• Title/Summary/Keyword: 철입자

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Effect of F$e_2$P Addition on Microstructures of Sintered 4600 Steel (4600계 소결강의 조직에 미치는 F$e_2$P첨가의 영향)

  • Kim, Dong-Uk;Lee, Wan-Jae
    • Korean Journal of Materials Research
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    • v.2 no.6
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    • pp.428-435
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    • 1992
  • AISI 4600 Iron powder was mixed with 0~1.0% phosphor as F$e_2$P powder and/or 0~0.8% carbon as graphite powder in rotating mixer. Mixed powder was pressed 800MPa in double-punch mould. Compacts were sintered at 115$0^{\circ}C$for 30 min. in vacuum or mixed hydrogen and nitrogen gas. Sintered compacts were ground and polished, and etched by 2% nital etchant. The microstructure was observed by image analyzer and optical microscope. Density and microhardness were tested by ASTM B3l2 and Microvickers hardness tester. The results obtained were as follows : (1) As the amount of F$e_2$P powder increased, sintered microstructure showed more densified effect and the grain size was larger. (2) The shape of pore was rounded and the number of pore was decreased by F$e_2$P addition. But mean pore size was larger with F$e_2$P content. (3) Simultaneous alloying addition of F$e_2$P and graphite brought about larger grain growth than respective addition. (4) Sintering atmosphere did not affect the microstructure. (5) Hardness of sintered compact increased with phosphrous and carbon content.

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Surface Modification of Liposomes Using Comblike Copolymer for Enhancing Stability in Blood Circulation (혈류 내 안정성 향상을 위한 빗 모양 고분자로 개질된 리포솜)

  • Sin, Byeong-Cheol;Song, Chung-Gil;Hwang, Tae-Won;Seong, Ha-Su;Park, Eun-Seok
    • Journal of the Korean Chemical Society
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    • v.50 no.3
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    • pp.216-223
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    • 2006
  • To increase the stability of liposomes in blood circulation, surface modification of liposomes by incorporating a lipid-polymer derivative in the lipid bilayer or conjugating a hydrophilic polymer to the liposomal surface has been developed. In this study, the comblike copolymer, poly(HEMA-co-HPOEM), having multiple polyethyleneoxide side chains was prepared by free radical polymerization of hydroxyethylmethacrylate (HEMA) and hydroxypolyoxyethylenemethacrylate (HPOEM) as vinyl monomers. Poly(HEMA-co-HPOEM) was conjugated to the liposomal surface and the characteristics of the modified liposomes in serum were investigated. Conjugation of poly(HEMA-co-HPOEM) to liposomes increased the particle size of the liposomes by 30 nm and decreased the absolute value of zeta potential of the liposomes by shielding the negative charge of liposomal surface. Loading efficiency of model drug, doxorubicin, in liposomes was about 90% and the efficiency was not affected by conjugation of poly(HEMA-co-HPOEM) to liposomes. The particle size of poly(HEMA-co-HPOEM)-conjugated liposomes in serum did not changed and the protein adsorption was lower than that of control liposomes or liposomes containing polyethyleneoxide-lipid derivative (PEG-liposomes). These results suggest that poly(HEMA-co-HPOEM) is efficient for the stabilization of liposomes in blood circulation.

Simulation of Water Quality Changes in the Saemangeum Reservoir Induced by Dike Completion (방조제 완공에 따른 호내부 수질변화 모의)

  • Suh, Seung-Won;Lee, Hwa-Young;Yoo, Sang-Cheol
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.22 no.4
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    • pp.258-271
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    • 2010
  • In order to figure out hydrodynamic and water quality changes after completion of dike construction of the Saemangeum, which behaves as a semi-enclosed estuarine lake, numerical simulations based on fine grid structure by using EFDC were intensively carried out. In this study some limitations of precedent study has been improved and gate operation were considered. Also 3 phases such as air-water-sediment interaction modeling was considered. It is clear that inner mixing of the Saemangeum is dominated by Mankyeong and Dongjin riverine discharges rather than the gate opening influence through the Lagrangian particle tracking simulations. Vertical DO structure after the dike completion shows steep gradient especially at Dongjin river estuary due to lessen of outer sea water exchange. Increasing SOD at stagnantly changed man-made reservoir might cause oxygen deficiency and accelerating degradation of water quality. According to TSI evaluation test representing eutrophication status, it shows high possibility of eutrophication along Mankyeong waterway in spite of dike completion, while the index is getting high after final closing along Dongjin waterway. Numerical tests with gate operations show significant differences in water quality. Thus it should be noted that proper gate operation plays a major role in preserving target water quality and management for inner development plan.

