• Title/Summary/Keyword: 초분자

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CHOBUN, Understanding the Double Burial Custom in Korea from a Jungian Perspective : Focusing on Putrefaction and Reduction to Bones (초분, 한국 이중장제의 분석심리학적 고찰 : 부패와 뼈로의 환원을 중심으로)

  • Jahyeon Cho
    • Sim-seong Yeon-gu
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    • v.31 no.2
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    • pp.113-150
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    • 2016
  • Chobun refers to a temporary grave covered with straw thatch that contains a corpse until its flesh is gone. When all the flesh has rotted away, the straw grave is disassembled and only the bones are retrieved. Therefore, Chobun is an example of a secondary burial custom (German : Doppel Bestattung) that is composed of a first temporary funeral for processing the corpse's flesh, and a second permanent burial of the final remains (bones or ashes). The duration of the temporary burial is determined by the time needed for decomposing the flesh of the deceased. Building a Chobun progresses putrefaction and reduction to bone. In the literature of alchemy, putrefaction and new life occur simultaneously. The purpose of rotting is to make the flesh disappear, leaving only its essence. It is making the physical body enter a spiritual state, so that the dead can enter into a different world. One must endure the unstable rotting process until the smell of flesh has faded. The rotting process is the attitude of accepting the terrible, polluted aspect of the corpse, while maintaining a helpless, passive posture, in order to allow new possibilities. When we try to approach an archetypal aspect of the unconscious, it is often experienced in threatening, aggressive ways. In the individuation process, the unconscious offers us the blessing of a new spiritual awakening and renewed sense of life, only when we have the courage to see this terrifying and contaminated side of our psyche. This is exactly what putrefaction means. Bone and skeleton symbolize the indestructible, imperishable, and essential elements of life. Bone is the minimum unit and foundation for regeneration, where new life can grow. Reduction to bone is moving back to the origin of life, to the womb. Psychologically, it means discarding one's ego-centeredness and allowing the Self to lead the entire process of individuation. Going through the painful process of reduction to a skeleton for the purpose of further development is a declaration of the death of the ego, aiming at the liberation from perishable flesh and acquisition of the spiritual, regenerative, and immortal elements of life. Chobun also denotes the yearly decay and revival of life, especially of vegetal life. In Chobun, this symbolic meaning of the vegetal cycle of life is emphasized to represent the part of life that survives even after death. Vegetation related to Chobun deals with the continuity of life and psychologically with the Self. Images of vegetation are closely related to the existence of life beyond death, which is the existence of the Self, the source of energy that constantly renews and rejuvenates the consciousness.

Synthesis and Properties of Hyperbranched Polyester with Second-Order Outical Nonlinearity (2차 비선형 광학 초분지형 폴리에스테르의 합성 및 특성)

  • 이종협;이광섭
    • Polymer(Korea)
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    • v.25 no.6
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    • pp.803-810
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    • 2001
  • A nonlinear optical hyperbranched polyester (PE-Azo/Hyper) was synthesized from 4-[N,N-bis(hydroxyethyl)amino-4'-formyl] azobenzene and cyanoacetic acid by a Knoevenagel polycondensation using 4-(dimethylamino) pyridine as a base. The resulting polymer was soluble in polar aprotic solvents such as N,N-dimethylformamide and 1-methyl-2-pyrrolidinone and could be processed into optical quality films by spin coating. The molecular weight was determined to be $M_w$=61,800 ($M_W/M_n{=1.86}$) by gel permeation chromatography using polystyrene as a standard. No melting point was detected by differential scanning Calorimeter, indicating that this polymer presents an amorphous state. It shows a glass transition temperature of $121^{\circ}C$. The second-order nonlinear optical coefficient $d_{33}$ of the poled polymer determined by the second harmonic generation at 1064 nm was 25.4 pm/V.

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Effect of Hydrophilic Polymers on the Release of BCNU from BCNU-loaded PLGA Wafer (친수성 고분자가 BCNU 함유 PLGA 웨이퍼로부터 BCNU의 방출에 미치는 효과)

  • 안태군;강희정;문대식;이진수;성하수
    • Polymer(Korea)
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    • v.26 no.5
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    • pp.670-679
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    • 2002
  • 1,3-bis(2-chloroethyl)-1-nitrosourea (BCNU, carmustine) is one of the effective chemotherapeutic agents which has been used clinically for treating malignant glioma. Poly(D,L-lactide-co-glycolide) (PLGA, molecular weight: 20000 g/mole. mole ratio of lactide to glycolide 75 : 15) is a well known biodegradable polymer used as a drug carrier for drug delivery system. In this study, we investigated the BCNU release behaviour of BCNU-loaded PLGA wafers containing poly (N-vinylpyrrolidone) (PVP) or polyethyleneoxide (PEO) and the effect of hydrophilic polymers incoporated in the wafers. BCNU-loaded PLGA microparticles with or without hydrophilic polymers were prepared by a spray drying method and fabricated into wafers by direct compression. Encapsulation efficiency of BCNU-loaded PLGA microparticles containing PVP and PEO was 85 ∼ 97% and crystallinity of BCNU encapsulated in PLGA decreased significantly initial release amount and release rate of BCNU increased with the increasing PVP or PEO amount. Morphological change and mass loss of wafers during the release test were confirmed that hydration and degradation of PLGA would be facilitated with an increase of hydrophilic polymers.

