• Journal of Korean Society of Environmental Engineers
• /
• v.28 no.8
• /
• pp.836-842
• /
• 2006

Pine needle samples(1 year, 2 year, 3 year old) were collected in Seoul and Ansung to investigate the deposition characteristics of atmospheric PCBs depending on exposure periods. Total PCBs concentration of pine needle samples in Seoul and Ansung showed 2,429, 1,198 pg/g DW(dry weight), respectively. PCB homologs concentration of pine needle samples decreased with increasing chlorine-substituted compounds. It showed that higher chlorine- substituted compounds in existing particle phase compared to lower chlorine-substituted compounds existing in gaseous phase were difficult to accumulate lipids of the pine needles samples. The results of regression analysis between exposure periods in the atmosphere and concentration of total PCBs measured in pine needles at two sites showed significant levels($R^2>0.94$, p<0.01), which implies that atmospheric PCBs accumulated on pine needles with positive linearity depending on exposure periods in this study. Therefore pine needle samples can be used as passive air sampler(PAS) for monitoring air contamination for a long time in different sites.

• Journal of Astronomy and Space Sciences
• /
• v.22 no.1
• /
• pp.13-20
• /
• 2005

Bound abrasive grinding is used for the initial fabrication phase of the precision aspheric mirrors for both space and ground based astronomical telescopes. We developed a new grinding optimization process that determines the input grinding variables for the target surface roughness, checks the grinding error magnitude in resulting surface roughnesses, and minimizes the required machining time. Using the machining data collected from the previous grinding runs and subsequently fed into the multivariable regression engine, the process has the evolving controllability that suggests the optimum set of grinding variables for each target surface roughness. The process model was then used for ten grinding experiments that resulted in the grinding accuracy of $=-0.906{\pm}3.38(\sigma)\;nm(Ra)$ for the target surface roughnesses of Zerodur substrate ranging from 96.1 nm (Ra) to 65.0 nm (Ra) The results imply that the quantitative process optimization technique developed in this study minimizes the machining time and offers the nanometric surface roughness controllability superior to the traditional, qualitative, craftsman based grinding process for the astronomical optical surfaces.

• Journal of Korean Society of Environmental Engineers
• /
• v.22 no.10
• /
• pp.1825-1832
• /
• 2000

Column experiments were conducted by using soil columns, to investigate feasibility and efficiency of in-situ ozone enhanced remediation for diesel-contaminated soil. The injection of gaseous ozone into soil column revealed the enhanced decomposition of ozone due to the catalytic reaction between ozone and metal (e.g., Fe, Mn etc.) oxides as evidenced by as much as 25 times shorter half-life of ozone in a sand packed column than in a glass beads packed column. Substantial retardation in the transport of and the consumption of ozone were observed in the diesel contaminated field soil and sand packed columns. After 16 hrs ozonation, 80% of the initial mass of diesel (as diesel range organic) concentration of $800{\pm}50mg/kg$, was removed under the conditions of the flow rate of 50mL/min and $6mg-O_3/min$. Whereas, less than 30% of diesel was removed in the case of air injection. Analysis of the residual TPH(total petroleum hydrocarbon) and selected 8 aliphatics of diesel compounds in the inlet and the outlet of the column confirmed that diesel nonselectively reacted with ozone and then shifted to lower carbon numbered molecules. Water content also was found to be an important parameter in employing ozone to the hydrocarbon-contaminated soil.

• Conservation Science in Museum
• /
• v.17
• /
• pp.69-84
• /
• 2016

Yuso is the term for decorative tassels of a braided string which hangs a scroll painting. This study, drawing on extant research concerning the yuso made for Joseon period portrait scrolls of kings and meritorious retainers, focuses on the yuso created to hang literati portraits. Concretely, It examines yuso of seven portraits in the collection of the National Museum of Korea in order to characterize their appearance and determine their material composition. The study found that most of the yuso are sixteen-strand strings braided into a rounded cross-section(dongdahoe). The seven yuso, of which six are red and one indigo-blue, reflect the popular style associated with Joseon period literati portraits. The yuso for the portrait of Yun Geup(duksu 3503) is made from gilded paper. Analysis showed Fe particles present in a red pigment underlying the gold layer, suggesting the presence of red ochre(seokganju), an iron oxide mineral. The yuso of the portrait of Shin Im(duksu 4846) is used a paper which contains gold as well as traces of Pb, Hg and Ag. The paper in the yuso for the portrait of Yi Seongwon(bongwan 10122) mainly consisted of Ag, indicating silver paper having been used in its fabrication. The inner paper in the yuso of the portrait of Yi Seogu(sinsu 1065) is a leather combined with Ag, Fe, and Br, according to chemical analysis. The FTIR of the leather sample reveals that the spectrum in the fingerprint region is nearly identical to that of sheepskin, indicating the yuso was made from gold-coated sheepskin.

• Journal of the Korean Magnetics Society
• /
• v.17 no.2
• /
• pp.60-64
• /
• 2007

Ba-Ferrite single crystals were prepared and characterized by X-ray, SEM and Mossbauer spectroscopy. The single crystal layers was cut in the c-axis and radiated to the surface by ${\gamma}-rays$ for Mossbauer spectroscopy. We found out that the spin states in Fe atoms were parallel to the ${\gamma}-rays$ direction. The temperature dependence of the hyperfine field is almost similar to that of powder samples. The crystal structure is a Magnetoplumbite without any other phases and the lattice parameters are found out with $a_0=5.892{\AA},\;b_0=5.892{\AA},\;c_0=23.198{\AA}$. $M\"{o}ssbauer$ spectrum in single crystal have 5 sets off absorption lines in each Fe site when the ${\gamma}-rays$ have the same radiation direction with the c-axis in the crystal, which mean that the whole crystal bulk formed only one crystal and same spin direction. The hysteresis curve shows the saturation moment and coercive force of 70.71 emu/g and 320 Oe respectively.

