• Clean Technology
• /
• v.11 no.4
• /
• pp.171-179
• /
• 2005

Biodiesel is synthesized by transesterification of vegetable or animal oils with alcohols. Since it has similar characteristic with diesel fuel, it can be used as a fuel by mixing with diesel fuel. Moreover, it is advantageous that biodiesel can reduce air pollution emitted from fuel combustion and is produced from sustainable energy, biomass. Recently, many researchers have investigated biodiesel synthesis using supercritical methanol since it is economical due to shorter reaction time and simple separation/purification process, compared with conventional alkali- or acid-catalyzed process. By the development of biodiesel production process from waste edible oil using supercritical methanol, it can be expected to utilize potential energy resources, reduce carbon dioxide emission, and improve environmental conditions.

• Clean Technology
• /
• v.17 no.4
• /
• pp.300-305
• /
• 2011

A mixture of supercritical carbon dioxide and a co-solvent was employed to strip a high-dose ion-implanted photoresist (HDIPR) from the surface of semiconductor wafers. The stripping efficiency was highly improved by the physical force generated from a ultrasonication tip inside the reactor. In addition, helium gas was injected in the reactor as a barrier gas before the introduction of pure supercritical $CO_2$ ($scCO_2$), which reduced the rinsing time significantly. The effect of co-solvents on the stripping efficiency was investigated. The wafer surfaces were analyzed by scanning electron microscopy and by an energy dispersive X-ray spectrometer.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2017.05a
• /
• pp.475-481
• /
• 2017

In this paper, high speed camera images were used to analyze the supercritical injection behavior of liquid hydrocarbon compounds used as main components of propellant fuel. Decane and Methylcyclohexane (MCH), which have different critical points among kerosene constituents, were selected as experimental fluid and Shadowgraphy technique was used for the analysis. The difference in the temperature variation from the initial injector state of the subcritical condition until the vaporization occurs was represented by the different behaviors of Decane and MCH. However, under the Supercritical conditions, the enthalpy of vaporization near the critical point approaches zero and the phase change to the Supercritical phase occurs instead of vaporization process. In the phase change of the Supercritical system, there was no rapid density change, so the liquid state image was observed in both the Decane and MCH.

• KSBB Journal
• /
• v.18 no.4
• /
• pp.301-305
• /
• 2003

The study of pancreatin extraction was investigated by supercritical fluid process. Using supercritical carbon dioxide extraction with entrainer the purification of pancreatin was possible to remove lipids from Hog pancreas. To observe the optimum conditions different experimental variables were changed as pressure, temperature, flow rate of solvent and 0.25 mm of sample size were evaluated for effective removal of lipids. Ethanol and n-hexane were used as an entrainer with 5 mL/min. Increasing pressure at constant temperature the efficiency of the lipid removal in Hog pancreas was improved and the protein was concentrated without denaturalization, compared that of the control Hog pancreas. The most efficient conditions of lipid elimination were 17 MPa of pressure and 35$^{\circ}C$ of temperature and 0.25 mm of sample size.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.20 no.4
• /
• pp.26-33
• /
• 2016

In order to analyze supercritical transition of liquid hydrocarbon fuel which used propulsion engine, visualization of phase changing using Methylcyclohexane (MCH) was performed. Also, measurements of temperature and pressure were conducted to obtain saturation lines of MCH and Decane. delayed increase of the pressure existed near the critical point due to dramatical increase of specific heats and the critical opalescence was only observed from the end point of delaying to the critical point. Beyond the critical point, the boundary between phases disappeared and the strong density gradient was observed. As the comparison between experimental and numerical saturation lines, the numerical estimation for mixture had relatively little difference while the results of pure components had almost coincidence.

• The Journal of Engineering Research
• /
• v.3 no.1
• /
• pp.207-213
• /
• 1998

In order to fabricate ideal powders, new processing is necessary in which the solute atoms in solution rapidly move to mix each other to the degree of molecular level, the viscosity of solution should be low not to effect the moving of solute atoms, and the powders could be directly obtained as crystalline. Supercritical fluid is defined as condensed gas state up to its critical pressure and temperature. In this paper, supercritical fluid methods were studied as a new ceramic processing of powder preparation. The crystalline anatase powders of $TiO_2$ which are useful for photocatalyst materials were fabricated by hydrolysis of titanium(IV) ethoxide using water which was ethanol as a supercritical fluid.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.31 no.1 s.256
• /
• pp.40-50
• /
• 2007

The present contribution describes the application of elliptic-blending second moment closure to predict the gas cooling process of turbulent super-critical carbon dioxide flow in a square cross-sectioned duct. The gas cooling process under super-critical state experiences a drastic change in thermodynamic and transport properties. Redistributive terms in the Reynolds stress and turbulent heat flux equations are modeled by an elliptic-blending second moment closure in order to represent strongly non-homogeneous effects produced by the presence of walls. The main feature of Durbin's elliptic relaxation second moment closure that accounts for the nonlocal character of pressure-velocity gradient correlation and the near-wall inhomogeneity guaranteed by the elliptic blending second moment closure.

• Proceedings of the SAREK Conference
• /
• 2004.11a
• /
• pp.103-103
• /
• 2004

• Proceedings of the KSME Conference
• /
• 2001.06e
• /
• pp.524-529
• /
• 2001

Because of the ozone layer depletion and global wanning, new alternative refrigerants are being developed. Among them, HFC refrigerants are thought promising, but some European countries are arguing that these refrigerants are also harmful to the global wanning. Therefore, natural refrigerants should be considered as an eventual alternative in refrigerators and heat pumps. In the present study, the supercritical gas cooling process are computationally analysed by employing various turbulence models of carbon dioxide in a trans critical refrigeration cycle. The gas cooling process near the critical point experiences a drastic change in thermodynamic and transport properties, thus the heat transfer characteristics would be different from those of two or single phases. Based on the computational results, the correlations to estimate the near-critical heat transfer characteristics will are obtained.

• Journal of ILASS-Korea
• /
• v.15 no.4
• /
• pp.182-188
• /
• 2010

Significant real fluid behaviors including rapid property changes take place where high pressure combustion devices such as rocket engines. The flamelet model is the reliable approach to account for the real fluid effects. In the present study, the flamelet equations are extended to treat the general fluids over transcritical and supercritical states. The real fluid flamelet model is carried out for the gaseous hydrogen and cryogenic liquid oxygen flames at the wide range of thermodynamic conditions. Based on numerical results, the precise discussions are made for effects of real fluid, pressure, and differential diffusion on the local flame structure.