• Proceedings of the Korean Institute of Industrial Safety Conference
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• 2002.05a
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• pp.57-60
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• 2002

국내에서 사용되고 있는 대부분의 화재대피용 방독마스크 정화통은 외국에서 고가에 수입되고 있거나, 국내 제조시는 많은 기술을 외국에 의존하고 있다. 이들 정화통의 충진재는 일산화탄소(CO)를 제거하기 위해 망간(Mn), 구리(Cu)등을 활성탄에 담지시켜 제조한 촉매층과 $SO_2$, HCI 등의 유독가스를 제거하기 위한 제올라이트 등의 흡착층으로 구성되어있다. 그러나 이들 충진재중 CO 제거용 촉매는 상온에서 CO의 제거효율이 낮아 많은 양을 충진해야 하는 어려움이 있다.(중략)

• Journal of Aerospace System Engineering
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• v.11 no.2
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• pp.9-15
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• 2017

In order to verify the possiblity of improving the combustion performance of ethanol using zeolite catalyst and the characteristics of nitrogen oxides and carbon monoxide emission, micro gas turbine experiments were performed using catalytic reaction products, ethanol and kerosene as fuels and the results were compared. The thrust of the catalytic reaction product was lower than that of kerosene, but it was improved by 5% on average compared with the use of ethanol. Nitrogen oxides and carbon monoxide emissions of the catalytic reaction products were measured to be very low overall compared to kerosene. As a result, when the ethanol was reformed using the zeolite catalyst, the engine performance could be improved while maintaining the environment friendliness of the ethanol.

• Journal of the Korean Institute of Gas
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• v.20 no.2
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• pp.1-9
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• 2016

Combined removal of n-heptane and carbon monoxide (CO) using a plasma-catalytic process was investigated. The performance of the plasma-catalytic process was compared with that of the catalyst-alone process to characterize the decomposition of n-heptane and CO with the operation parameters such as the type of catalyst, reaction temperature, and discharge power. From several sets of experiments, it was found that the decomposition efficiency of n-heptane mainly depended on the specific input energy rather than the reactor temperature, whereas the oxidation of CO on both the energy density and the reaction temperature. The results conducted over several metal oxide catalysts exhibited that the decomposition efficiency of n-heptane was in the order: $Pd/{\gamma}-Al_2O_3$ > $Ru/{\gamma}-Al_2O_3{\approx}Ag/{\gamma}-Al_2O_3$. Especially, $Pd/{\gamma}-Al_2O_3$ catalyst did hardly generate CO as a byproduct during the decomposition of n-heptane under an appropriate condition, revealing $CO_2$ selectivity of nearly 100%. The CO oxidation efficiency was largely affected by the type of catalyst ($Pd/{\gamma}-Al_2O_3$ > $Ru/{\gamma}-Al_2O_3$ > $Ag/{\gamma}-Al_2O_3$). At temperatures below $180^{\circ}C$, the plasma-catalytic process was more effective in the oxidation of CO, while above $180^{\circ}C$, the catalytic process resulted in slightly higher CO oxidation efficiency.

• Journal of the Korean Chemical Society
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• v.29 no.6
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• pp.656-663
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• 1985

A catalytic conversion of carbon monoxide has been studied in a coal combustion system. Three different catalysts were prepared by impregnating 0.2% platinum on three different types of supports, ${\gamma}-Al_2O_3$ pellets, ceramic foam and honeycomb. These catalysts have shown an excellent initial activities in the coal combustion system, but they were rapidly deactivated in repeated uses. Among these catalysts ceramic foam has shown to be better than others both in activities and durabilities. The main cause of deactivation seems to be ascribed to poisoning by zinc metal and sulfur compounds and to decrease in platinum surface area by sintering.

• Applied Chemistry for Engineering
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• v.22 no.3
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• pp.243-248
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• 2011

Pt deposited porous carbon nanofibers was prepared as a highly sensitive material of hydrogen gas sensor operating at room temperature. Nanofibers was obtained by electrospinning method using polyacrylonitrile as a carbon precursor and then thermally treated for carbon nanofibers. Chemical activation of carbon nanofibers was carried out to enlarge specific surface area up to $2093m^2/g$. Sputtered Pt layer was uniformly distributed keeping the original shape of carbon nanofibers. The hydrogen gas sensing time and sensitivity were improved based on effects of high specific surface area, micropore structure and deposited Pt catalyst.

