• Title/Summary/Keyword: 체적 함유비

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Evaluation of Oil Infiltration Behavior in Porous Media Using Dielectric Response (유전율에 의한 지반 매질내 유류침투거동 분석)

  • Kim Man-Il;Jeong Gyo-Cheol
    • The Journal of Engineering Geology
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    • v.15 no.1
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    • pp.29-39
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    • 2005
  • For detecting a ground contamination survey, soil sampling method have been used a drilling or coring technique in general. However these methods are very difficult to systematically real-time monitoring of variation of contamination degree in field. ]'n this research frequency Domain Reflectometry (FDR) system was suggested and carried out to experimental approaches for determination of oil contamination on surface and underground. Experimental method using FDR method was discussed with feasibility of measurement in the laboratory column test. It is determined to degree of oil contamination due to response of dielectric constant re-lated with volumetric water content(θ/sub w/) and volumetric oil content( θ/sub al/ ) of saturated and unsaturated soil media. And physical properties such as effective porosity and oil residual ratio of saturated soil media were also measured through real-time monitoring works using installed FDR measurement sensors, which are defected characteristics of oil movement in the saturated soil media under the soil column tests. In the results of these experiments, a range of effective porosity was estimated to about 0.35 compared with initial porosity 0.40 of manufactured saturated soil media, which is also calculated to about 87.5% to the ratio of initial porosity to effective porosity. Finally oil residual ratio which is compared with volumetric water content and volumetric oil content was calculated about 62.5%.

Effect of Experimental Factors on Reduction of Nitrogen Compounds Contained in Crude Methylnaphthalene Oil by Formamide Extraction (포름아미드 추출에 의한 조제 메틸나프탈렌유에 함유된 질소화합물의 저감에 관한 실험인자의 영향)

  • Su Jin Kim
    • Applied Chemistry for Engineering
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    • v.34 no.6
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    • pp.665-669
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    • 2023
  • The crude methylnaphthalene oil (CMNO) contains nitrogen compounds (NCs) such as quinoline (QU), isoquinoline (IQU), and indole (IN). These NCs in the CMNO are treated as impurities contained in the CMNO due to contamination of the atmospheric environment and unpleasant odors. In order to improve the quality of CMNO, this study examined the effect of extraction experimental factors on the reduction of NCs contained in CMNO using CMNO as a raw material and an aqueous formamide solution as a solvent, respectively. The increase in the volume ratio of solvent to feed in initial (S/F)0 in initial increased the distribution coefficient of NCs and the selectivity of NCs in reference to 2-methylnaphthalene (2MNA). Additionally, an increase in operating temperature (T) increased the distribution coefficient of NCs but conversely decreased selectivity. The compositions of QU, IQU, and IN in the raffinate oil recovered through equilibrium extraction under a constant condition (volume fraction of water to solvent in initial (yw,0) = 0.1, (S/F)0 = 9, T = 303 K, liquid-liquid contacting time = 72 h) were reduced by about 58.5 wt%, 61.9 wt%, and 73.4 wt%, respectively, compared to those of CMNO. The formamide extraction method in this study was expected to be an effective reduction method for NCs contained in CMNO.

A Study on the Geotechnical Property caused by Contact Volume between Weathered Soils and Moisture Sensor for Application of Field Monitoring (현장 모니터링 적용을 위한 풍화토와 함수비센서의 접촉체적에 따른 지반물성 연구)

  • Kim, Man-Il;Chae, Byung-Gon
    • The Journal of Engineering Geology
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    • v.18 no.3
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    • pp.311-319
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    • 2008
  • Evaluation of an amplitude domain reflectometry (ADR) type soil moisture sensor as ThetaProbe ML2x using the response of frequency impedance was performed in a variety of soil porous media such as Jumunjin standard sand, weathered granite soil at Sangju area, and weathered gneiss soil at Jangsu area. The tested soils were classified with a dried condition and a wetted condition for comparing with soil volumetric water content under different installed depths of the measurement sensor. In the results the part of measurement rod including one signal rod and three shield rod 6cm in length was found to decrease the variation of measurement output voltage with insert 5cm over into the soil porous media. The measurement output voltage was verified to more stable output voltage under weathered granite soils and weathered gneiss soils contained the fine grain materials such as clay and silt minerals than the gradual grain material like as the standard sands. Therefore, measurement values by soil moisture sensor can be offered the more stable values when an contact volume between soil porous media and measurement sensor increase.

