• Title/Summary/Keyword: 초기경화시간

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Effects of Temperature on Diacylglycerol Production by Enzymatic Soli-Phase Glycerolysis of Hydrogenated Beef Tallow (온도조절이 고상계에 경화우지로부터 디글리세리드의 효소적생산에 미치는 영향)

  • Kang, Sung-Tae;Yamane, Tsuneo
    • Korean Journal of Food Science and Technology
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    • v.26 no.5
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    • pp.567-572
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    • 1994
  • Diglyceride was prepared by reaction of hydrogenated beef tallow and glycerol (GL) in the presence of a Pseudomonas lipase. Both substrates were mixed at the ratio of GL/Triglyceride of 0.5 which is the stoichiometric molar ratio for the complete conversion of triglyceride (TG) to diglyceride (DG). DG can be obtained by solid phase-glycerolysis of hydrogenated beef tallow without use of organic solvents or emulsifiers by careful control of reaction temperature. Optimized reaction temperature condition was as follows: An initial incubation at$60^{\circ}C$ for 2h followed by the first temperature shift down to $55^{\circ}C$ for 4h, and then the second shift down to $50^{\circ}C$ for up to 3 days. There was a large decrease in the content of TG during the first $60^{\circ}C$ incubation for 2h. Even a prolonged incubation at $60^{\circ}C$ could not make a change of the composition of the reaction mixture at liquid state. By controlling the temperature lower than $60^{\circ}C$, reaction mixtures were solidified. The reaction temperature at $50^{\circ}C$ below the melting temperature of hydrogenaed beef tallow gave an 71% optimum yield of DG after 72h enzymatic glycerolysis and about 73% of total DG was 1,3-DG.

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Analysis of mixing ratio of lacquer and glue for lacquer drying in low relative humidity environment (상온저습 환경에서의 옻의 건조를 위한 옻과 교의 배합 분석 연구)

  • Kim, Eun-Kyung;Jeong, Se-Ri;Yu, Jae-Eun
    • 보존과학연구
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    • s.32
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    • pp.37-52
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    • 2011
  • This study investigates the hardening characteristics of the mixture lacquer and glue at room temperature. Diverse samples were made from manufacturing of glue to the adding ratio in sap of the lacquer tree. After the examination of moisture content of samples, it has been seen that there is no relation with glue's kinds or adding ratio, but only with contain level of moisture. The samples made with film shape in order to examine the drying time. Samples with isinglass needed for over three days and had smooth surface. However, samples mixed with animal glue dried within a day and had ripples on the surface because of fast drying rate. In addition, the samples with isinglass had slow change of colour in early step of drying and no colour difference after completely drying although it had significant changes to black oxide as soon as contact with air. In structural analysis with FT-IR showed that the carbonyl bond increased in the samples of mixed with glue, compared to raw lacquer and treated lacquer.

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Effect of Cement Contents and Combinations of Accelerators on Strength Development of Concrete Cured at 10℃ (10℃ 양생조건에서 단위 시멘트량 변화 및 경화촉진제의 복합사용에 따른 강도발현 성능에 관한 연구)

  • Song, Young-Chan;Lee, Tea-Gyu;Kim, Yong-Ro;Seo, Chi-Ho
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.2
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    • pp.94-99
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    • 2018
  • The purpose of this study is to investigate the effect of combinations of different accelerators mixed on the early age strength development of concrete of 21 to 27MPa in the curing temperature of $10^{\circ}C$ compared with existing early strength agent. The present study was assessed the early strength development of combinations of three different accelerating admixtures with early strength type agent comparing to single accelerating admixture with early strength type agent. As a result of this study, the effect of $CaBr_2+NaSCN+DEA$ combination on strength development showed better than $CaBr_2$ or NaSCN alone with early strength type agent. Therefore, we observed that concrete using $CaBr_2+NaSCN+DEA$ combination with early strength agent was achieved 5MPa 12hours earlier than use of $CaBr_2$ or NaSCN alone.

Estimation of Transient Creep C(t)-integrals for SE(B) Specimen Under Elastic-Plastic-Creep Conditions (탄성-소성-크리프 상태에서 SE(B) 시편의 천이크리프 C(t)-적분 평가)

  • Lee, Han-Sang;Je, Jin-Ho;Kim, Dong-Jun;Kim, Yun-Jae
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.9
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    • pp.851-857
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    • 2015
  • In this paper, we estimate the time-dependent C(t) integrals under elastic-plastic-creep conditions. Finite-element (FE) transient creep analyses have been performed for single-edge-notched-bend (SEB) specimens. We investigate the effect of the initial plasticity on the transient creep by systematically varying the magnitude of the initial step load. We consider both the same stress exponent and different stress exponents in the power-law creep and plasticity to elastic-plastic-creep behavior. To estimate the C(t) integrals, we compare the FE analysis results with those obtained using formulas. In this paper, we propose a modified equation to predict the C(t) integrals for the case of creep exponents that are different from the plastic exponent.