• Journal of the Korean Institute of Gas
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• v.14 no.2
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• pp.7-14
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• 2010

Synthesis gas was produced by the partial oxidation of methane. For the preparation of catalysts, Ni, known to be active in this reaction and cheap, was used as the active component and $CeO_2$, having high oxygen storage capability and high redox ability, was used as the support. The catalysts were prepared by the impregnation and urea methods. The catalyst prepared by the urea method showed about 11 times higher surface area and finer particle size than that prepared by the impregnation method. The catalysts prepared by the urea method showed higher methane conversion and synthesis gas selectivity than that prepared by the impregnation method. In this reaction, carbon deposition is a problem to be solved, so La was added to the catalyst system to reduce the carbon deposition. TGA analysis results showed that there was 2% carbon deposition with La-added catalysts and 16% with La-free catalysts. It was found that the addition of La decreases the amount of carbon deposition and prevents catalyst deactivation.

• Journal of Hydrogen and New Energy
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• v.34 no.4
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• pp.327-333
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• 2023

The water gas shift reaction was carried out using the commercial catalyst pellet and the simulated gases expected to occur from waste plastic gasification. In the water gas shift reaction, the high temperature shift reaction and the low temperature shift reaction were continuously performed with CO:H₂O ratio of 1:2, 1:2.5, and 1:3, and the CO conversion and H₂ increase rate were evaluated. The H₂ increase rate increased in order to CO:H₂O ratio of 1:3 > CO:H₂O ratio of 1:2.5 > CO:H₂O ratio of 1:2. The CO conversion showed a high value of more than 97% at each CO:H₂O ratio. The water gas shift reaction at a CO:H₂O ratio of 1:3 showed the highest H2 increase rate and CO conversion.

• Journal of Korean Society of Environmental Engineers
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• v.34 no.12
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• pp.840-846
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• 2012

Global climate changes caused by $CO_2$ emissions are currently debated around the world; green sources of energy are being sought as alternatives to replace fossil fuels. The sustainable use of biogas for energy production does not contribute to $CO_2$ emission and has therefore a high potential to reduce them. Catalytic steam reforming of a model biogas ($CH_4:CO_2$ = 60%:40%) is investigated to produce $H_2$-rich synthesis gas. The biogas utilized 3D-IR matrix burner in which the surface combustion is applied. The ruthenium catalyst was used inside a reformer. Parametric screening studies were achieved as Steam/Carbon ratio, biogas component ratio, Space velocity and Reformer temperature. When the condition of Steam/Carbon ratio, $CH_4/CO_2$ ratio, Space velocity and Refomer temperature were 3.25, 60% : 40%, $14.7L/g{\cdot}hr$ and $550^{\circ}C$ respectively, the hydrogen concentration and methane conversion rate were showed maximum values. Under the condition mentioned above, $H_2$ yield, $H_2$/CO ratio, CO selectivity and energy efficiency were 0.65, 2.14, 0.59, 51.29%.

• Journal of Hydrogen and New Energy
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• v.20 no.6
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• pp.519-525
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• 2009

The catalytic steam reforming of woody biomass tar and soot to convert a synthetic gas containing hydrogen was investigated by using a bench-scale biomass gasification system. One commercial nickel-based catalyst, Katalco 46-6Q, and two different kinds of natural minerals, dolomite and olivine, were tested as a reforming catalyst at various reforming temperatures. The reaction characteristics of woody biomass tar were also investigated by TGA at a variety of heating rates. With all three catalysts conversion efficiency of tar and soot increased at increasing temperature. The reforming of tar and soot in the synthetic gas induce the increase of combustible gases such as $H_2$, CO and $CH_4$ in the product gas. The nickel-based catalyst showed a higher tar and soot conversion efficiency than mineral catalysts under the same temperature conditions.

• Applied Chemistry for Engineering
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• v.19 no.4
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• pp.376-381
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• 2008

The deactivation of $V/TiO_2$ catalyst used in SCR (Selective Catalytic Reduction) using ammonia as a reductant to remove the nitrogen oxides (NOx) in the exhaust gas from fired power plant has been studied. The activity and surface area of the catalyst (Used-cat) which was exposed to the exhaust gas for long period have considerably decreased. The characterizations of these SCR catalysts were performed by XRD, FT-IR, FE-SEM, and IC/ICP. The crystal structure of $TiO_2$ both fresh and used catalyst has not been changed. However, $(NH_4)HSO_4$ deposited on the used catalyst surface verified from FT-IR, FE-SEM, and IC/ICP analysis. Moreover, the durability of $SO_2$ was increased by diminishing sulfate ($SO_4^{-2}$)f form.