Hyperspectral Image Analysis Technology Based on Machine Learning for Marine Object Detection (해상 객체 탐지를 위한 머신러닝 기반의 초분광 영상 분석 기술)

  • Sangwoo Oh;Dongmin Seo
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.28 no.7
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    • pp.1120-1128
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    • 2022
  • In the event of a marine accident, the longer the exposure time to the sea increases, the faster the chance of survival decreases. However, because the search area of the sea is extremely wide compared to that of land, marine object detection technology based on the sensor mounted on a satellite or an aircraft must be applied rather than ship for an efficient search. The purpose of this study was to rapidly detect an object in the ocean using a hyperspectral image sensor mounted on an aircraft. The image captured by this sensor has a spatial resolution of 8,241 × 1,024, and is a large-capacity data comprising 127 spectra and a resolution of 0.7 m per pixel. In this study, a marine object detection model was developed that combines a seawater identification algorithm using DBSCAN and a density-based land removal algorithm to rapidly analyze large data. When the developed detection model was applied to the hyperspectral image, the performance of analyzing a sea area of about 5 km2 within 100 s was confirmed. In addition, to evaluate the detection accuracy of the developed model, hyperspectral images of the Mokpo, Gunsan, and Yeosu regions were taken using an aircraft. As a result, ships in the experimental image could be detected with an accuracy of 90 %. The technology developed in this study is expected to be utilized as important information to support the search and rescue activities of small ships and human life.

Photo-responsive Smart Polymer Materials (광 응답형 스마트 고분자 소재)

  • Yu, Jong-Su;Lee, Seong-Yun;Na, Hee-Yeong;Ahn, Tae-Jung;Kim, Hyun-Kyoung
    • Elastomers and Composites
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    • v.47 no.4
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    • pp.282-291
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    • 2012
  • Control of shape/volume, mechanical, optical, electrical, and chemical switching of materials by external stimuli such as light, temperature, pH, electric field, and pressure has attracted great attention. Among these materials, photo-responsive materials containing photochromic compounds such as azobenzene, spiropyran, and cinnamic acid groups have been the subject of intense interest in recent years. In this review, we describe the recent progress in the area of azobenzene containing polymer materials that can convert light energy into mechanical energy directly. Especially we focus our attention on light-driven actuators such as artificial muscle, motor, and valve. We summarize the photomechanical effects in liquid crystal elastomer, amorphous polymer, monolayer, and supramolecules containing azobenzene, respectively.

Synthesis and Properties of Photocurable Pentaerythritol Modified Hyperbranched Acrylate (광경화형 Pentaerythritol 변성 초분지형 아크릴레이트의 합성과 물성)

  • Kim Dong Kook;Lim Jin Kyu;Kim Woo Geun;Heo Jung Lim
    • Polymer(Korea)
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    • v.29 no.3
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    • pp.237-241
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    • 2005
  • Photocurable pentaerythritol modified hyperbranched acrylates were prepared from trimellitic anhydride, glycidyl methacrylate and pentaerythritol derivatives. Thermal stability obtained by using TGA showed that HBMA-1 was superior to the others. Hardness, abrasion resistance and tensile strength of HBMA-1 showed that Hey were also superior to the others. Value of yellow index of HBMA-1 showed the lowest.

Semiempirical Calculations of Hyperpolarizabilities for Quinoline Derivatives (Quinoline계 분자의 초분극률에 관한 반경험적 계산)

  • Ryu Ungsik;Choi Donghoon;Kim Nakjoong;Lee Yoon Sup
    • Journal of the Korean Chemical Society
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    • v.37 no.1
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    • pp.62-67
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    • 1993
  • The microscopic origin of nonlinear optical properties of quinoline derivatives have been investigated theoretically using MOPAC-AM1 method. In order to prepare promising nonlinear optical active polymers of polyquinoline derivatives, the optimized positions of strong electron donor and electron acceptor are determined in the heterocyclic ring for the energetically favorable structures. For each compound, the effect of the substituted positions on the microscopic nonlinear coefficients were investigated. Polyquinoline was already evaluated to have outstanding physical and mechanical properties so that its monomeric analogues were designed and synthesized for developing new second and third order nonlinear optical main chain polymers. Using the MOPAC-AM1 method, properties calculated include the intrinsic ground-state dipole moments, the polarizabilities, first and second hyperpolarizabilities under the condition of finite-field $(\omega$ = 0).