Experimental Study on Reduction of Nitrogen-Containing Compounds Contained in Crude Methylnaphthalene Oil by Solvent Extraction (II) (용매 추출에 의한 조제 메틸나프탈렌유에 함유된 함질소화합물의 저감에 관한 실험적 연구(II))

  • Kang, Ho-Cheol;Kim, Su Jin
    • Applied Chemistry for Engineering
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    • v.33 no.5
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    • pp.477-481
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    • 2022
  • As a part of improving the quality of crude methylnaphthalene (CMNO), this study was experimentally examined the reduction of nitrogen-containing compounds (NC) present in the CMNO by solvent extraction. The CMNO was composed of three kinds of NC [quinolone (QU), iso-quinoline (IQU), indole (IN)], three kinds of bicyclic aromatic compound [BAC; naphthalene (NA), 1-methylnaphthalene (1MNA), 2-methylnaphthalene (2MNA)] and biphenyl (BP) etc., in addition to an aqueous formamide solution, which were used as raw materials and a solvent, respectively. The increase in the volume fraction of water to the solvent in the initial state (yw,0) caused a sharp decrease in the distribution coefficient and the yield of NC, but conversely raised the increased selectivity of NC based on 2MNA. The compositions of QU, IQU and IN in the raffinate oil recovered through the equilibrium extraction of batch co-current 5-stage under constant conditions [yw,0 = 0.1, volume fraction of solvent to feed (CMNO) at the initial state = 1, operating temperature = 303 K, liquid-liquid contacting time = 72 h] were reduced by about 51.5%, 55.2%, and 71.8%, respectively, when compared to those of CMNO. From the excellent reduction rate of NC, the formamide extraction method suggested in this study can be expected to be a useful reduction method for NC contained in the CMNO.

Experimental Investigation on Relationship of Winding Process Variables and Mechanical Properties for Filament Wound Composites (필라멘트와인딩 복합재의 기계적 특성과 와인딩시 공정변수와의 관계에 대한 실험적 고찰)

  • 윤성호;김준영;황태경
    • Journal of the Korean Society of Propulsion Engineers
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    • v.3 no.2
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    • pp.56-65
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    • 1999
  • The relationship of the winding process variables and the mechanical properties of filament wound composites is investigated experimentally. The winding process variables considered are the fiber tensions and the fiber ends. The filament wound ring specimens are fabricated using 3-axis controlled filament winding machine. Two types of carbon fibers, TZ-507 and IZ-40, are used as reinforcements and epoxy for filament winding is used as resin. During the winding process, the fiber tensions are varied from 0.5kgf to 3.0kgf, and the number of the fiber ends are varied from 1 to 6. The fiber volume fractions and the void contents for the ring specimens are measured through the resin digestion. The mechanical properties of the ring specimens are also evaluated by the split disk test. The test results show that the winding process variables affect the fiber volume fractions and the void contents of the ring specimens, which result in the variation of the tensile properties of the ring specimens. Therefore, suitable winding process variables should be applied to maximize the structural performance and the productivity for filament wound structures.

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Development of Numerical Model for Mixed Soil Problems Using Dry Bulk Density and Investigation of Its Numerical Stability (건조체적밀도를 적용한 혼합토사 수치모델의 개발과 수치적 안정성 평가)

  • Cho, Yong-Hwan;Lee, Kwang-Ho
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.33 no.3
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    • pp.110-121
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    • 2021
  • The importance of tidal flats lost due to industrialization has recently received attention, and attention is being paid to the creation of artificial tidal flats and maintenance of natural tidal flats. However, there is still a lack of understanding about the behavioral characteristics of mud, mud, and sand that form tidal flats. Although research on the movement characteristics of mixed soils such as tidal flats has been conducted through field investigations and hydraulic experiments, interest in developing a numerical model based on these results has not yet reached. In this paper, the purpose of this paper is to establish a mixed soil model that can efficiently manage the low quality of the tidal flats. In constructing a model for reproducing the surface movement of mixed soil, the numerical stability of the reproduction and movement of sand and mud constituting the mixed soil in the numerical model should be considered first, so first, the volume of sand and mud constituting the mixed soil A mixed soil model representing the relationship was proposed based on a topographical diagram representing the geometric structure of the mixed soil. In order to consider the dry bulk density of the mixed soil, it was possible to consider the dry bulk density of the mud by introducing the water content of the mud containing water. In addition, it was confirmed that the mud and sand movement calculation according to the slope collapse of the mixed soil was stably performed through the calculation of the slope collapse of the mixed soil through the numerical analysis model to which the proposed mixed soil model was applied.

