• Clean Technology
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• v.30 no.1
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• pp.23-27
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• 2024

Bismuth is a promising anodic for Li-ion batteries (LIBs) due to its adequate operating voltage and high-volume capacity (3,765 mAh cm^-3). Nevertheless, inevitable volume expansion during Bi alloy reactions leads to severe capacity loss and cell destruction. To address this, a complex of bismuth alloy nanoparticles (Bi@NC) embedded in an N doping-carbon coating is fabricated via a simple pyrolysis method. Nano-sized bismuth alloys can improve the reaction dynamics through a shortened Li⁺-ion diffusion path. In addition, the N-doped carbon coating effectively buffers the volume change of bismuth during the extended alloy/dealloy reaction with Li⁺ ions and maintains an effective conductive network. Based on the Thermogravimetric analysis (TGA) showed high bismuth alloy loading (80.9 wt%) and maintained a high gravimetric capacity of 315 mAh g^-1 up to 100 cycles with high volumetric capacity of 845.6 mAh cm^-3.

• Journal of the Korea Concrete Institute
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• v.18 no.3 s.93
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• pp.331-338
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• 2006

This paper presents the experimental results on volumetric changes in ordinary portland cement concrete made with various water-to-cement ratios(W/C's) ranging from 0.32 to 0.50 and cured in low different conditions. Curing regimes employed in this work were designed to exhibit autogenous and drying shrinkage as well as swelling of concrete. The concrete avoided any moist evaporation(Regime f showed only autogenous shrinkage and the lower the W/C, the feater the autogenous shrinkage. The concrete exposed to air drying conditions at $20{\pm}1^{\circ}C$ and $60{\pm}3%$ RH after 6-day water curing at $20{\pm}1^{\circ}C$(Regime II) swelled and then started to shrink. The maximum swelling value of concrete developed in water curing was between 15 and $40{\pm}10^{-6}$, and the greatest total shrinkage(autogenous+drying shrinkage) was obtained for the mixture made with W/C of 0.32. The concrete let to air drying conditions(Regime III) showed greater total shrinkage compared to the concrete cured in Regime II. The concrete exposed to air drying condition after 6-day sealed curing(Regime IV) exhibited slightly smaller total shrinkage than that of the concrete cured in Regime III. Net drying shrinkage that can be derived from the results of Regime I, III, and IV increased as the W/C increased despite of similar total shrinkage. This result indicated that drying shrinkage governs total shrinkage of high-W/C concretes. In other words, a portion of autogenous shrinkage in total shrinkage increased in low-W/C concretes. Therefore, it should be controlled in terms of cracking potential. Finally, total shrinkage of high-strength and high-performance concrete made with low W/C can be effectively reduced by appropriate early moisture curing.

• Journal of the Korean Electrochemical Society
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• v.18 no.2
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• pp.68-74
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• 2015

To compare the microstructure and electrochemical properties between two binary alloys (Cr-Si, Ni-Si), two composition of binary alloys with the same capacity were selected using phase-diagram and prepared by matrix-stabilization method to suppress the volume expansion of Si by inactive-matrix. Master alloys were made by Arc-melting followed by fine structured ribbon sample preparation by Rapid Solidification Process (RSP, Melt-spinning method) under the same conditions. Also powder samples were produced by wet grinding for X-Ray Diffraction (XRD) and electrochemical measurements. As predicted from the phase diagram, only active-Si and inactive-matrix ($CrSi_2$, $NiSi_2$) were detected. The results of Scanning Electron Microscope (SEM) and Transmission Electron Microscopy - Energy Dispersive X-ray Spectroscopy (TEM-EDS) show that Cr-Si alloy has finer microstructure than Ni-Si alloy, which was also predictable through phase diagram. The electrochemical properties related to microstructure were evaluated by coin type full- and half-cells. Separately, self-designed test-cells were used to measure the volume expansion of Si during reaction. Volume expansion of Cr-Si alloy electrode with finer microstructure was suppressed significantly and improved in cycle capability, in comparison Ni-Si alloy with coarse microstructure. From these, we could infer the correlation of microstructure, volume expansion and electrochemical degradation and these properties might be predicted by phase diagram.

• Tunnel and Underground Space
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• v.29 no.4
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• pp.262-279
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• 2019

In the engineering barriers of high-level radioactive waste disposal, gases could be generated through a number of processes. If the gas production rate exceeds the gas diffusion rate, the pressure of the gas increases and gases could migrate through the bentonite buffer. Because people and the environment can be exposed to radioactivity, it is very important to clarify gas migration in terms of long-term integrity of the engineered barrier system. In particular, it is necessary to identify the hydro-mechanical mechanism for the dilation flow, which is a very important gas flow phenomenon only in medium containing large amounts of clay materials such as bentonite buffer, and to develop and validate new numerical approach for the quantitative evaluation of the gas migration phenomenon. Therefore, in this study, we developed a two-phase flow model considering the mechanical damage model in order to simulate the gas migration in the engineered barrier system, and validated with 1D gas flow modelling through saturated bentonite under constant volume boundary conditions. As a result of numerical analysis, the rapid increase in pore water pressure, stress, and gas outflow could be simulated when the dilation flow was occurred.

