• Title/Summary/Keyword: 초음파분무기

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Rare Earth Element Analysis with Chromatography-Inductively Coupled Plasma Atomic Emission Spectrometry and the Comparison of Cross Flow and Ultrasonic Nebulizers (크로마토그래피-유도 결합 플라스마 원자방출 분광법을 이용한 희토류 원소들의 연속적 분석 및 직교형과 초음파분무기의 비교)

Theory and practice of synthesized ZnO powders by ultrasonic spray pyrolysis method (초음파 분무 열분해법에 의한 ZnO 합성의 이론과 실제)

  • 서수형;신건철
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.5 no.1
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    • pp.60-66
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    • 1995
  • Abstract The experimental results which is the aerosols behavior and distribution of atomized zinc nitrate ($Zn(NO_3)_2$) solution (0.5 M) by ultrasonic vibrator were in accord with the computer simulations. i.e., most aerosols passing through the reactor (hot zone) moved toward the center of reactor by thermophoresis as the axis of reactor increase. Also, the distribution of aerosols concentration was high at the center of reactor as the axis increase. Among the synthesized ZnO particles, shell-like aggregates of fracture type which could not see at the center of reactor were observed at near the wall of reactor, and the particle size ($ 1.2 {\mu\textrm{m}$) of near the wall was larger than that ($0.9 {\mu\textrm{m}$) of the center.

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Signal compensation by the light scattering of sample aerosols in ICP-AES (ICP-AES에서 에어로졸의 광산란에 의한 신호의 보정)

  • Yeon, Pyung-Hum;Pak, Yong-Nam
    • Analytical Science and Technology
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    • v.25 no.4
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    • pp.223-229
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    • 2012
  • Analytical signal from ICP was compensated by the light scattering of sample aerosols. Reference scattering signal was generated by a He-Ne or diode laser, monitored for the amount of aerosol producing and used for the compensation of analytical signals. The result showed that significant improvement in precision could be achieved for the short-term signal (within 1 minute) from 3.4% to 0.9% RSD in signal and 14.9% to 4.2% for the long-term (10 minutes) for Be, Pb and Co. This method is very useful not only for the pulse type but for continuous type signals especially when a nebulizer is unstable. To improve long-term precision, higher stability is required in the scattering cell and detector as well as the reduction of noise from the line between a nebulizer and plasma.

Atomization Effects of Diesel on Autothermal Reforming Reaction (디젤연료의 미립화에 따른 자열개질 반응특성에 관한 연구)

  • Bae, Joong-Myeon;Yoon, Sang-Ho;Kang, In-Yong
    • Journal of ILASS-Korea
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    • v.11 no.4
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    • pp.234-243
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    • 2006
  • Diesel autothermal reforming (ATR) is a chemical process to produce hydrogen for fuel cell applications. Several previous studies were carried out to identify technical issues in diesel reforming. It is hard to vaporize diesel due to its high boiling points. Liquid droplets of diesel result in inhomogeneous fuel mixing with other reactants such as $O_2\;and\;H_2O$, which leads to reduce the reforming efficiency and make undesired coke in reactor. To solve the fuel delivery issue, we applied an ultrasonic device as a fuel injection system. Ultrasonic injector (UI) remarkably enhanced the reforming efficiency. This paper will present the reforming results using UI. And we will discuss about atomization effects of diesel on autothermal reforming reaction.

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Restraint of carbon deposition in diesel ATR using fuel atomizer (연료 미립화기를 이용한 디젤 자열개질기 내 탄소침적 억제)

  • Yoon, Sang-Ho;Kang, In-Yong;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.67-70
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    • 2007
  • Diesel autothermal reforming has several problems such as carbon deposition in reforming reactor, sulfur poisoning of catalyst, difficulty of aromatics decomposition and mixing problems of reactants(diesel, steam, oxygen). Severe carbon deposition causes the rapid performance degradation of reformer. Carbon deposition is formed from ethylene, carbon precursor. Ethylene was generated at the homogeneous reaction zone of the reactor entrance. This phenomenon is closely linked to the mixing of reactants. In this investigation, we try to minimize the ethylene generation at the reactor entrance atomization technique.