Exercise Prescription and Dietary Modification for Prevention and Treatment of Chronic Degenerative Disease II. On Arteriosclerosis and Hypertension (성인병의 예방과 치료를 위한 영양과 운동처방 II. 고혈압과 동맥경화에 미치는 영향)

  • 백영호
    • Journal of Life Science
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    • v.9 no.2
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    • pp.231-240
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    • 1999
  • Regular exercise is effective in preventing coronary disease such as angina pectoris and infarction, inside it can lower the blood pressure and aids in weight control and release of stress. Risk factors of arteriosclerosis is hypertension, hyperlipidemia, diabetes, obesity, physical inactivity and excessive smoking. Arteriosclerosis begins at young age worsens with age, particulary in male. For people with risk factors of arteriosclerosis, it is important to prevent arteriosclerosis-related disease with dietary, living pattern and exercise prescription. Dietary fibers promote exercise of the digestive tract and shortens the time food remains inside the digestive tract. It can prevent obesity, hyperlipidemia, arteriosclerosis and colin cancer by blocking the absorption of cholesterol. Various vegetables and sea foods are lichen unsaturated fats and prevent the absorption of cholesterol inside the digestive tract. Essential fatty acids and unsaturated fats which are contained in vegetable oils, promotes metabolism while preventing absorption. In fruits, pectin water-soluble fiber, is present and lowers the level of cholesterol. By consuming foods that low in cholesterol and saturated fats, and rich in unsaturated fats, aliomentotherapy alone can reduce the plasma cholesterol by 10~l5$\%$. For ideal exercise, it should be aerobic with intensity of 60~80$\%$ HRmax, duration of 15~60min/day. The frequancy of 3~6/week is desirable the better exercise prescription is endurance aerobic exercise. To get more effect exercise, exercise consistency is very important.

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Characteristics of Salt Adsorption by Calcium Alginate Beads (칼슘알긴산비드에 의한 염분의 흡착특성)

  • 방병호;서정숙
    • The Korean Journal of Food And Nutrition
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    • v.15 no.2
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    • pp.89-96
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    • 2002
  • The adsorption characteristics of sodium chloride into Ca-alginate beads have been investigated and the result were as follows: Sodium chloride uptake by Ca-alginate beads increased with time. The highest uptake volume of sodium chloride was 4.2g after 10 minutes. The uptake volume by Fe, Ca, Ba, and Sr-alginate beads was 5.6g, 4.2g, 4.2g and 4.0g, respectively but in case of Fe-alginate beads, the induced hydrogel beads were very fragile and the strength of Fe-alginate beads were weaker than Ca- and Ba-alginate beads. Mg-alginate bead was not formed and Ca-, Ba- and Sr-alginate beads had a similar uptake volume about 4.2g, respectively. The uptake volume of sodium chloride by CaCl$_2$concentration(0.1M. 0.2M and 1M), curing solution, was 4.8, 4.2g and 4.1g, respectively. The uptake volume by sodium alginate concentration(0.6%, 1% and 2%) was 2.8g, 4.0g, and 4.4g, respectively and Ca-alginate bead size was not effected in uptake sodium chloride. The uptake rate on initial sodium chloride concentration(4%, 8%, 12% and 16%) was 30%, 28%, 27% and 25%, respectively. The uptake rate on basic pH(10.0) was higher than when compared to other neutral pH(6.8) and acidic pH(4.0). The initial uptake velocity of sodium chloride from immobilization beads with salt resistant bacteria was lower than that of non-immobilization beads. The uptake rate of sodium chloride was decreased according to elongation of curing time. Reusability of Ca-alginate beads was possible but according to reutilization, the salt uptake volume of beads was also decreased. The uptake volume of sodium chloride from Doengjang by Ca-alginate beads on time course(3, 6, 12, and 24 hour) was revealed 5g, 6g, 7g and 7g, respectively.

