적으로 명쾌감을 준다. 이러한 기하학적 패턴은 복식 디자인에 있어서 20 세기 이후 여러 디자이너의 작품을 통해 재구성되어 현대적 이미지를 나타내는 중요한 모티브가 되고 있으며, 다양한 기법과 재료로 형성화하여 도입되고 있다. 이에 본 연구는 복식의 문양, 실루엣, 디테일에 사용되고 있는 기하학적 패턴을 연구함으로써 기하학적 패턴의 새로운 조형가치를 고찰하였다. 먼저 기하학의 용어 정의를 하였고 기하학적 패턴의 유형과 표현 기법을 분석하고 정리하여 현대 패션에 나타난 기하학적 패턴의 조형미와 그것을 바탕으로 패션 이미지를 추론해 보았다. 현대 패션에 나타난 기하학 패턴을 분석해 보면 유형으로는 첫째, 기하하적 문양으로 복식디자인에 있어서 주로 평면적인 형태로 많이 나타나지만, 크기가 다르고 동일한 기하학적 패턴을 조합시킴으로서 평면적인 형태에 공간감을 부여하기도 하며, 같은 기하학적 패턴의 표면이라도 배치구조에 의해 직선 혹은 사선으로 지각되므로 전혀 다른 이미지를 주었다. 또한 현대 패션에 나타난 기하학적 패턴이 종류는 세로 스트라이프, 가로 스트라이프, 격자 문양, 원, 사선 스트라이프, 마름모, 사각형, 삼각형 등의 순서로 많이 나타났다. 둘째, 색채는 단색의 복식에 강한 대비가 이루어지는 색상으로 표현되어 역동감과 유연한 운동감을 나타났다. 셋째, 기하학적 실루엣으로 단순한 라인의 형태를 나타내거나 입체적이고 부조적인 형태로 구성되어 전체적인 실루엣으로 사용되어 강한 조형감각을 보여주는데 원형을 이용한 실루엣이 가장 많았으며 사각형을 이용한 실루엣, 삼각형을 이용한 실루엣 순서로 나타났다. 넷째, 기하학적인 디테일로 복식의 어느 한 부분에 장식적으로 사용되거나 입체적 형태로 부출 되어 부조적인 느낌을 주는데 소매에 가장 많이 나타났으며 앞여밈, 칼라, 밑단, 주머니 순서로 장식되었다. 다섯째, 현대 패션에 표현된 기하학적 패턴의 표현기법으로는 프린팅, 퀼팅, piece기법, 패치워크, 엮기, 꼴라쥬, 아플리케 순서로 많이 나타났다. 위의 분석을 토대로 기하학 패턴을 활용한 디자인에 내재된 조형의지는 다음과 같이 정리되었다. 첫째, 기하학적 패턴이 지닌 단순성과 경직성을 완화하기 위하여 여러 가지 패브릭을 조합시켜 입체적인 표면효과로 시각적인 착시효과를 극대화하였다. 둘째, 표현기법은 입체파적 표현주의의 특성의 하나로 복시에 사용되는 소재의 왜곡으로 설명할 수 있으며, 새롭고 실험적인 소재의 도입으로 인해 의외성과 부조화를 유발시키는 통시에 유희직인 일면도 지니는 일종의 그로테스크를 나타냈다. 이상에서 정립된 조형의지를 바탕으로 현대 패션에 나타란 기하학 패턴은 절제된 단순함과 명확성으로 단순미가 유추되었고 강한 색상대비로 인한 시각적 집중효과로 주목성을 가지며 재현이 가능하므로 반복성이 유추되었다. 그리고 표준영역이 없는 창의적 표현으로 풍부한 독창성을 보여주고 있다. 또한 내재된 패션 이미지를 분석해 보면 정확함과 차가움의 의미를 지닌 이지적 이미지와 우주의 질서를 반영하는 상징적 이미지, 복잡한 자연으로부터 간결한 형태로의 경향성이 이루어낸 인공적 이미지를 느낄 수 있었으며, 미래적 이미지와 전통적 이미지의 상반된 개념의 이미지를 같이 내포하고 있음을 추론할 수 있었다. 이와 같이 현대 패션에 표현된 기하학적 패턴은 복식을 조형예술 분야로 확실히 인식시키고 발전시키는 데 중요한 촉매제 역할을 담당하고 있으며 또한 많은 디자이너들에게 창조적 욕구를 불러일으키고 영감을 주는데 중요한 모티브를 제공하고 있다.

$CO_2$ Removal Process Case Studies and Plant Performance Analysis for 300MW IGCC Power Plant (300MW 급 IGCC Power Plant $CO_2$ 제거공정의 Case Studies 및 Plant 성능 영향 분석)