• Journal of the Korean Geotechnical Society
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• v.30 no.6
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• pp.5-21
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• 2014

It has been pointed out that the collapses of unsaturated road embankments caused by earthquake are attributed to high water content caused by the seepage of the underground water and/or the rainfall infiltration. Hence, it is important to study influences of water content on the dynamic stability and deformation mode of unsaturated road embankments for development of a proper design scheme including an effective reinforcement to prevent severe damage. This study demonstrates dynamic centrifugal model tests with different water contents to investigate the effect of water content on deformation and failure behaviors of unsaturated road embankments. Based on the measurement of displacement, the pore water pressure and the acceleration during dynamic loading, dynamic behavior of the unsaturated road embankments with about optimum water content and the higher water content than the optimum one have been examined. In addition, an image analysis has revealed the displacement field and the distributions of strains in the road embankment, by which deformation mode of the road embankment with higher water content has been clarified. It has been confirmed that in the case of higher water content the settlement of the crown is large mainly owing to the volume compression underneath the crown, while the small confining pressure at the toe and near the slope surface induces large shear deformation with volume expansion.

• Land and Housing Review
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• v.8 no.4
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• pp.249-256
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• 2017

Urbanization can be remarkable affected flood, pollutant loading, ecological system, and green infrastructure by distortion of hydrologic cycle. In order to mitigate these problems in urban, Low Impact Development(LID) technique has been introduced and applied in the world. SWMM model was calibrated with sets of field monitoring data and applied for calculation of runoff and pollutant loading in Asan-tangjung LID city under 2016 rainfall. Runoff reduction of watershed and catchment basins were showed efficiency 12.2% and 62.0%, respectively. Reduction of COD and TP loading also high efficiency in catchment basins were evaluated 74.9 and 71.4%. The results of this study can be used effectively in decision making processes of urban development project by comparing watershed runoff and pollutant reduction by designs of sort of LID technique, LID volume and location.

• Computational Structural Engineering
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• v.3 no.2
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• pp.89-95
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• 1990

As modern industry go further, a rigid concrete pavement has been widely constructed. The load carrying capacity of the flexible asphalt pavements is brought about by a layered system, distributing the load over the subgrade, rather than by the bending action of the slab. On the other hand, the rigid pavement, because of its rigidity and high modulus of elasticity, tends to distribute the traffic load over wide subbases, and its capacity of the strength is supplied by the slab itself. Thus, it is necessary to study the structural behavior of concrete slab under the variations of temperature changes and applied traffic loads. It reguires the development of finite element analysis program for the concrete highway pavement, which provides better understanding of concrete pavement behavior and effective design data to highway engineers.

• Transactions of the Korean hydrogen and new energy society
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• v.17 no.1
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• pp.1-7
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• 2006

The free-piston hydrogen fueled engine is estimated as the next generation power system which can obtain high efficiency and low emission, simultaneously. In order to develop the free-piston hydrogen fueled engine, it is necessary to stable the combustion. The engine combustion, backfire and knock phenomenons were studied by using RICEM for researching combustion characteristics of free-piston engine. As the results, backfire occurrence was not observed in the free-piston engine under limited experimental condition. And knocking occurred in case of higher cylinder wall temperature.

• Journal of Energy Engineering
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• v.12 no.1
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• pp.29-34
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• 2003

Thermo-acoustic waves can be generated in a compressible fluid by rapid heating and cooling near the boundary walls. These phenomena are very important mechanism of heat transfer in the space environment in which natural convection does not exist. In this study, the generation and transmission characteristics of thermo-acoustic waves in an air filled enclosure with rapid wall heating are studied numerically. The governing equations were discretized using control volume method, and were solved using PISO algorithm and second-order upwind scheme. For the stable solution time step were considered as t=1$\times$$10^{-9}$ order, and grids are 50$\times$800. The induced thermo-acoustic wave propagates through the fluid until it decays due to viscous and heat dissipation. The wave showed sharp front shape and decreased with long tail.

• Proceedings of the Korean Geotechical Society Conference
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• 2004.03b
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• pp.348-355
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• 2004

본 연구에서는 geosynthetics로 보강된 다짐토의 보강 메카니즘을 파악하기 위한 목적으로 실내시험 및 수치계산 수행하였다. 본 연구에서 고려하는 보강 메카니즘은 전단에 의한 다짐토의 체적 팽창(부의 다일렌탄시)을 geosynthetics에 의해 구속 억제하는 과정에서 생성되는 효과로 생각한다. 먼저, 실내실험을 위한 구제직인 방법으로서, geosynthetics의 보강효과를 정량직으로 파악하기 위하여 사질토를 다짐하여 공시체를 만들어 그 주위에 geosynthetics를 설치하여 전체적으로 압축전단 시험을 실시하였다. 또한, 다짐토의 다짐도를 달리 하고 한 가지 종류만의 geosynthetics를 이용하여, 다짐토와 geosynthetics의 상호작용에 따른 압축력 변화, geosynthetics의 인장력 변화 및 공시체의 파괴 진행상황 등을 살펴보았다. 수치계산에서는 다짐토의 다일렌탄시 특성에 대하여 표현 가능한 탄소성 구성모델을 이용하였다. 또한, 탄소성 구성 모델에서의 항복 이전의 탄성영역의 거동을 묘사하기 위하여 Hashiguchi(1989)가 제안한 subloading surface의 개념을 도입하였고, 유한요소(FEM)해석을 통해 얻어진 결과들을 실내시험의 결과와 비교 분석하였으며, 그 결과 양자 양호한 결과를 얻었다.