• Journal of the Microelectronics and Packaging Society
• /
• v.18 no.4
• /
• pp.39-42
• /
• 2011

The composite electroplating is accomplished by adding inert materials during the electroplating. Permalloy is the term for Ni-Fe alloy and it is used for industrial applications due to its high magnetic permeability, surface wear resistance, corrosion protection. Microhardness for microdevices is enhanced after composite coating and it increases the life cycle. However, the hydroxyl group on the silica makes their surface susceptible to moisture and it causes the silica nanoparticles to be agglomerated in the aqueous solution. The agglomeration problem causes poor dispersion which eventually interrupts uniform deposition of silica nanoparticles. In this study, the dispersion of silica nanoparticles in the permalloy electroplated layer is reported with variation of additives and current densities. The optimum current density was 20 $mA/cm^2$ and the silica content was 9 at% at $50^{\circ}C$. The amount of silica nanopowder codeposition and surface morphologies were influenced with variation of additives. In the bath, smooth surface morphology and relatively high contents of silica nanopowder codeposition were obtained with addition of sodium lauryl sulfate.

• Journal of the Korean Geosynthetics Society
• /
• v.17 no.2
• /
• pp.33-40
• /
• 2018

Characteristics of interface friction between cohesionless soils and geotechnical structure surfaces play an important role in the analysis of earth load and resistance on the structure. In general, geotechnical structures are mainly composed of either steel or concrete, and their surface roughnesses with respect to soil particle sizes influence the interface characteristics between soils and the structures. Accurate assessment of the interface friction characteristics between soils and structures is important to ensure the safety of geotechnical structures, such as mechanically stabilized earth walls reinforced with inextensible reinforcements, piles embedded into soils, retaining wall backfilled with soils. In this study, based on the database of high quality interface friction tests between frictional soils and solid surfaces from literature, equation representing peak interface friction angle is proposed. The influential factors of the peak interface friction angle are relative roughness between soil and solid surface, relative density of frictional soil, and residual (constant volume) interface friction angle. Futhermore, for the developed equation of the interface friction angle, its uncertainty was assessed statistically based on Goodness-of-fit test results.

• Journal of the Korean Geotechnical Society
• /
• v.29 no.8
• /
• pp.5-14
• /
• 2013

Coarse granular geomaterials containing large gravels are broadly used for construction of large geotechnical systems such as dams, levees, railways and backfills. It is necessary to evaluate deformation characteristics of these materials for dynamic analysis, e.g. seismic design. This study presents evaluation of dynamic deformation characteristics of coarse materials using large scale resonant column testing apparatus, which uses specimens with 200 mm in diameter and 400 mm in height, and the effects of gradation characteristics on maximum shear modulus, shear modulus reduction curve and damping characteristics were investigated. From experimental study using rock-fill materials for a dam, we could see that the largest or mean particle size affects the shape of shear modulus reduction curve. When the specimens are prepared under the same conditions for maximum particle size, the coefficient of uniformity affects the confining stress exponent of maximum shear modulus. It could be concluded that the maximum particle size is an factor which affects shear modulus reduction curve, and that the coefficient of uniformity is for small strain shear modulus, especially for the sensitivity to confining stress.

• Journal of the Korean Ceramic Society
• /
• v.34 no.2
• /
• pp.163-170
• /
• 1997

The retarding effects of MgSiF6.6H2O on the hydration of portland cement were studied. The setting time, flow value and compressive strength of mortar were measured and the mechanism of retardation was also studied by ion concentration in solution, SEM, BET, and X-ray diffraction. The results are as follows ; 1. Setting time was delayed by the addition of MgSiF6.6H2O. 2. The flow value of mortar decreases depending upon the amount of MgSiF6.6H2O. 3. The compressive strength was almost same or some increase on 28 days hydration. 4. The main retardation mechanism of MgSiF6 on the hydration of portland cement may be explained by the following hypothesis. MgSiF6 depressing the Ca++ and K+ ion concentration of cement paste solution be-cause of the recrystalization of K2SiF6 and CaF2 phase. The new products of K2SiF6 and CaF2 deposit on the surface of unhydrated cement powder and harzard the mass transfer through these layer. The low con-centration of Ca++, K+ ion in solution was decreasing the hydration rate of portland cement.

• Journal of the Korean Ceramic Society
• /
• v.34 no.2
• /
• pp.115-122
• /
• 1997

The powder preparation by using emulsion drying method, one of the chemical powder fabrication methods has the advantages; easy to control the chemical stoichiometry and to fabricate homogeneously fine particles. In the present study, the initial morphology and size distribution of the powder fabricated by using emulsion dry-ing method were controlled and were improved the homogeneity. By carefully controlling the mixing ratio of oil phase and aqueous solution and surfactant of preventing emulsion separation, the Bi(Pb)-Sr-Ca-Cu-O su-perconducting powders were prepared. The properties of the superconducting powder fabricated by this method and the microstructures and superconducting properties of the pelletized samples were investigated. The microstructures and electric properties of the tapes prepared by oxide powder-in-tube method were in-vestigated. The fabricated powder was spherical with less than 1$\mu$m but most of them was agglomerated with 2~5$\mu$m in size. The critical temperature of the pelletized sample annealed at 84$0^{\circ}C$ for 72 hours in oxygen par-tial pressure of 1/13atm in Ar atmosphere was 108K. And the critical current of the first and second annealed tapes in air prepared by oxide powder-in-tube process were 0.4A and 1.5A, respectively.