A Study on the Mill Scale Pretreatment and Magnetite Production for Phosphate Adsorption (인 흡착을 위한 Mill Scale 전처리 및 Magnetite 제조 연구)

  • Chun, Hyuncheol;Choi, Younggyun
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.4
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    • pp.246-252
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    • 2015
  • In steel factory, hot roller cleaning process produces a lot of iron oxide particles called as mill scale. Major components of these particles are wustite (FeO), magnetite ($Fe_3O_4$), and hematite ($Fe_2O_3$). In this study, we tried to produce pure magnetite from the mill scale because of the largest phosphate adsorption capacity of the magnetite. The mill scale was treated with acid (HCl+$H_2O_2$), base (NaOH), and acid-base ($H_2SO_4$+NaOH). Batch adsorption tests showed the acid and/or base treatment could increase the phosphate adsorption capacity of the iron oxides from 0.28 to over 3.11 mgP/g. Magnetite, which could be obtained by acid and base treatment of the mill scale, showed the best adsorption capacity. From the kinetic analysis, both Freundlich and Langmuir isotherm well described the phosphate adsorption behavior of the magnetite. In Langmuir model, maximum phosphate adsorption capacity was found to be 5.1 mgP/g at $20^{\circ}C$.

Comparison of Characteristics of Local Meteorological and Particulate Matter(TSP) on the Beopjusa Temple and Seonamsa Temple (법주사와 선암사의 국지 기상 및 미세먼지 특성 비교)

  • Kim, Myoung Nam;Lim, Bo A;Lee, Myeong Seong;Jeong, So Young
    • Journal of Conservation Science
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    • v.33 no.4
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    • pp.283-295
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    • 2017
  • It is crucial to measure meteorological elements in relation to the biodeterioration of building cultural heritages. The Beopjusa and Seonamsa temples located respectively in Chungbuk and Jeonnam provinces, Korea, exhibit biological damage to the building cultural heritages and cause noticeable climatic differences. To compare biodeterioration environments of the abovementioned temples, 10 meteorological elements were observed, and particulate matter (TSP) was collected at each location. Furthermore, a correlation analysis was conducted between meteorological elements, and between meteorological elements and TSP. The local meteorology at Beopjusa temple characteristically showcased high total horizontal radiation, UV radiation, evaporation, wind speed, and TSP concentration, whereas, that at Seonamsa temple showcased high temperature, humidity, dew point temperature, air pressure, precipitation and number of days with precipitation. An elemental analysis of TSP revealed the presence of sae-salts at Seonamsa temple, and compared to that of Beopjusa temple, the monthly frequencies of biogenic aerosol and Fe-containing particles were higher. The correlation analysis showed that wind speed and humidity were major meteorological factors at Beopjusa and Seonamsa temples, respectively. Subsequently, the characteristics of the local meteorology at Seonamsa temple are expected to affect the biological damage of the building cultural heritages, which is favorable for the growth of various organisms.

Saccharification of Uncooked Starch (무증자 전분의 당화에 관한 연구)

  • Lee, S.Y.;Shin, Y.C.;Lee, S.H.;Park, S.S.;Kim, H.S.;Byun, S.M.
    • Korean Journal of Food Science and Technology
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    • v.16 no.4
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    • pp.463-471
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    • 1984
  • For the eventual alcohol production from uncooked starch, an efficient saccharification process was examined by using the combined action of steeping, pectin depolymerase, ${\alpha}-amylase$ and glucoamylase. The total sugar content of rice, sweet potato and tapioka used were 4.53, 4.26, and 3.92 mmole/g sample. $70\;{\pm}\;10%$ of the total sugar was hydrolyzed when cooked starch was saccharified under the condition which is currently used in industry. The smaller starch particle was used, the more saccharification was obtained. Efficient saccharification was obtained by treatment with 5% $H_2SO_4$ (sample: working volume = 1:2) at $60^{\circ}C$ for 12 hr. Optimization was carried out for the saccharification of uncooked starch by the combined action of pectin depolymerase, ${\alpha}-amylase$, and glucoamylase. The conditions are: pectin depolymerase; pH 4.5, $45^{\circ}C$, 2 hr, ${\alpha}-amylase$; pH 6.0, $60^{\circ}C$, 1 hr, and glucoamylase; pH 3.5, $60^{\circ}C$, 1 hr. Simultaneous treatment of the combined action of macerating, liquifying and saccharifying enzymes yielded better result than stepwise treatment of 3 enzymes. Degrees of saccharification of uncooked tapioka, rice and sweet potato were 82, 90.5, and 84.5%, respectively on the basis of total sugar, under the optimized conditions.

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Characteristics of the Lidar Ratio Determined from Lidar and Sky Radiometer Measurements in Seoul (라이다와 스카이 라디오미터 관측 자료를 이용한 서울지역 라이다 비의 특성 분석)

  • Kim, M.H.;Kim, S.W.;Yoon, S.C.;Sugimoto, Nobuo;Sohn, B.J.
    • Atmosphere
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    • v.21 no.1
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    • pp.57-67
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    • 2011
  • Aerosol lidar ratio (extinction-to-backscatter ratio) at 532 nm was determined using 4-year measurements of elastic-backscatter lidar and sky radiometer at Seoul National University of Seoul, Korea. The mean lidar ratio (with standard deviation) based on 4 years of measurements is found to be $61.7{\pm}16.5$ sr, and weak seasonal variations are noted with a maximum in JJA ($68.1{\pm}16.8$ sr) and a minimum in DJF ($57.2{\pm}17.9$ sr). The lidar ratios for clean, dust, and polluted conditions are estimated to be $45.0{\pm}9.5$ sr, $51.7{\pm}13.7$ sr, and $62.2{\pm}13.2$ sr, respectively. While the lidar ratio for the polluted condition is appears to be consistent with previous studies, clean and dust conditions tend to have larger ratios, compared to previous estimates. This discrepancy is thought to be mainly due to the anthropogenic aerosols existing throughout the year around Seoul, which may cause increased lidar ratios even for clean and dust conditions.