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A Study on Ppray Ignition Phenomena Using Shock Tube Combustion System Design (충격파관 시스템설계에 의한 분무의 착화현상 연구)

  • ;水谷幸夫
    • Journal of Energy Engineering
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    • v.3 no.1
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    • pp.54-61
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    • 1994
  • 계단형태의 고온발생장치로서, 고온의 흐름을 형성하고 난류유동이 없이 일정한 혼합기류를 만들 수 있는 2단격막구조 충격파관 장치를 이용하여, 혼합을 동반하지 않는 분무의 착화과정에 관한 실험을 수행하였다. 본 실험에서는 충격파관 속에 하향으로 설치된 초음파 분무기에 의해 자유낙하 상태에 있는 예혼합 분무주를 만들어서 반사충격파에 의해 순간적으로 단열압축시켜서 착화 현상을 관찰하였다. 고온영역과 저온영역에서 얻어진 활성화에너지는 큰 차이가 나며 본 연구에서 얻은 착화지연의 실험결과는 통상의 분무착화 실험인 전기로법, 급속압축기법, 고온기류속에 연료를 분사하는 방법과 다른 현상을 보였다. 그 대표적인 결과에 대한 예로는 착화지연에 대한 압력 의존성과 연료분사율의 영향이 일반적인 분무의 결과에 비해 적게 나타났다.

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The Characteristics of an Ultrasonic Sprayer by using Piezoelectric Ceramic Resonator (압전 세라믹 진동자를 이용한 초음파 분무기의 분무 특성)

  • Bae, Sang-Tae;Lee, Su-Ho;Sug, Jeong-Young;Kim, Cheol-Hwan;SaGong, Geon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.5
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    • pp.405-410
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    • 2009
  • The conventional ultrasonic nozzle produces a mist by applying an ultrasonic vibration into a non-flowering liquid. In this paper, we first present a novel designed nozzle type sprayer that is able to apply an ultrasonic vibration directly to the moving liquid and generate a mist instantly. For the novel nozzle, a ring-type actuator of the novel nozzle was designed and built using the PZW-PMN-PZT ceramics. This paper will describe a variety of physical, mechanical, and electrical characteristics of the ultrasonic nozzle. The characteristics of the mist particles was also measured as the amount of the outflow liquid was varied.

Determination of Rare Earth Elements by Inductively Coupled Plasma Mass Spectrometry with Introduction of Organic Phase Using Ultrasonic Nebulizer (초음파 분무기를 이용한 유기상의 주입에 의한 희토류 원소의 유도결합 플라스마 질량분석법적 정량)

  • Lee, Sang Hak;Son, Bum Mok
    • Analytical Science and Technology
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    • v.15 no.2
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    • pp.127-134
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    • 2002
  • Analytical method to determine rare earth elements which were extracted to organic phase by inductively coupled plasma mass spectrometry(ICP-MS) was investigated. Organic phase which had extracted rare earth elements was directly aspirated into ICP-MS by ultrasonic nebulizer(USN) in order to reduce solvent load to the plasma. Then, the count rate increased when MIBK(methyl isobutyl ketone) was added to EtOH(ethanol) but decreased when 0.03 M HEH(2-ethylhexyl-2-ethylhexyl phosphonic acid, $P_{507}$, PC88A) was added to solvent which mixed MIBK with EtOH. The optimal temperatures of desolvation system were -10 $^{\circ}C$ for the condenser and 150 $^{\circ}C$ for the heating tube. The optimal nebulizer flow rate which gave maximum count rate and minimum reflect power was 0.7 L/min. The optimal pH and extraction time were 4.3 and 10 min for MIBK-0.03 M HEH system. Detection limits which were obtained through calibration curves at the range of 0.2 ${\sim}$ 20 ng/mL were 0.02 ${\sim}$ 0.05 ng/mL under the optimal experimental conditions.