• Electrical & Electronic Materials
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• v.3 no.2
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• pp.90-98
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• 1990

Y-Bi-Ba-Cu-O계 초전도체를 보통의 ceramic방법과 screen printing과 소결법으로 원판형과 후막형으로 제작하였다. B $i_{2}$ $O_{3}$를 첨가하여 소결한 $Y_{1}$B $a_{2}$C $u_{3}$ $O_{7-y}$의 초전도 성질은 전기저항측정과 자석위에 부상 유무로 조사하였다. 또한 B $i_{2}$ $O_{3}$를 첨가함에 따라 소결된 시편의 미세구조에 어떠한 영향을 주었는지 알아보았다. 전기저항 측정시 Yttrium 대신에 Bi로 부분적으로 치환한 경우인 $Y_{0.85}$B $i_{0.15}$B $a_{2}$C $u_{3}$ $O_{7-y}$의 상온 저항치가 기본조성인 $Y_{1}$B $a_{2}$C $u_{3}$ $O_{7-y}$의 그것보다 향상된 미세구조로 인해 더 작은 값을 나타낸다. 반면 $Y_{1}$B $a_{2}$C $u_{3}$ $O_{7-y}$에다가 초과로 B $i_{2}$ $O_{3}$를 첨가한 경우 오히려 미세구조는 불량하고 상온저항치도 더 높다. 이러한 사실은 입계에 잔류하는 이차상은 전기적 성질에는 크게 영향을 주나 자기적 성질에는 거의 영향을 주지않는 것으로 보인다. 후막으로 Y-Bi-Ba-Cu-O를 제작시 기판에 의해 좌우되는데 단지 magnesia 기판에서 소결시 bulk시편과 유사한 성질을 나타냈다.질을 나타냈다.다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1997.11a
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• pp.182-184
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• 1997

Superconducting thick films were fabricated with various paticle sizes on Allumina substrates by MPMG method. The sample of about 63${\mu}{\textrm}{m}$ in this experimented the size of particles was the best for uniformity and the number of Y211. In this experiment It is observed that powder size is very important to fabricate the superior thick finns.

• Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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• 1999.02a
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• pp.22-25
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• 1999

A well oriented Bi-2212 superconductor thick films were fabricated by screen printing with a Cu-free Bi-Sr-Ca-Cu-O powder on a copper plate and heat-treating at 820- $880^{\circ}C$for several minute in low oxygen pressure or are. At minute in low oxygen pressure of air. At , the printing layer partially melted by reaction between the Cu-free precursor by reaction between the Cu-free$870^{\circ}C$ precursor and CuO of the oxidizing copper plate. It is believed that the solid phase is Bi : Sr : Ca : Cu = 2 : 2 : 0 : 1. It is likely that the Bi-2212 superconducting phase is formed at Bi-2212 superconducting phase is formed at Bi-free phase/liquid interface by nucleation and grows.

• Progress in Superconductivity and Cryogenics
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• v.10 no.1
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• pp.6-9
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• 2008

We have investigated the MOD process successfully for the fabrication of the YBCO thick film on the $LaAlO_3$(001) single crystalline substrate. The cracking problem in YBCO thick film, a serious problem in the conventional TFA-MOD method, could be overcome with a careful control of precursor materials. Thus coating solution was prepared for the YBCO thick film by using fluorine-free precursor material. The precursor solutions were coated on the LAO(001) single crystalline substrate using the dip coating method, calcined at the temperature up to $500^{\circ}C$, and fired at various high temperatures for 2 h in a reduced oxygen atmosphere. Optimally processed YBCO thick film exhibited high critical current($I_c$) over 200 A/cm-width at 77K in self-field.