Reinforcing Characteristics on Volume and Shape of Ductile Short-Fiber in Brittle Matrix Composites (취성기지 복합재료에서 연성 단섬유의 함유량 및 형상에 관한 보강특성)

  • Sin, Ik-Jae;Lee, Dong-Ju
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.1 s.173
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    • pp.250-258
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    • 2000
  • The reinforcing effects of ductile short-fiber reinforced brittle matrix composites are studied by, measuring flexural strength, fracture toughness and impact energy as functions of fiber volume fraction and length. The parameters of fracture mechanics, K and J are applied to assess fracture toughness and bridging stress. It is found that fracture toughness is greatly, influenced by the bridging stress ill which fiber pull-out is occur. For the reinforcing effects as functions of fiber volume fraction($V_f$ = 1, 2, 3 %) and length(L = 3, 6. 10cm), the flexural strength is maximum at $V_f$ = 1% and both fracture toughness.

Effects of Elastic Modulus Ratio on Internal Stresses in Short Fiber Composites (단섬유 복합체에서 탄성계수비가 내부응력에 미치는 영향)

  • 김홍건;노홍길
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.13 no.4
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    • pp.73-78
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    • 2004
  • The conventional SLT(Shear Lag Theory) which has been proven that it can not provide sufficiently accurate strengthening predictions in elastic regime when the fiber aspect ratio is small. This paper is an extented work to improve it by modifying the load transfer mechanism called NSLT(New Shear Lag Theory), which takes into account the stress transfer across the fiber ends and the SCF(Stress Concentration Factor) that exists in the matrix regions near the fiber ends. The key point of the model development is to determine the major controlling factor among the material and geometrical coefficients. It is found that the most affecting factor is the fiber/matrix elastic modulus ratio. It is also found that the proposed model gives a good result that has the capability to correctly predict the elastic properties such as interfacial shear stresses and local stress variations in the small fiber aspect ratio regime.

Characterization of Weathered Zone bearing Corestones through Scale Model Test (실내모형실험에 의한 핵석 풍화대 지반 특성 산정)

  • Woo, Ik
    • The Journal of Engineering Geology
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    • v.17 no.3
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    • pp.435-443
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    • 2007
  • This study shows the prediction of the engineering properties of weathered zone bearing corestones through the engineering geological surveys and the scale model test in the laboratory. The window survey and the observation on the borehole core were peformed on three natural slopes in corestones area in order to analyse the distribution pattern and the geometrical properties of corestones. Natural corestones were crushed and abrased for the scale model test into less than 5 mm in maximum-2mm in average by the scale reduction ratio based on the size of natural corestones and the specimen size. Scale model tests were carried out on soil and plaster model specimens with different corestone content ratio - 0%, 10%, 20%. The direct shear test on soils shows that shear strength is increased by the increase of corestone content ratio. The increase of cohesion is, however, more important factor to the shear strength of soil for 20% corestone content ratio due to interlocking of crushed corestone particles. The plaster model test shows a tendance of increase of UCS and modulus of elasticity with increase of corestone content. The variation ratio of specimen property by change of corestone content ratio in plaster model test was applied to in situ properties in order to estimate the properties of weathered zone bearing corestones. So it could be predicted that the increase of corestone content to 10% and to 20% produce about 18% and 30% UCS's increase respectively.

Unsaturated Soil-Water Characteristics Curve with Silt Contents for Nak-Dong River Sand (실트함유율에 따른 낙동강 모래의 불포화 함수특성곡선)

  • Moon, Hongduk;Kim, Daeman
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.2
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    • pp.23-33
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    • 2011
  • In this paper, we got soil-water characteristic curve(SWCC) of Nak-Dong River's sand respectively as relative density 40%, 60%, 80% and content of silt 0%, 10%, 20%, 30%. As a result, the more the sand densify in the same silt content and the more the sand has silt in the same relative density, the change of volume water content was decreased. we have known effect of silt contents for SWCC and verified existing empirical formula of SWCC. As experiment results of soil-water characteristic curves compared to the empirical solutions, the results of van Genuchten(1980) and Fredlund & Xing(1994) were well-matched showing S type curves with experiment results. Especially the empirical solution of Fredlund & Xing showed almost same results of the coefficient of correlation($R^2$) equal to 0.99.