Study on Correlation between Compressive Strength and Compressional Wave Velocity for CLSM According to Curing Time (양생시간에 따른 CLSM의 압축강도 및 압축파 속도 상관성 연구)

  • Han, Woojin;Lee, Jongsub;Cho, Samdeok;Kim, Jinhwan;Byun, Yonghoon
    • Journal of the Korean GEO-environmental Society
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    • v.16 no.11
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    • pp.5-11
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    • 2015
  • The development of Controlled Low Strength Material (CLSM), which is a highly flowable material, has been performed for the application of backfill. The objective of this study is to compare the compressive strength and compressive wave velocity of CLSM according to the curing time. To investigate the characteristics of the CLSM consisting of sand, silt, water, flyash, and CSA cement, uniaxial compression test and flow test were carried out. For the measurement of compressional waves, a cell and a couple of transducers were used. The test results show that the compressive strength increases with the curing time, while the increment of compressive strength decreases with the curing time. In addition, the compressive wave velocity increases with the curing time, and the correlation between the compressive wave velocity and compressive strength is similar to exponential function. This study suggests that the correlation between the compressive wave velocity and compressive strength may be effectively used for the estimation of compressive strength of the CLSM at early curing time.

A Study on the Character of Concrete compressive strength according to Bottom-Ash and Internal gap for Crack aspect predictions (Bottom-Ash를 활용한 콘크리트 압축강도와 내부 공극 특성 분석 및 균열양상 예측)

  • Jung, Woo-Young;Sim, Young-Hwan;Lee, Sang-Moon;Choi, Hyun-Kyu
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.713-716
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    • 2008
  • In about the concrete application which recycles Ash the research came to be advanced as research in compliance with researchers relation actively in about cement substitutional concrete mixing ratio and burglar quality of existing. The research which it sees as fundamental research the research which it follows in cement substitutional concrete mixing ratio of existing and it researched different Bottom-Ash recycling qualities in about cup aggregate partial substitution Bottom-Ash application.

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Fundamental Properties of Magnesia-Prosphate Composite Considering Mix Conditions and Curing Temperature (배합조건 및 양생온도에 따른 마그네시아 인산염 복합체의 기초물성 평가)

  • Cho, Hyun Woo;Kang, Su Tae;Shin, Hyun Seop;Lee, Jang Hwa
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.6
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    • pp.163-170
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    • 2012
  • With the advantage of a rapid exothermic reaction property, jet set concrete may be used as a cold weather concrete because it can reach the required strength before being damaged by cold weathers. And it can be hardened more quickly if the field temperature is properly compensated by heating. Because ordinary concrete cannot be hardened well under sub-zero temperatures, anti-freeze agents are typically added to prevent the frost damage and to ensure the proper hardening of concrete. While the addition of a large amount of anti-freeze agent is effective to prevent concrete from freezing and accelerates cement hydration resulting in shortening the setting time and enhancing the initial strength, it induces problems in long-term strength growth. Also, it is not economically feasible because most anti-freeze agents are mainly composed of chlorides. Recent studies reported that magnesia-phosphate composites can be hardened very quickly and hydrated even in low temperatures, which can be used as an alternative of cold weather concrete for cold weathers and very cold places. As a preliminary study, to obtain the material properties, mortar specimens with different mixture proportions of magnesia-phosphate composites were manufactured and series of experiments were conducted varying the curing temperature. From the experimental results, an appropriate mixture design for cold weathers and very cold places is suggested.

Study on Characteristics of Controlled Low Strength Material Using Time Domain Reflectometry (시간영역반사법을 이용한 유동성 채움재의 특성 연구)

  • Han, Woojin;Lee, Jong-Sub;Byun, Yong-Hoon;Cho, Samdeok;Kim, Juhyong
    • Journal of the Korean GEO-environmental Society
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    • v.17 no.4
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    • pp.33-37
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    • 2016
  • The hydration process of Controlled Low Strength Material (CLSM) used for backfill is the primary factor to determine the construction period. The objective of this study is to monitor the hydration process of CLSM using the Time Domain Reflectometry (TDR) and to establish the relationship between dielectric constant and compressive strength. The CLSM specimen is composed of cement, flyash, silt, sand, accelerator, and water. The material characteristics of the CLSM including flow, unit weight, compressive strength are investigated. To measure the dielectric constant of the CLSM during the curing time, TDR probe incorporated with a mold and a reflectometer are used. Experimental results show that the dielectric constant remains constant at early stage, and then decreases as the curing time increases. In addition, the dielectric constant is related to the compressive strength in inverse power function. This paper suggests that the TDR technique may be used as a non-destructive testing method in order to estimate the compressive strength of the CLSM mixture under construction.