• 한국초전도학회:학술대회논문집
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• v.9
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• pp.315-318
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• 1999

Bi$_{2}Sr_{2}CaCu_{2}O_{\delta}$ superconducting films were rapidly fabricated on copper tape by liquid reaction between a Cu-free precursor and Cu tape (LiReac-PreCu) method. Those thick films were well oriented along the c-axis. The precursor was made by melt-quenched technology using twin roller. The melt-quenched films were transparent and glossy yellow in appearance. These films which were the compostion of Bi$_2SrCaO_y$, Bi$_3Sr_2CaO_z$ were placed on copper tape and then heated at various temperatures for several minutes in air. They were analyzed using X-ray powder diffraction, SEM, a DC four-probe method. The mechanism of superconducting phase formation . from the melt-quenched precursor on Cu tape was studied

• Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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• 1999.02a
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• pp.47-50
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• 1999

The orientation mechanism of an amorphous $Bi_{2}$$Sr_{2}$$Ca_{2 x}$$Cd_{x}$$Cu_{3}$$O_{y}$ phase were studied by using the dilatometry. The amorphous $Bi_{2}$$Sr_{2}$$Ca_{2 x}$$Cd_{x}$$Cu_{3}$$O_{y}$ samples brought about a volume shrinkage at the onset of the crystallization of a $Bi_{2}$$Sr_{2}$$CaCu_{2}$$O_{6}$phase around $400^{\circ}C$. The random crystal growth of $Bi_{2}$$Sr_{2}$$CaCu_{2}$$O_{8}$ phase around $800^{\circ}C$. yielded a rapid volume expansion and after then samples shrinmed, accompanied with the crystal orientation. The$Bi_{2}$$Sr_{2}$$Ca_{2 x}$$Cd_{x}$$Cu_{3}$$O_{y}$ (x=0.4) sample exhibited the best-oriented structure because the liquid phase formed seemed to have the lowest viscosity which would contributed to the easy collapse of the card-house structure.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2003.05a
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• pp.38-41
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• 2003

상업용 Ag 판재 위에 cyclic 전위와 일정 전위를 인가하는 전기증착법으로 Tl-1223상 precursor 막을 증착하는 연구를 수행한 다음, 이를 이영역 전기로를 사용하여 열처리함으로써 고온초전도 coated conductors를 제조하는 연구를 수행하였다. 전기증착법으로 비교적 균질하고 치밀한 precursor막을 증착할 수 있었으며, 이 막을 $870^{\circ}C$에서 20분 동안 열처리하여 임계온도가 114 K이고 자속고정능력도 비교적 우수한 50%의 Tl-1223상과 50%의 Tl-1212상으로 구성된 고온초전도 도체를 제조할 수 있었다. 이로부터 아주 값싼 증착법인 전기증착법을 이용하여 후막의 고온초전도 도체를 제조할 수 있음을 증명하였다.

• 한국초전도학회:학술대회논문집
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• v.9
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• pp.296-299
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• 1999

Bi$_2Sr_2CaCu_2O$(Bi-2212) thick films were fabricated on Y2l1 substrate by screen printing method. And the samples were annealed in various atmospheres, respectively. Though samples had many voids, the sample annealed in N$_2$ ; O$_2$ = 1:0 atmosphere and the sample in N$_2$ : O$_2$ = 0:1 showed some Bi 2212 low phase in comparison to other samples. The thickness of Bi-2212 on Y2ll substrates was about 20 ${\mu}$m.

• Journal of the Korean Ceramic Society
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• v.31 no.12
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• pp.1483-1490
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• 1994

YBa2Cu3Ox-Ag(YBCO-Ag) thick films were fabricated on the zirconia substrate by a screen printing method. The starting powder was a mixture of YBCO, prepared by a coprecipitation in oxalic acid, and Ag2O. The influence of heat treatment conditions on properties of thick films was investigated. It was observed that Jc of thick films was directly proportional to the orientation factor of thick films and the optimimum preparation condition was the heat treatment of thick films at 100$0^{\circ}C$ for 3 min in O2. The improvement of Jc by the addition of Ag was considered as a result of the suppression of microcracks in the films.

• Journal of the Korean Ceramic Society
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• v.30 no.12
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• pp.1007-1014
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• 1993

YBa2Cu3Ox(YBCO) thick films were prepared by a screen printing of the powders, obtained by a coprecipitation in oxalic acid, on the Y2O3-stabilized zirconia substrates and their superconducting properties were determined. TC, JC and the orientation factor of the thick films increased with increasing temperature up to 103$0^{\circ}C$ and then the superconducting properties disappeared with further heat treatments. The optimization of JC was achieved by heating thick films at 103$0^{\circ}C$ for 7min. In this case the TC of the thick film was determined to be 87.5K. It was observed that TC of thick films depends on the orthorhombicity and JC is likely governed by a microstructure of YBCO rather than by the orientation factor.