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Development of tracer concentration analysis method using drone-based spatio-temporal hyperspectral image and RGB image (드론기반 시공간 초분광영상 및 RGB영상을 활용한 추적자 농도분석 기법 개발)

  • Gwon, Yeonghwa;Kim, Dongsu;You, Hojun;Han, Eunjin;Kwon, Siyoon;Kim, Youngdo
    • Journal of Korea Water Resources Association
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    • v.55 no.8
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    • pp.623-634
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    • 2022
  • Due to river maintenance projects such as the creation of hydrophilic areas around rivers and the Four Rivers Project, the flow characteristics of rivers are continuously changing, and the risk of water quality accidents due to the inflow of various pollutants is increasing. In the event of a water quality accident, it is necessary to minimize the effect on the downstream side by predicting the concentration and arrival time of pollutants in consideration of the flow characteristics of the river. In order to track the behavior of these pollutants, it is necessary to calculate the diffusion coefficient and dispersion coefficient for each section of the river. Among them, the dispersion coefficient is used to analyze the diffusion range of soluble pollutants. Existing experimental research cases for tracking the behavior of pollutants require a lot of manpower and cost, and it is difficult to obtain spatially high-resolution data due to limited equipment operation. Recently, research on tracking contaminants using RGB drones has been conducted, but RGB images also have a limitation in that spectral information is limitedly collected. In this study, to supplement the limitations of existing studies, a hyperspectral sensor was mounted on a remote sensing platform using a drone to collect temporally and spatially higher-resolution data than conventional contact measurement. Using the collected spatio-temporal hyperspectral images, the tracer concentration was calculated and the transverse dispersion coefficient was derived. It is expected that by overcoming the limitations of the drone platform through future research and upgrading the dispersion coefficient calculation technology, it will be possible to detect various pollutants leaking into the water system, and to detect changes in various water quality items and river factors.

A Comparative Study on Speech Rate Variation between Japanese/Chinese Learners of Korean and Native Korean (학습자의 발화 속도 변이 연구: 일본인과 중국인 한국어 학습자와 한국어 모어 화자 비교)

  • Kim, Miran;Gang, Hyeon-Ju;Ro, Juhyoun
    • Korean Linguistics
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    • v.63
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    • pp.103-132
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    • 2014
  • This study compares various speech rates of Korean learners with those of native Korean. Speech data were collected from 34 native Koreans and 33 Korean learners (19 Chinese and 14 Japanese). Each participant recorded a 9 syllabled Korean sentence at three different speech rate types. A total of 603 speech samples were analyzed by speech rate types (normal, slow, and fast), native languages (Korean, Chinese, Japanese), and learners' proficiency levels (beginner, intermediate, and advanced). We found that learners' L1 background plays a role in categorizing different speech rates in the L2 (Korean), and also that the leaners' proficiency correlates with the increase of speaking rate regardless of speech rate categories. More importantly, faster speech rate values found in the advanced level of learners do not necessarily match to the native speakers' speech rate categories. This means that learning speech rate categories can be more complex than we think of proficiency or fluency. That is, speech rate categories may not be acquired automatically during the course of second language learning, and implicit or explicit exposures to various rate types are necessary for second language learners to acquire a high level of communicative skills including speech rate variation. This paper discusses several pedagogical implications in terms of teaching pronunciation to second language learners.

Preparation of Gold-Peptide Hybrid Nanoparticles and Its Applications in Catalytic Reduction of Methylene Blue (금-펩타이드 하이브리드 나노입자의 제조와 메틸렌 블루의 촉매 환원 응용)

  • Hur, Yun-Mi;Min, Kyoung-Ik
    • Applied Chemistry for Engineering
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    • v.32 no.2
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    • pp.163-167
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    • 2021
  • In the present work, we studied a method for the synthesis of uniform gold-peptide hierarchical superstructures using tyrosine rich peptide, Tyr-Tyr-Leu-Tyr-Tyr (YYLYY). Peptide nanoparticles self-assembled by dityrosine bonds were synthesized through the photo-crosslinking reaction of the peptide, and gold-peptide hybrid nanoparticles were synthesized using biomineralization properties of tyrosine in a green synthetic manner. The synthesized gold-peptide hybrid nanoparticles were then characterized by transmission electron microscopy, scanning electron microscopy, dynamic light scattering, UV-vis spectroscopy, scanning transmission electron microscopy-energy dispersive X-ray spectroscopy, and X-ray diffraction. Furthermore, the catalytic activity of gold-peptide hybrid nanoparticles was confirmed by the reduction reaction of methylene blue where the catalytic reaction rate constant was 13.4 × 10-3 s-1.