  • Jeon, Jinhee;Yoo, Jeongseok;Paek, Minsu
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.71.2-71.2
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    • 2011
  • 300MW 급 태안 IGCC 가스화 플랜트 및 기존 발전소에 CCS 를 설치할 경우에 대해 기술 타당성 검증을 목적으로 CCS 모델링을 수행하였다. CCS Case Studies 는 플랜트 운전부하에 따른 $CO_2$ 제거율, $H_2S$ 제거율, 소모동력 범위 등 플랜트 성능을 예측할 수 있다. Case Studies 결과를 활용하여 설계된 CCS 설비 용량이 운전범위에 적합한지를 판단할 수 있고 과잉 설계되었을 경우 플랜트 건설비를 절감할 수 있다. IGCC 가스화 플랜트에서 생산되는 합성가스의 $CO_2$ 분압, 목표 $CO_2$ 제거율, 경제성을 기준으로 적합한 CCS 공정을 판단한 결과 Selexol 공정이 선정되었다. Selexol 공정은 고압, 고농도의 산성가스 제거에 적합하며 다른 물리적 용매인 Rectisol 공정에 비해 건설비용이 경제적이고 화학 흡수제인 아민과 비교하여 운전 온도 범위가 넓다. CO, $H_2O$$CO_2$, $H_2$ 로 전환하는 Water Gas Shift Reaction (WGSR) 공정은 Co/Mo 촉매 반응기로 구성되었고 Selexol 공정은 $H_2S$ Absorber, $H_2S$ Stripper, $CO_2$ Absorber, $CO_2$ Flash Drum 로 구성되었다. WGSR+Selexol 모델링은 Wet Scrubber 후단의 합성가스 (40.5 bar, $136{\sim}139^{\circ}C$) 를 대상으로 하였다. WGSR+Selexol 공정 운전 조건 변화 [Process Design Case(PDC), Equipment Design Case(EDC), Turndown Design Case(TDC)] 에 따른 플랜트 모델링 결과를 비교분석 하였다. 주요 분석 내용은 WGSR 설비에서의 CO 의 $CO_2$ 전환 효율, Selexol 설비에서 $CO_2$ 제거 효율, $H_2S$ 제거 효율이다. 모델링 결과 WGSR 설비에서의 CO 의 $CO_2$ 로의 전환율 99.1% 이상, Selexol 설비에서 $CO_2$ 제거율은 91.6% 이상, $H_2S$ 제거율 100%이었다. CCS 설비 설치에 따른 플랜트 성능 영향을 분석하기 위해서 CCS 설비의 Chiller, Compressor, Pump 소비동력을 계산하였다. 모델링 결과 Chiller 는 2.6~8.5 MWth, Compressor 는 3.0~9.6 MWe, Pump 는 1.4~3.0 MWe 범위 이었다. 플랜트 로드가 50%인 TDC 소모동력은 플랜트 로드가 100%인 PDC 소모동력의 절반 수준이었다. 합성가스를 WGS+Selexol 공정을 통해 수소가스로 전환시키면 가스터빈 연료가스의 Lower Heating Value (LHV) 값이 평균 11.5% 감소하였다.

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Surface Modification of Proton Exchange Membrane by Introduction of Excessive Amount of Nanosized Silica (과량 실리카 도입을 통한 고분자 전해질막 표면 개질)

  • Park, Chi Hoon;Kim, Ho Sang;Lee, Young Moo
    • Membrane Journal
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    • v.24 no.4
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    • pp.301-310
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    • 2014
  • In this study, the silica nanoparticles were considerably chosen to improve a dimensional stability, proton transport and electrochemical performance of the resulting inorganic-organic nanocomposite membranes. For this purpose, hydrophobic silica (Aerosil$^{(R)}$ 812, Degussa) and hydrophilic silica (Aerosil$^{(R)}$ 380, Degussa) nanoparticles were, respectively, introduced into a Sulfonated poly(arylene ether sulfone) (SPAES) polymer matrix. The $SiO_2$ particles are evenly dispersed in a SPAES matrix by the aid of a non-ionic surfactant (Pluronics$^{(R)}$ L64). A $SiO_2$ content plays an important role in membrane microstructures and membrane properties such as proton conductivity and water uptake. Therefore, to study nanocomposite membranes with excessive amount of silica, the content of silica nanoparticles were increased up to 5 wt%. Interestingly, a hydrophobic $SiO_2$ containing nanocomposite membrane showed better electrochemical performance (29% higher than pristine SPAES) despite of low proton conductivity due to its adhesive properties with a catalyst layer in a single cell test. All the silica-SPAES membranes exhibited better performance than a pristine SPAES membrane.

Kinetics and Mechanism of the Selective Oxidation of Ethylene for Ethylene Oxide over Monolithic Silver Catalyst (모놀리스형 은촉매상에서 에틸렌선택산화반응의 속도론적 고찰)

  • Park, Rho-Bum;Kim, Sang-Chai;Sunwoo, Chang-Sin;Yu, Eui-Yeon
    • Applied Chemistry for Engineering
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    • v.2 no.2
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    • pp.165-174
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    • 1991
  • The kinetics and the mechanism for the selective oxidation of ethylene on the supported monolithic silver catalyst were experimentally investigated in a fixed bed tubular reactor. The formation rates of ethylene oxide and carbon dioxide were measured at the atmospheric pressure with various combinations of partial pressures of ethylene and oxygen at temperature range of $225-300^{\circ}C$, conversion with 1.2-7.5 %, and then the mechanism of the selective oxidation of ethylene was verified. Their formation rates fitted with the Langmuir-Hinshelwood mechnism. The ethylene oxide and carbon dioxide are produced by reation of adsorbed ethylene with monoatomic oxygen adsorbed on the active sites of Ag-surface, and their formation rate equation are expressed as : $R_{EO}={\frac{k_1K_0{^{1/2}}K_EK_SP_{02}{^{3/2}}P_E}{(1+{\sqrt{K_0P_{02}}}+K_EP_E+K_PP_P)^2(1+{\sqrt{K_SP_{02}})^2}}$ $R_C={\frac{k_2K_0{^3}K_EK_S{^{7/2}}P_{02}{^{13/2}}P_E}{(1+{\sqrt{K_0P_{02}}}+K_EP_E+K_PP_P)^7(1+{\sqrt{K_SP_{02}})^7}}$ The activation energies of ethylene oxide and dioxide and carbon dioxide formations can be estimated to be 12.25 and 17.85 Kcal/mol, respectively.

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