Strength Characteristics on Sulfuric Acid Corrosion of Recycled PET Polymer Concrete with Different Fillers (충전재 종류에 따른 PET재활용 폴리머콘크리트의 황산부식에 대한 강도 특성)

  • Jo Byung-Wan;Shin Kyung-Chul;Park Seung-Kook
    • Journal of the Korea Concrete Institute
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    • v.17 no.4 s.88
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    • pp.499-504
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    • 2005
  • Polymer concrete shows excellent mechanical properties and chemical resistance compared with conventional normal cement concrete. The polymer concrete Is drawing a strong interest as high-performance materials in the construction industry Resins using recycled PET offer the possibility of a lower source cost of materials for making useful polymer concrete products. Also the recycling of PET in polymer concrete would help solve some of the solid waste problems Posed by plastics and save energy. An objective of this paper is to estimate the damage of sulfuric acid, through investigating recycled PET polymer concrete, immersed at sulfuric acid solution for 84 days. As a result of testing, recycled PET PC, used $CaCO_3$ as filler, makes a problem of appearance and strength if they are exposed for long term at corrosion environment. On the other hand, recycled PET PC, used fly-ash as filler, had less effect on decrease in weight and strength. Recycled PET PC is excellent chemical resistance, resulting in the role of unsaturated polyester resin which consists of polymer chain structure accomplishes bond of aggregates and filler strongly. Also, recycled PET PC, used fly-ash as filler, is stronger resistance of sulfuric acid corrosion than $CaCO_3$, because it is composed of $SiO_2$ and very strong glassy crystal structure. Therefore, recycled PET PC, used fly-ash as filler, is available under corrosion circumstances like sewer pipe or waste disposal plant.

Control of Suspended Dust in Various Ventilation Systems of Cement Packaging Process (시멘트 포장공정에서 환기시스템에 따른 발생분진의 제어)

  • Lee, Seung-Chul;Kim, Soo-Chang;Noh, Kwang-Chul;Park, Myoung-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.3
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    • pp.463-469
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    • 2009
  • We performed the experimental study on the control of suspended dust in a cement packaging process for various ventilation systems. To effectively remove the dust generated in the cement packaging process, three different kinds of ventilation system, such as local exhaust ventilation, electrostatic scrubber, and local air supply system, were adopted. Dust concentrations in the packaging process were measured with the variation of the airflow rate of the ventilation systems and then their ventilation performance were evaluated. From the results, we knew that the ventilation performance was the best when the local exhaust ventilation and the electrostatic scrubber were simultaneously operated in the packaging process. In the electrostatic scrubber system, the effect of the airflow rate on the indoor dust removal efficiency was negligible so hat he system ust be operated at $2,700m^3/h$ for saving power consumption.

A Study on Strength and Durability Characteristics of Cemented Weathered Mudstone (풍화 이암 고결토의 강도 및 내구성 특성에 관한 연구)

  • Kim, Seong-Heon;Moon, Hong-Duk;Park, Sung-Sik
    • Journal of the Korean Geotechnical Society
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    • v.35 no.10
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    • pp.33-45
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    • 2019
  • In this study, in order to recycle a large amount of rocks and weathered mudstones produced by civil engineering projects such as railways and highways, as materials for roadbeds or embankment materials, circumferential specimens with a diameter of 5 cm and a height of 10 cm were made. A mudstone that weathered rapidly during rainfall was collected from Pohang construction sites. The weathered mudstone passed through a 2 mm sieve. It was prepared with the cement ratio, the sand ratio, curing condition and curing days. Three specimens were prepared according to each condition and then the unconfined compressive test, durability test and SEM analysis were performed to evaluate the engineering properties of the cemented soil. In the case of 28 days cured specimen, the strength of under-water cured specimens was 32-55% and the durability index was about 15% higher than air cured specimens. In addition, when the CR increased from 8% to 16%, the unconfined compressive strength (UCS) of pure mudstone cemented soil under water increased by about 1.6 times and the durability index increased by about 1.9 times. When the SR increased from 0% to 50%, the UCS of the specimen with SR = 10% was slightly less than or equal to specimen with SR = 0%. Then, as the SR became 30-50%, the UCS increased up to 51%. Unlike the UCS, the durability index increased continuously as the SR increased. As a result of SEM analysis, when SR was 50% rather than SR = 0%, the contact between sand particles increased and they were connected to each other. Such contact between these particles resulted in the increase of strength.